silver;ethanedithioamide;triphenylphosphane;chloride | 177413-11-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: silver;ethanedithioamide;triphenylphosphane;chloride
• CAS: 177413-11-5
• 化学式: C₃₈H₃₄AgClN₂P₂S₂
• 分子量: 788.102
• InChiKey: VVAHGBVTBPKKMU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.45
• 重原子数：
  46
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  116
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  tetraethylammonium tetrathiomolybdate 、 silver;ethanedithioamide;triphenylphosphane;chloride 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and Characterization of Copper(I) and Silver(I) Complexes Containing Thioamide Ligands

  摘要：

  Mononuclear complexes of the type (Ph(3)P)(2)MLX, where M = Cu, Ag; X = Cl, Br; L = dithiooxamide, thiourea aminothiourea, have been synthesized and characterized by elemental analyses and IR spectra. The X-ray crystallographic structure determination of (Ph(3)P)(2)Cu(C2H4N2S2)Br is reported. Dithiooxamide acts as a monodentate ligand through one S atom coordinated to Cu. The coordination of the Cu atom is a distorted terrahedron with a Cu-Br distance of 2.482(3) and Cu-S distance of 2.356(5) Angstrom.

  DOI：

  10.1080/00945719608004331
• 作为产物：
  描述：

  四甲基氯化铵 、 AgNO₃(PPh₃) 、 二硫代乙酰胺 以 二氯甲烷 为溶剂， 以79.3%的产率得到silver;ethanedithioamide;triphenylphosphane;chloride
  参考文献：
  名称：

  Synthesis and Characterization of Copper(I) and Silver(I) Complexes Containing Thioamide Ligands

  摘要：

  Mononuclear complexes of the type (Ph(3)P)(2)MLX, where M = Cu, Ag; X = Cl, Br; L = dithiooxamide, thiourea aminothiourea, have been synthesized and characterized by elemental analyses and IR spectra. The X-ray crystallographic structure determination of (Ph(3)P)(2)Cu(C2H4N2S2)Br is reported. Dithiooxamide acts as a monodentate ligand through one S atom coordinated to Cu. The coordination of the Cu atom is a distorted terrahedron with a Cu-Br distance of 2.482(3) and Cu-S distance of 2.356(5) Angstrom.

  DOI：

  10.1080/00945719608004331

文献信息

• Chloro(ethanedithioamide-S)bis(triphenylphosphine)silver(I)
  作者：D. L. Long、X. Q. Xin、X. Y. Huang、B. S. Kang

  DOI：10.1107/s0108270195013813

  日期：1996.5.15

  The structure of the title compound, [AgCl(C2H4N2S2)-(C18H15P)(2)], is reported. Dithiooxamide acts as a monodentate ligand coordinating via one S atom to Ag. The coordination polyhedron of the Ag atom is a distorted tetrahedron, with an Ag-S distance of 2.604(1)Angstrom and an Ag-Cl distance of 2.580(1) Angstrom.