二(2,4,6-三溴苯基)氯磷酸酯 | 70757-60-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 二(2,4,6-三溴苯基)氯磷酸酯
• 中文别名: 环己羧酸,4-[2-(4-丙基环己基)乙基]-,4-氰基苯基酯,[反(反)]-(9CI)
• 英文名称: bis(2,4,6-tribromophenyl) phosphorochloridate
• 英文别名: 1,3,5-tribromo-2-[chloro-(2,4,6-tribromophenoxy)phosphoryl]oxybenzene
• CAS: 70757-60-7
• 化学式: C₁₂H₄Br₆ClO₃P
• 分子量: 742.013
• InChiKey: OAUJBKXCQJYOTO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  23
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  二(2,4,6-三溴苯基)氯磷酸酯 在 水 作用下， 反应 18.0h， 以68%的产率得到双(2,4,6-三溴苯基)磷酸氢盐
  参考文献：
  名称：

  Hydrogen phosphates: Self initiated organocatalysts for the controlled ring-opening polymerization of cyclic esters

  摘要：

  A series of arylhydrogenphosphates and aryldihydrogenphosphates was synthesized and characterized using spectroscopic methods and single crystal X-ray diffraction. These compounds were assessed as catalysts towards the ring-opening polymerization and proved to be potent organocatalysts for the ring-opening polymerization of cyclic esters. The bulk polymerizations were performed in the absence of external initiator. The polymerization proceeds in a controlled fashion which leads to well defined polyesters with narrow molecular weight distributions. In the post polymerization experiments, kinetics, mechanism and monomer concentration effects were investigated. The kinetic results have confirmed the pseudo-living character of the polymerizations and mechanistic studies suggest that the polymerization operates through a cationic mechanism. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.02.006
• 作为产物：
  描述：

  三溴苯酚 在 吡啶 、 三氯氧磷 作用下， 生成 二(2,4,6-三溴苯基)氯磷酸酯
  参考文献：
  名称：

  通过与（氨基-1,3,5-三嗪基）氨基磷酸酯的曼尼希反应获得阻燃性木质纤维素纳米纤维（LCNF）及其性能

  摘要：

  通过用 POCl 3连续处理 ArOH (Ar = Br n C 6 H 5− n , n = 0, 1, 2, 和 3) 制备了耐久阻燃剂氮/磷三聚氰胺 (NPCM)和三聚氰胺单体。所制备的阻燃剂通过曼尼希反应通过CH 2单元接枝至木质纤维素纳米纤维(LCNF)。使用 FT-IR (ATR) 和 EA 对所得三组分产品进行了表征。使用 TGA 和 DSC 分析确定经过 NPCM 处理的 LCNF 织物样品的热行为，并通过测量其有限氧指数 (LOI) 和 UL-94V 测试来评估其阻燃性。织物样品中的大量阻燃元素使 20 种未经处理的 LCNF 的 LOI 值增加了 45 之多。此外，还用扫描电子显微镜 (SEM) 研究了 NPCM 处理的 LCNF 及其烧焦织物的形态。用锥形量热计观察了 LCNF 织物对水性涂料的放热降低效果。此外，以 NPCM 处理的 LCNF 织物的拉伸强度表示的机械性能表明，PP

  DOI：

  10.1039/d1ra08716a
• 作为试剂：
  描述：

  3-benzoyl-1-[(2R,4S,5R)-4-bis(phenylsulfanyl)phosphoryloxy-5-(hydroxymethyl)oxolan-2-yl]-5-methylpyrimidine-2,4-dione 、 triethylammonium S-phenyl 5'-O-(4,4'-dimethoxytrityl)-3-N-benzoylthymidine 3'-phosphorothioate 在 3-nitrotriazole 、 二(2,4,6-三溴苯基)氯磷酸酯 作用下， 以 吡啶 为溶剂， 反应 0.25h， 以87%的产率得到
  参考文献：
  名称：

  磷酸三酯法中用于快速形成核苷酸间键的新型缩合试剂以及制备n 3-苯甲酰胸苷作为寡聚脱氧核糖核苷酸合成的关键中间体的方法

  摘要：

  在磷酸三酯方法快速间键形成已通过使用双（2,4,6-三trihalophenyl）phosphorochloridates（TCP和TBP）作为新的冷凝试剂和苯甲酰基作为N的以高产率取得3的亚胺保护基团胸腺嘧啶核苷。

  DOI：

  10.1016/0040-4039(84)80055-6

文献信息

• Kozlov,E.S. et al., Journal of general chemistry of the USSR, 1979, vol. 49, p. 666 - 669
  作者：Kozlov,E.S. et al.

  DOI：——

  日期：——
• KOZLOV EH. S.; KOLESNIK N. P.; DUBENKO L. G.; POVOLOTSKIJ M. I., ZH. OBSHCH. XIMII, 1979, 49, HO 4, 769-772
  作者：KOZLOV EH. S.、 KOLESNIK N. P.、 DUBENKO L. G.、 POVOLOTSKIJ M. I.

  DOI：——

  日期：——
• MATSUZAKI, JUN-ICHI;HOTODA, HITOSHI;SEKINE, MITSUO;HATA, TSUJIAKI, NUCLEOSIDES AND NUCLEOTIDES, 8,(1989) N, C. 367-382
  作者：MATSUZAKI, JUN-ICHI、HOTODA, HITOSHI、SEKINE, MITSUO、HATA, TSUJIAKI

  DOI：——

  日期：——
• Hydrogen phosphates: Self initiated organocatalysts for the controlled ring-opening polymerization of cyclic esters
  作者：Payal Malik、Debashis Chakraborty

  DOI：10.1016/j.ica.2013.02.006

  日期：2013.5

  A series of arylhydrogenphosphates and aryldihydrogenphosphates was synthesized and characterized using spectroscopic methods and single crystal X-ray diffraction. These compounds were assessed as catalysts towards the ring-opening polymerization and proved to be potent organocatalysts for the ring-opening polymerization of cyclic esters. The bulk polymerizations were performed in the absence of external initiator. The polymerization proceeds in a controlled fashion which leads to well defined polyesters with narrow molecular weight distributions. In the post polymerization experiments, kinetics, mechanism and monomer concentration effects were investigated. The kinetic results have confirmed the pseudo-living character of the polymerizations and mechanistic studies suggest that the polymerization operates through a cationic mechanism. (C) 2013 Elsevier B.V. All rights reserved.
• Flame retardance-donated lignocellulose nanofibers (LCNFs) by the Mannich reaction with (amino-1,3,5-triazinyl)phosphoramidates and their properties
  作者：Fumiaki Ono、Takumi Okihara、Noboru Osaka、Noriyuki Nagaoka、Yuji Kameoka、Akira Ishikawa、Hironari Ooki、Takumi Ito、Daisuke Todome、Shinya Uemoto、Mitsuaki Furutani、Tsutomu Inokuchi、Kenji Okada

  DOI：10.1039/d1ra08716a

  日期：——

  nanofibers (LCNFs) by the Mannich reaction. The resulting three-component products were characterized using FT-IR (ATR) and EA. The thermal behavior of the NPCM-treated LCNF fabric samples was determined using TGA and DSC analyses, and their flammability resistances were evaluated by measuring their Limited Oxygen Index (LOI) and the UL-94V test. A multitude of flame retardant elements in the fabric

  通过用 POCl 3连续处理 ArOH (Ar = Br n C 6 H 5− n , n = 0, 1, 2, 和 3) 制备了耐久阻燃剂氮/磷三聚氰胺 (NPCM)和三聚氰胺单体。所制备的阻燃剂通过曼尼希反应通过CH 2单元接枝至木质纤维素纳米纤维(LCNF)。使用 FT-IR (ATR) 和 EA 对所得三组分产品进行了表征。使用 TGA 和 DSC 分析确定经过 NPCM 处理的 LCNF 织物样品的热行为，并通过测量其有限氧指数 (LOI) 和 UL-94V 测试来评估其阻燃性。织物样品中的大量阻燃元素使 20 种未经处理的 LCNF 的 LOI 值增加了 45 之多。此外，还用扫描电子显微镜 (SEM) 研究了 NPCM 处理的 LCNF 及其烧焦织物的形态。用锥形量热计观察了 LCNF 织物对水性涂料的放热降低效果。此外，以 NPCM 处理的 LCNF 织物的拉伸强度表示的机械性能表明，PP