cis-dichlorobis(diphenyl(phenylethynyl)phosphine)platinum(II) | 42847-16-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cis-dichlorobis(diphenyl(phenylethynyl)phosphine)platinum(II)
• 英文别名: cis-PtCl2(diphenyl(phenylethynyl)phosphine)2；dichloroplatinum;diphenyl(2-phenylethynyl)phosphane
• CAS: 42847-16-5；30173-84-3
• 化学式: C₄₀H₃₀Cl₂P₂Pt
• 分子量: 838.612
• InChiKey: IFUMKPDWTCFUJB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  9.63
• 重原子数：
  45.0
• 可旋转键数：
  6.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  cis-dichlorobis(diphenyl(phenylethynyl)phosphine)platinum(II) 以 甲苯 为溶剂， 以73%的产率得到cis-dichloro(1-phenyl-2,3-bis(diphenylphosphino)naphthalene)platinum(II)
  参考文献：
  名称：

  Johnson, David K.; Rukachaisirikul, Thitima; Sun, Yan, Inorganic Chemistry, 1993, vol. 32, # 24, p. 5544 - 5552

  摘要：

  DOI：
• 作为产物：
  描述：

  苯基乙炔基二苯基膦 、 dichloro( 1,5-cyclooctadiene)platinum(ll) 以 苯 为溶剂， 以90-98的产率得到cis-dichlorobis(diphenyl(phenylethynyl)phosphine)platinum(II)
  参考文献：
  名称：

  Johnson, David K.; Rukachaisirikul, Thitima; Sun, Yan, Inorganic Chemistry, 1993, vol. 32, # 24, p. 5544 - 5552

  摘要：

  DOI：

文献信息

• Alkynyldiphenylphosphine d⁸ (Pt, Rh, Ir) Complexes:  Contrasting Behavior toward <i>cis</i>-[Pt(C₆F₅)₂(THF)₂]
  作者：Jesús R. Berenguer、María Bernechea、Juan Forniés、Ana García、Elena Lalinde、M. Teresa Moreno

  DOI：10.1021/ic048987j

  日期：2004.12.1

  CPh)Pt(C(10)H(4)-1-C(6)F(5)-4-Ph-2,3-kappaPP'(PPh(2))(2))](CF(3) SO(3)), 9 (X-ray), containing a 1-pentafluorophenyl-2,3-bis(diphenylphosphine)-4-phenylnaphthalene ligand, formed by annulation of a phenyl group and loss of the Pt(C(6)F(5)) unit. However, analogous reactions using 2 or 3 as precursors afford mixtures of complexes, from which we have characterized by X-ray crystallography the alkynylphosphine

  一系列具有至少两个P配位的炔基膦配体的单核d（8）配合物的合成，表征及其对顺式[Pt（C（6）F（5））（2）（THF）（2）的反应性]。阳离子[Pt（C（6）F（5））（PPh（2）C三键CPh）（3）]（CF（3）SO（3）），1，[M（COD）（PPh（ 2）C三键CPh）（2）]（ClO（4））（M = Rh，2和Ir，3）和中性[Pt（oC（6）H（4）E（2））（ PPh（2）C三键CPh）（2）]（E = O，6，和S，7）配合物已经制备，并且晶体结构为1，2，和7.CH（3）COCH（3 ）已通过X射线晶体学测定。单核络合物1-3、6和7与顺式[[Pt（C（6）F（5））（2）（THF）（2）]的反应过程受金属和金属的强烈影响。配体。因此，用1当量的顺式[[Pt（C（6）F（5））（2）（THF）（2）]处理1得到双插入阳离子产物[Pt（C（6）F（5））（ S）mu-（C（Ph）=
• Directed synthesis of phosphorus-substituted cyclopentadienones and cyclobutadienes via metal carbonyl promoted coupling of acetylenes held proximate to a metal
  作者：Thitima Rukachaisirikul、Samir Arabi、Fred Hartstock、Nicholas J. Taylor、Arthur J. Carty

  DOI：10.1021/om00088a023

  日期：1984.10
• Homo- and hetero-dinuclear complexes of palladium and platinum containing phosphinoacetylene and/or chloride as bridging ligands
  作者：Juan Forniés、Elena Lalinde、Antonio Martín、M. Teresa Moreno、Alan J. Welch

  DOI：10.1039/dt9950001333

  日期：——

  Reactions between the diphenylacetylenephosphine complexes cis-[M'Cl-2(PPh(2)C=CR)(2)] (M' = Pt or Pd, R = Ph or Bu(t)) and cis-[M(C6F5)(2)(thf)(2)] (M = Pt or Pd; thf = tetrahydrofuran) in a 1:1 molar ratio have been studied. Three types of products have been obtained: (a) asymmetric homo- and hetero-dinuclear complexes gem-[(C6F5)(2)M(mu-Cl)(2)M'(PPh(2)C=CR)(2)], (b) symmetric trans-palladium derivatives [Pd(mu-Cl)(C6F5)(PPh(2)C=CR)}(2)] and (c) the unusual chloride and diphenyl (phenylethynyl) phosphine bridged dinuclear compounds [(C6F5)(2)Pt(mu-Cl)(mu-PPh(2)C=CPh)M'Cl(PPh(2)C=CPh)]. The complexes have been characterised by microanalysis. IR and NMR spectroscopy and the molecular structure of [(C6F5)(2)Pt(mu-Cl)(mu-PPh(2)C=CPh)PtCl(PPh(2)C=CPh)]. OC4H8. The NMR spectral data (H-1, F-19 and P-31) indicate that, in solution, mixtures of isomers [(C6F5)(2)Pt(mu-Cl)(2)M'(PPh(2)C=CR)(2)] and [(C6F5)(2)Pt(mu-Cl)(mu-PPh(2)C=CPh)M'Cl(PPh(2)C=CPh)] are present.
• RUKACHAIISIRIKUI, THITIMA;ARABL, SAMIR;HARTSTOCK, F.;TAYLOR, N. J.;CARTY,+, ORGANOMETALLICS, 1984, 3, N 10, 1587-1589
  作者：RUKACHAIISIRIKUI, THITIMA、ARABL, SAMIR、HARTSTOCK, F.、TAYLOR, N. J.、CARTY,+

  DOI：——

  日期：——