[PtI(C6H3(CH2N(CH3)2)2-o,o')] | 82112-97-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [PtI(C6H3(CH2N(CH3)2)2-o,o')]
• 英文别名: [2,6-Bis[(dimethylamino)methyl]phenyl]iodoplatinum；1-[3-[(dimethylamino)methyl]benzene-2-id-1-yl]-N,N-dimethylmethanamine;iodoplatinum(1+)
• CAS: 82112-97-8
• 化学式: C₁₂H₁₉IN₂Pt
• 分子量: 513.281
• InChiKey: ZOYZVDGRUYVLIQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.49
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  [PtI(C6H3(CH2N(CH3)2)2-o,o')] 在 CH₃Br 作用下， 以 丙酮 为溶剂， 生成 [PtBr(C6H3(CH2N(CH3)2)2-o,o')]
  参考文献：
  名称：

  1,2-Methyl shift between platinum and the coordinated aryl group in the reaction of methyl iodide with 2,6-bis[(dimethylamino)methyl]phenyl-N,N',C complexes of platinum(II). X-ray crystal structure of the arenonium-platinum compound [Pt(o-tolyl)(MeC6H3(CH2NMe2)2-o,o')]I

  摘要：

  DOI：

  10.1021/ja00296a010
• 作为产物：
  描述：

  [PtBr(C6H3(CH2N(CH3)2)2-o,o')] 在 CH₃I 作用下， 以 丙酮 为溶剂， 以84%的产率得到[PtI(C6H3(CH2N(CH3)2)2-o,o')]
  参考文献：
  名称：

  1,2-Methyl shift between platinum and the coordinated aryl group in the reaction of methyl iodide with 2,6-bis[(dimethylamino)methyl]phenyl-N,N',C complexes of platinum(II). X-ray crystal structure of the arenonium-platinum compound [Pt(o-tolyl)(MeC6H3(CH2NMe2)2-o,o')]I

  摘要：

  DOI：

  10.1021/ja00296a010

文献信息

• Self-assembled organoplatinum(II) supermolecules as crystalline, SO2 gas-triggered switches †
  作者：Martin Albrecht、Martin Lutz、Antoine M. M. Schreurs、Egbert T. H. Lutz、Anthony L. Spek、Gerard van Koten

  DOI：10.1039/b006419j

  日期：——

  Square-planar platinum(II) complexes containing N,C,N terdentate coordinating, anionic ‘pincer’ ligands reversibly bind gaseous SO2 in the solid state by Pt–S bond formation and cleavage giving five-coordinate adducts. When the starting material is crystalline, exposure to this gas leads to quantitative adduct formation with the unique feature that the product is also crystalline, although the crystal structures of the adduct and the SO2 free complex are significantly different from each other and are both non-porous. Remarkably, the reverse reaction, i.e. the release of SO2 gas, modifies but does not destroy the crystalline ordering in the arylplatinum assemblies. These processes include repetitive expansion and reduction of the crystal lattice without any loss of crystallinity of the material. Variation of the ligand framework revealed that the presence of intermolecular interactions such as α- or β-type networks is not an essential prerequisite for these crystalline transformations. Consequently, this class of supermolecules provides access to sensitive crystalline switches with ‘on’ and ‘off’ positions which are a direct response to the gaseous environment.

  包含N,C,N三齿配位阴离子“铂夹”配体的平面正方形铂(II)配合物在固态下通过形成和断裂Pt–S键可逆地与气态SO2结合，形成五配位加合物。当起始材料为晶体时，暴露于这种气体会导致定量加合物的形成，其独特之处在于产物也是晶体，尽管加合物和无SO2的配合物的晶体结构之间存在显著差异，而且两者均为非多孔材料。值得注意的是，逆反应，即SO2气体的释放，改变但不破坏芳基铂组装体中的晶体排序。这些过程包括晶体晶格的重复膨胀和收缩，而材料的结晶性未受到损失。配体框架的变化显示，分子间相互作用如α型或β型网络并不是这些晶体转变的必要前提。因此，这类超分子为敏感的晶体开关提供了访问，具有“开”和“关”位置，能够直接响应气体环境。
• Carbon−Oxygen Bond Formation at Metal(IV) Centers:  Reactivity of Palladium(II) and Platinum(II) Complexes of the [2,6-(Dimethylaminomethyl)phenyl-<i>N</i>,<i>C</i>,<i>N</i>]^- (Pincer) Ligand toward Iodomethane and Dibenzoyl Peroxide; Structural Studies of M(II) and M(IV) Complexes
  作者：Allan J. Canty、Melanie C. Denney、Gerard van Koten、Brian W. Skelton、Allan H. White

  DOI：10.1021/om040061w

  日期：2004.11.1

  6-(dimethylaminomethyl)phenyl-N,C,N]- (pincer) ligand (NCN) in platinum(II) complexes has been used to generate stable organoplatinum(IV) complexes that model possible intermediates and reactivity in metal-catalyzed C−O bond formation processes. The complexes M(O2CPh)(NCN) [M = Pd (1), Pt (2)] were obtained by metathesis reactions from the chloro analogues, and although 1 does not react with dibenzoyl

  铂（II）配合物中[2,6-（二甲基氨基甲基）苯基-N，C，N ] -（钳）配体（NCN）的存在已用于生成稳定的有机铂（IV）配合物，该配合物可模拟可能的中间体和金属催化的C-O键形成过程中的反应性。络合物M（O 2 CPh）（NCN）[M = Pd（1），Pt（2）]是通过氯类似物的复分解反应获得的，尽管1不与过氧化二苯甲酰反应，但2确实形成了Pt。 （O 2 CPh）3（NCN）（3）作为模型中间体，用于在乙酸钯（II）和氧化剂存在下用乙酸将芳烃乙酰氧基化。复合物Pt（O 2 CPh）（NCN）（2）与碘甲烷以复杂方式反应形成PtI（NCN）（6）和顺式-Pt（O 2 CPh）2 Me（NCN）（7）。络合物7可能分解成Pt（O 2 CPh）（NCN）（2）和MeO 2 CPh，可能是通过苯甲酸酯解离，然后通过Pt IV -Me碳原子上的苯甲酸酯离子进行亲核攻击。Pd（II）类似物Pd（O
• Syntheses and characterization of dinuclear palladium and platinum complexes with a single unsupported bridging group. Crystal structure of [{C₆H₃(CH₂NMe₂)₂-o,o′}Pd(µ-Cl)Pd{C₆H₃(CH₂NMe₂)₂-o,o′}]BF₄
  作者：Jos Terheijden、Gerard van Koten、David M. Grove、Kees Vrieze、Anthony L. Spek

  DOI：10.1039/dt9870001359

  日期：——

  cationic [MC6H3(CH2NMe2)2-o,o′}(H2O)n]Y (M = Pd or Pt; n= 1, Y = BF4; M = Pt, n= 0, Y = O3SCF3) with neutral [MXC6H3(CH2NMe2)2-o,o′}](M = Pd or Pt; X = halide or CN) gives novel homo- and hetero-dinuclear complexes possessing a single unsupported halide or cyanide bridge. The complexes have been characterized by i.r., 1H n.m.r., and elemental analyses. A single-crystal X-ray structure determination

  阳离子[M C 6 H 3（CH 2 NMe 2）2 - o，o '}（H 2 O）n ] Y [Y = Md（Pd或Pt；n = 1，Y = BF 4； M = Pt ，n = 0，Y = O 3 SCF 3），中性[MX C 6 H 3（CH 2 NMe 2）2 - o，o'']]（M = Pd或Pt； X =卤化物或CN）给出了具有单个不支持的卤化物或氰化物桥的新型同核和杂核复合物。通过ir，1 H nmr和元素分析对复合物进行了表征。单晶X射线结构测定已经在钯物种进行[C 6 H ^ 3（CH 2 NME 2）2 - Ö，Ö '的Pd（μ-Cl）的钯C 6 H ^ 3（CH 2 NMe 2）2 - o，o '}] BF 4 [ a= 11.163（1），b = 21.347（2），c = 12.246（4）Å，β= 91.48（2）°，Z = 4；对于5 077次反射，R =
• Bis-<i>o</i><i>rtho</i>-chelated Diaminoaryl Platinum Compounds with σ-Acetylene Substituents. Investigations into Their Stability and Subsequent Construction of Multimetallic Systems. The Crystal Structure of [(μ²-[(η²-NCN)Pt(η¹-CO)C⋮CSiMe₃])Co₂(CO)₆] (NCN = 2,6-Bis[(dimethylamino)methyl]phenyl)
  作者：Stephan Back、Robert A. Gossage、Martin Lutz、Ignacio del Río、Anthony L. Spek、Heinrich Lang、Gerard van Koten

  DOI：10.1021/om000272a

  日期：2000.8.1

  bond, yielding a metal center with four different ligand donor atoms. Attempts to obtain related Pt(IV) acetylides by reaction of 2 with CuCl2 resulted in the formation of Pt}Cl3, [CuX]n, and [CuC⋮CSiMe3]n. The reaction with I2 gave neither a Pt(IV) diiodide nor a Pt(II) η1−Ι2 complex, but instead led to Pt−C(acetylide) bond cleavage and formation of Pt}I and IC⋮CSiMe3. The reaction of Pt}C⋮CC6H4CN-4

  一系列相关σ铂-乙炔化物的铂}℃⋮CR（铂} = [PT（C 6 H ^ 3 我2 NCH 2 } 2 -2,6）] +）由锂乙炔化物与以下物质反应制备 PT} Cl（1）为了研究PT-乙炔σ键的稳定性及其在包含PT}“钳”单元的多金属化合物组装中的可能应用。这可以通过η来实现2的乙炔化-coordination或通过在乙炔化阴离子结合有第二配位位点。这两种方法都在本文中进行了演示。使PT} C⋮CSiMe 3（2）与[M] [BF 4]（[M] = [Cu（NCMe）4 ]，Ag）和不同形式的卤化Cu（I）。只有前者才能观察到稳定的π配位的M（I）化合物的形成。[（η 2 - [铂}℃⋮CSiMe 3 ] 2）的Cu] [BF 4 ]表现出η 2既炔单元到正式的Cu（I）金属中心的-coordination，由此形成heterotrimetallic化合物。在存在卤离子的情
• Comparative Rates of Ligand Substitution Reactions of Pt−C-Bonded Complexes in Aqueous Solution and the X-ray Crystal Structure of [Pt{C₆H₃(CH₂NMe₂)₂-2,6}(OH₂)][OSO₂CF₃]
  作者：Michael Schmülling、David M. Grove、Gerard van Koten、Rudi van Eldik、Nora Veldman、A. L. Spek

  DOI：10.1021/om950474k

  日期：1996.3.5

  nucleophiles. The mechanism for the substitution of the coordinated water molecule is associative, as demonstrated by the large negative values of ΔS⧧ and ΔV⧧. The results are compared to those obtained earlier for the geometrically related neutral zwitterionic complex [PtC6H4(CH2NMe2)-2}(NC5H4SO3-3)(OH2)] (2). Both cyclometalated complexes 1 and 2 have very high substitution reactivities that can be ascribed

  有机金属配合物阳离子的取代行为[PT C 6 H ^ 3（CH 2 NME 2）2 -2,6}（OH 2）] +（1）已被研究了一系列亲核试剂（CL的- ，溴-我-，N 3 -，NCS - ，硫脲，N，N- '-dimethylthiourea，N，N，N- ' ñ “-tetramethylthiourea）作为亲核试剂浓度（[女]），pH值，温度和压力的函数。复数1提供伪一阶速率常数kobs，对于由k obs = k 1 [Nu] + k - 1给出的络合物形成反应；所述ķ - 1项是由于反向水合作反应和不显着的强，S-供体亲核体。用于协调水分子的取代的机制是结合的，通过Δ的大的负的值作为证明小号⧧和Δ V ⧧。将结果与早先获得的与几何相关的中性两性离子络合物[PT C 6 H 4（CH 2 NMe 2）-2}（NC5 H 4 SO 3 -3）（OH 2）]（2）。环金属化的配合物