α-ethylbenzyl ethyl sulfide | 75490-49-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: α-ethylbenzyl ethyl sulfide
• 英文别名: [1-(Ethylsulfanyl)propyl]benzene；1-ethylsulfanylpropylbenzene
• CAS: 75490-49-2
• 化学式: C₁₁H₁₆S
• 分子量: 180.314
• InChiKey: LPTDJGUBRAOSSX-UHFFFAOYSA-N

物化性质

• 沸点：
  245.3±9.0 °C(Predicted)
• 密度：
  0.966±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  α-(ethylthio)styrene 、 甲基锂 生成 α-ethylbenzyl ethyl sulfide
  参考文献：
  名称：

  Arene-metal complexes in organic synthesis: addition to styrene-type ligands

  摘要：

  DOI：

  10.1021/ja00541a048

文献信息

• The Formation of 1,2-Bis(alkylthio)-1,2-diphenylethanes by the Lithium Diisopropylamide-induced Fragmentation of Dibenzyl Disulfide Followed by the Trapping with Some Alkyl Halides
  作者：Hideyuki Ikehira、Shigeo Tanimoto

  DOI：10.1246/bcsj.57.1423

  日期：1984.5

  It was found that dibenzyl disulfide undergoes lithium diisopropylamide-induced fragmentation to afford several intermediate species which, on trapping with alkyl halides, lead to the formation of 1,2-bis(alkylthio)-1,2-diphenylethanes and α-alkylbenzyl alkyl sulfides.

  发现二苄基二硫化物经过二异丙基氨基锂诱导的碎裂以提供几种中间体，这些中间体在被烷基卤化物捕获时导致形成 1,2-双（烷硫基）-1,2-二苯基乙烷和 α-烷基苄基烷基硫化物.
• The Lithium Diisopropylamide-induced Fragmentation of 1,3-Dithiolane Derivatives of Several Ketones Having α-Hydrogen
  作者：Hideyuki Ikehira、Shigeo Tanimoto、Tatsuo Oida

  DOI：10.1246/bcsj.56.2537

  日期：1983.8

  The reaction of 1,3-dithiolane derivatives of ketones having α-hydrogen with lithium diisopropylamide results in fragmentation to the corresponding thioketone followed by further conversion in a few steps to the other intermediate species which, on trapping with alkyl halide, leads to a vinylic sulfide and/or a sulfide bearing a secondary alkyl group.

  具有 α-氢的酮的 1,3-二硫杂环戊烷衍生物与二异丙基氨基锂的反应导致裂解为相应的硫酮，然后在几个步骤中进一步转化为其他中间体物种，在用烷基卤化物捕获时，产生乙烯基硫化物和/或带有仲烷基的硫化物。
• IKEHIRA, HIDEYUKI;TANIMOTO, SHIGEO;OIDA, TATSUO, BULL. CHEM. SC. JAP., 1983, 56, N 8, 2537-2538
  作者：IKEHIRA, HIDEYUKI、TANIMOTO, SHIGEO、OIDA, TATSUO

  DOI：——

  日期：——
• IKEHIRA, HIDEYUKI;TANIMOTO, SHIGEO, BULL. CHEM. SOC. JAP., 1984, 57, N 5, 1423-1424
  作者：IKEHIRA, HIDEYUKI、TANIMOTO, SHIGEO

  DOI：——

  日期：——
• FORMULATIONS COMPRISING A MIXTURE OF ZNO CUBANES AND PROCESS USING THEM TO PRODUCE SEMICONDUCTIVE ZNO LAYERS
  申请人：Thiem Heiko

  公开号：US20110193084A1

  公开（公告）日：2011-08-11

  The present invention relates to formulations comprising a) at least two different ZnO cubanes of which at least one ZnO cubane is present in solid form under SATP conditions and at least one ZnO cubane is present in liquid form under SATP conditions, and b) at least one solvent, to processes for producing semiconductive ZnO layers from these formulations, to the use of the formulations for producing electronic components and to the electronic components themselves.