9-[2-(2-methoxyvinyl)phenyl]phenanthrene | 1152089-85-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 9-[2-(2-methoxyvinyl)phenyl]phenanthrene
• 英文别名: 9-[2-(2-Methoxyvinyl)phenyl]phenanthrene；9-[2-(2-methoxyethenyl)phenyl]phenanthrene
• CAS: 1152089-85-4
• 化学式: C₂₃H₁₈O
• 分子量: 310.395
• InChiKey: VKYNIJKLEGOWGB-UHFFFAOYSA-N

物化性质

• 沸点：
  494.3±24.0 °C(Predicted)
• 密度：
  1.148±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9-[2-(2-methoxyvinyl)phenyl]phenanthrene 在 甲烷磺酸 potassium carbonate 作用下， 以 二氯甲烷 、 dichloromeerosene 、 水 为溶剂， 反应 8.0h， 以25%的产率得到苯并[G]屈
  参考文献：
  名称：

  NITROGENATED HETEROCYCLIC RING DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT COMPRISING SAME

  摘要：

  公开号：

  EP2524913B1
• 作为产物：
  描述：

  9-溴菲 、 2-甲酰基苯硼酸 在 四(三苯基膦)钯 potassium tert-butylate 、 sodium carbonate 作用下， 以 四氢呋喃 、 乙二醇二甲醚 、 水 为溶剂， 反应 10.0h， 生成 9-[2-(2-methoxyvinyl)phenyl]phenanthrene
  参考文献：
  名称：

  NITROGENATED HETEROCYCLIC RING DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT COMPRISING SAME

  摘要：

  公开号：

  EP2524913B1

文献信息

• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Kawamura Yuichiro

  公开号：US20120153268A1

  公开（公告）日：2012-06-21

  An organic electroluminescence device includes an anode, an emitting layer, an electron-transporting region, and a cathode, the anode, the emitting layer, the electron-transporting region, and the cathode being stacked in this order, the emitting layer including a host material, and a dopant material that emits fluorescence having a main peak wavelength of 550 nm or less, the electron-transporting region including a barrier layer that is adjacent to the emitting layer, and the barrier layer including a barrier material that includes an electron-transporting structural part, and a triplet barrier structural part that includes a fused polycyclic aromatic hydrocarbon compound, and satisfies the relationship “E T b >E T h ” (where, E T h is the triplet energy of the host material, and E T b is the triplet energy of the barrier material).

  一种有机电致发光器件包括阳极、发光层、电子传输区和阴极，阳极、发光层、电子传输区和阴极依次堆叠，发光层包括主体材料和发射荧光的掺杂材料，其主峰波长为550nm或更低，电子传输区包括邻近发光层的阻挡层，该阻挡层包括具有电子传输结构部分和包括融合的多环芳香族碳化合物的三重态阻挡结构部分的阻挡材料，并满足“ETb>ETh”的关系（其中，ETh是主体材料的三重态能量，而ETb是阻挡材料的三重态能量）。
• NITROGENATED HETEROCYCLIC RING DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT COMPRISING SAME
  申请人：Kawamura Masahiro

  公开号：US20120132899A1

  公开（公告）日：2012-05-31

  A nitrogen-containing heterocyclic derivative represented by the following formula (1): wherein any “12-a” groups of R 1 to R 12 are independently a hydrogen atom, a fluorine atom, a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms or a substituted or unsubstituted heterocyclic group having 5 to 30 ring atoms; any “a” groups of R 1 to R 12 are independently a single bond which is bonded to L 1 ; L 1 is a single bond, a “b+1” valent substituted or unsubstituted hydrocarbon ring group having 6 to 30 ring carbon atoms or a “b+1” valent substituted or unsubstituted heterocyclic group having 5 to 30 ring atoms; HAr is a substituted or unsubstituted nitrogen-containing heterocyclic group; and “a” and “b” are independently an integer of 1 to 4, and at least one of “a” and “b” is 1. Also disclosed is a nitrogen-containing heterocyclic derivative represented by the following formula (21) or (31):

  一种含氮杂环衍生物，由以下公式（1）表示：其中R1至R12中的任何“12-a”基团独立地是氢原子、氟原子、具有6至30个环碳原子的取代或未取代芳基基团或具有5至30个环原子的取代或未取代杂环基团；R1至R12中的任何“a”基团独立地是与L1相结合的单键；L1是单键、具有6至30个环碳原子的“b+1”价取代或未取代的碳氢环基团或具有5至30个环原子的“b+1”价取代或未取代的杂环基团；HAr是取代或未取代的含氮杂环基团；“a”和“b”分别是1至4的整数，且至少有一个“a”和“b”为1。还公开了一种由以下公式（21）或（31）表示的含氮杂环衍生物：
• Organic electroluminescence device
  申请人：Kawamura Yuichiro

  公开号：US08803420B2

  公开（公告）日：2014-08-12

  An organic electroluminescence device includes an anode, an emitting layer, an electron-transporting region, and a cathode, the anode, the emitting layer, the electron-transporting region, and the cathode being stacked in this order, the emitting layer including a host material, and a dopant material that emits fluorescence having a main peak wavelength of 550 nm or less, the electron-transporting region including a barrier layer that is adjacent to the emitting layer, and the barrier layer including a barrier material that includes an electron-transporting structural part, and a triplet barrier structural part that includes a fused polycyclic aromatic hydrocarbon compound, and satisfies the relationship “ETb>ETh” (where, ETh is the triplet energy of the host material, and ETb is the triplet energy of the barrier material).

  一种有机电致发光器件包括阳极、发光层、电子传输区和阴极，阳极、发光层、电子传输区和阴极依次堆叠，发光层包括主体材料和发射荧光的掺杂材料，其主峰波长为550纳米或更短，电子传输区包括邻近发光层的阻挡层，阻挡层包括包含电子传输结构部分和三重态阻挡结构部分的阻挡材料，满足“ETb>ETh”的关系（其中，ETh是主体材料的三重态能量，ETb是阻挡材料的三重态能量）。
• Nitrogenated heterocyclic ring derivative and organic electroluminescent element comprising same
  申请人：Kawamura Masahiro

  公开号：US09126943B2

  公开（公告）日：2015-09-08

  A nitrogen-containing heterocyclic derivative represented by the following formula (1): wherein any “12-a” groups of R1 to R12 are independently a hydrogen atom, a fluorine atom, a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms or a substituted or unsubstituted heterocyclic group having 5 to 30 ring atoms; any “a” groups of R1 to R12 are independently a single bond which is bonded to L1; L1 is a single bond, a “b+1” valent substituted or unsubstituted hydrocarbon ring group having 6 to 30 ring carbon atoms or a “b+1” valent substituted or unsubstituted heterocyclic group having 5 to 30 ring atoms; HAr is a substituted or unsubstituted nitrogen-containing heterocyclic group; and “a” and “b” are independently an integer of 1 to 4, and at least one of “a” and “b” is 1. Also disclosed is a nitrogen-containing heterocyclic derivative represented by the following formula (21) or (31):

  一种含氮杂环衍生物，由以下式子（1）表示： 其中R1至R12中的任何“12-a”基团分别独立地为氢原子、氟原子、具有6至30个环碳原子的取代或未取代芳基团或具有5至30个环原子的取代或未取代杂环基团；R1至R12中的任何“a”基团分别独立地为与L1键合的单键；L1为单键、具有6至30个环碳原子的“b+1”价取代或未取代碳氢环基团或具有5至30个环原子的“b+1”价取代或未取代杂环基团；HAr为取代或未取代的含氮杂环基团；且“a”和“b”独立地为1至4的整数，且至少一个为1。还公开了由以下式子（21）或（31）表示的含氮杂环衍生物：
• BENZOCHRYSENE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2213640B1

  公开（公告）日：2016-10-05