p-(N,N-diethylamino)thiophenol | 4946-24-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯硫酚类
• 英文名称: p-(N,N-diethylamino)thiophenol
• 英文别名: 4-diethylamino-thiophenol；p-N,N-Diaethylaminothiophenol；4-Diaethylamino-thiophenol；4-(diethylamino)-benzenethiol；4-(Diethylamino)thiophenol；4-(diethylamino)benzenethiol
• CAS: 4946-24-1
• 化学式: C₁₀H₁₅NS
• mdl: MFCD06201796
• 分子量: 181.302
• InChiKey: WUBPBSLVSRGNFH-UHFFFAOYSA-N

物化性质

• 沸点：
  124 °C(Press: 0.14 Torr)
• 密度：
  1.047±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  4.2
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 海关编码：
  2930909090

反应信息

• 作为反应物：
  描述：

  p-(N,N-diethylamino)thiophenol 在 碘 、 碳酸氢钠 、 potassium iodide 作用下， 生成 bis-(4-diethylamino-phenyl)-disulfide
  参考文献：
  名称：

  Benn et al., Journal of the Chemical Society, 1958, p. 2800,2804

  摘要：

  DOI：
• 作为产物：
  描述：

  4-thiocyanato-N,N-diethylaniline 在 lithium aluminium tetrahydride 作用下， 生成 p-(N,N-diethylamino)thiophenol
  参考文献：
  名称：

  Benn et al., Journal of the Chemical Society, 1958, p. 2800,2804

  摘要：

  DOI：

文献信息

• 7.alpha.-Substituted derivatives of androstenedione as inhibitors of estrogen biosynthesis
  作者：M. V. Darby、J. A. Lovett、R. W. Brueggemeier、M. P. Groziak、Raymond E. Counsell

  DOI：10.1021/jm00383a019

  日期：1985.6

  In an effort to obtain more information on the structure-activity relationship among the 7 alpha-(phenylthio)androstenedione inhibitors of the enzyme aromatase, a series of compounds containing both electron-donating and electron-withdrawing ring substituents was synthesized and tested for aromatase inhibitory activity. No linear correlation between substituent electronic effects and inhibitory activity

  为了获得有关7种芳香酶的α-（苯硫基）雄烯二酮抑制剂之间的构效关系的更多信息，合成了一系列同时具有给电子和吸电子环取代基的化合物，并测试了其对芳香酶的抑制作用。活动。在取代基电子效应和抑制活性之间没有观察到线性相关性。含卤素的化合物，特别是8种，似乎是非常有效的抑制剂。为了评估在测定条件下消除侧链的可能性，合成了8的125I类似物。在测定条件下，大约90％的[125I] -8保持完整状态长达1小时。
• Cytotoxic compounds. Part VIII. Some S-α-(acylamino)acyl-p-[di-(2-halogenoethyl)amino]thiophenols
  作者：M. V. A. Baig、L. N. Owen

  DOI：10.1039/j39660000540

  日期：——

  Fourteen thiolesters of this type have been synthesised by acylation of p-[di-(2-chloroethyl)amino]thiophenol, or the dibromo-analogue, with a variety of α-N-acylamino-acids in the presence of dicyclohexylcarbodi-imide. The deactivation of the “mustard” caused by this acylation of the thiol group, as measured by the diminished rate of hydrolysis of the halide, is similar to that brought about by simple

  在对二[环己基碳二亚胺]存在下，通过对-[二-（2-氯乙基）氨基]苯硫酚或二溴类似物与各种α - N-酰基氨基酸的酰化反应，已经合成了十四种这种类型的巯基酯。如通过卤化物的水解速率降低所测量的，由巯基的这种酰化作用引起的“芥末”的失活类似于由简单的乙酰化所引起的失活。
• RADIATION-SENSITIVE COLORED COMPOSITION, COLORED CURED FILM, COLOR FILTER AND METHOD OF PRODUCING THE SAME, SOLID-STATE IMAGING DEVICE, LIQUID CRYSTAL DISPLAY APPARATUS, AND METHOD OF PRODUCING DYE
  申请人：USHIJIMA Kenta

  公开号：US20120235099A1

  公开（公告）日：2012-09-20

  The object of the present invention is to provide a radiation-sensitive colored composition which can supress the generation of the contamination of the device. A radiation-sensitive colored composition including: (A) a dye containing of from 10 ppm to 1000 ppm of a halogen ion; (B) a polymerizable compound; and (C) a solvent.

  本发明的目的是提供一种辐射敏感的着色组合物，可以抑制器件的污染产生。一种辐射敏感的着色组合物，包括：（A）一种含有10 ppm至1000 ppm卤离子的染料；（B）一种可聚合化合物；和（C）一种溶剂。
• BLACK PHOTOSENSITIVE RESIN COMPOSITION, AND COLOR FILTER AND METHOD OF PRODUCING THE SAME
  申请人：Einaga Hiroyuki

  公开号：US20090280416A1

  公开（公告）日：2009-11-12

  A black photosensitive resin composition, a light-shielding color filter using the composition and its production method are provided, the black photosensitive resin composition including: a black colorant; a compound represented by Formula (I) or (II) as defined in the specification; and a photopolymerization initiator.

  提供了一种黑色光敏树脂组合物、使用该组合物的遮光彩色滤光片及其生产方法，该黑色光敏树脂组合物包括：黑色着色剂；由公式（I）或（II）表示的化合物，如规范所定义；以及光聚合引发剂。
• Plasma display filter
  申请人：MITSUI TOATSU CHEMICALS, INCORPORATED

  公开号：EP0782164A1

  公开（公告）日：1997-07-02

  As a plasma display filter for efficiently cutting off near infrared rays radiated from a plasma display so that malfunction of electronic equipment located around the display making use of near infrared light can be avoided, a filter containing in a base material at least one near infrared ray absorbing compound having a maximum absorption wavelength at 800 to 1,200 nm is provided.

  作为一种等离子显示器滤光片，它可以有效地切断等离子显示器辐射的近红外线，从而避免显示器周围使用近红外线的电子设备发生故障。