| 477564-63-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 477564-63-9
• 化学式: C₁₁H₉Cl₃NO₂P
• 分子量: 324.531
• InChiKey: MWJZTPVZLACHHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  22.3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  、 苯乙炔 生成 2,6-dichloro-2-oxo-4-phenylbenzo[e]-1,2-oxaphosphorinine
  参考文献：
  名称：

  Synthesis and Chemical Properties of Benzo[e]-1,2-Oxaphosphorinine Derivatives—Analogues of Coumarins

  摘要：

  The 4-aryl(alkyl)benzo[e]-1,2-oxaphosphorine derivatives (phosphacoumarins) were obtained by the reaction of 2,2,2-trihalogenobenzo[d]-1,3,2-dioxaphospholes with terminal acetylenes. The reactions of phosphacoumarins with halogens and Grignard reagents were investigated.

  DOI：

  10.1080/10426500701764957
• 作为产物：
  描述：

  吡啶 、 1,2-亚苯基三氯磷酸 生成
  参考文献：
  名称：

  Synthesis and Chemical Properties of Benzo[e]-1,2-Oxaphosphorinine Derivatives—Analogues of Coumarins

  摘要：

  The 4-aryl(alkyl)benzo[e]-1,2-oxaphosphorine derivatives (phosphacoumarins) were obtained by the reaction of 2,2,2-trihalogenobenzo[d]-1,3,2-dioxaphospholes with terminal acetylenes. The reactions of phosphacoumarins with halogens and Grignard reagents were investigated.

  DOI：

  10.1080/10426500701764957

文献信息

• Synthesis and Chemical Properties of Benzo[<i>e</i>]-1,2-Oxaphosphorinine Derivatives—Analogues of Coumarins
  作者：E. N. Varaksina、D. A. Tatarinov、K. Yu. Cherkin、A. V. Nemtarev、V. F. Mironov、A. I. Konovalov

  DOI：10.1080/10426500701764957

  日期：2008.1.14

  The 4-aryl(alkyl)benzo[e]-1,2-oxaphosphorine derivatives (phosphacoumarins) were obtained by the reaction of 2,2,2-trihalogenobenzo[d]-1,3,2-dioxaphospholes with terminal acetylenes. The reactions of phosphacoumarins with halogens and Grignard reagents were investigated.