2-Methylene-malonic acid diisobutyl ester | 116280-15-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-Methylene-malonic acid diisobutyl ester
• 英文别名: Bis(2-methylpropyl) 2-methylidenepropanedioate
• CAS: 116280-15-0
• 化学式: C₁₂H₂₀O₄
• 分子量: 228.288
• InChiKey: GBEGIAPIORNUEN-UHFFFAOYSA-N

物化性质

• 沸点：
  64-65 °C(Press: 0.02 Torr)
• 密度：
  0.995±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  bis(2-methylpropyl) tetracyclo[6.6.2.02,7.09,14]hexadeca-2,4,6,9,11,13-hexaene-15,15-dicarboxylate 在 马来酸酐 作用下， 以 paraffin 为溶剂， 反应 0.75h， 以61%的产率得到2-Methylene-malonic acid diisobutyl ester
  参考文献：
  名称：

  A versatile and convenient multigram synthesis of methylidenemalonic acid diesters

  摘要：

  DOI：

  10.1021/jo00255a038

文献信息

• 3D-PRINTING METHOD USING GAS-ACTIVATED CYANOACRYLATES
  申请人：Henkel AG & Co. KGaA

  公开号：EP3708370A1

  公开（公告）日：2020-09-16

  Method for fabricating a three-dimensional object by dispensing an anionically polymerisable material and contacting with an activator in gaseous form.

  通过分配阴离子可聚合材料并与气态活化剂接触来制造三维物体的方法。
• Process for producing ethylene oligomers
  申请人：HANWHA TOTAL PETROCHEMICAL CO., LTD.

  公开号：US10308563B2

  公开（公告）日：2019-06-04

  The present disclosure relates to a process for producing ethylene oligomers and more particularly, to a process for oligomerizing ethylene by recycling butene, hexene, and octene in an ethylene oligomerization reaction with a catalyst system including a transition metal or transition metal precursor, a ligand with a backbone structure expressed by the following Chemical Formula 1, and a co-catalyst. [Chemical Formula 1] R1—O—Y—O—R2 or R1—OC(═O)—Y—C(═O)OR2 Herein, R1, R2 are each independently hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl, or substituted heterohydrocarbyl, and Y represents a group connecting O or C(═O)O and is hydrocarbyl, substituted hydrocarbyl, hetero hydrocarbyl, or substituted heterohydrocarbyl. According to the oligomerization method of the present disclosure, in the distribution of the produced α-olefins, C10″-C12″ α-olefins care highly distributed, the produced α-olefins have a remarkably high purity.

  本公开涉及一种生产乙烯低聚物的工艺，更具体地说，涉及一种通过在乙烯低聚反应中回收丁烯、己烯和辛烯而使乙烯低聚的工艺，该催化剂体系包括过渡金属或过渡金属前体、具有以下化学式1表示的骨架结构的配位体和助催化剂。[化学式 1] R1-O-Y-O-R2 或 R1-OC(═O)-Y-C(═O)OR2 这里，R1、R2 各自独立地为烃基、取代的烃基、杂烃基或取代的杂烃基，Y 代表连接 O 或 C(═O)O 的基团，并且是烃基、取代的烃基、杂烃基或取代的杂烃基。根据本公开的低聚方法，在生成的α-烯烃的分布中，C10″-C12″ α-烯烃的分布较多，生成的α-烯烃具有显著的高纯度。
• DE, KEYSER JEAN-LUC;DE, COCK CHRISTIAN J. C.;POUPAERT, JACQUES H.;DUMONT,+, J. ORG. CHEM., 53,(1988) N 20, C. 4859-4862
  作者：DE, KEYSER JEAN-LUC、DE, COCK CHRISTIAN J. C.、POUPAERT, JACQUES H.、DUMONT,+

  DOI：——

  日期：——
• PROCESS FOR PRODUCING ETHYLENE OLIGOMERS
  申请人：HANWHA TOTAL PETROCHEMICAL CO., LTD.

  公开号：US20180170827A1

  公开（公告）日：2018-06-21

  The present disclosure relates to a process for producing ethylene oligomers and more particularly, to a process for oligomerizing ethylene by recycling butene, hexene, and octene in an ethylene oligomerization reaction with a catalyst system including a transition metal or transition metal precursor, a ligand with a backbone structure expressed by the following Chemical Formula 1, and a co-catalyst. [Chemical Formula 1] R 1 —O—Y—O—R 2 or R 1 —OC(═O)—Y—C(═O)OR 2 Herein, R 1 , R 2 are each independently hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl, or substituted heterohydrocarbyl, and Y represents a group connecting O or C(═O)O and is hydrocarbyl, substituted hydrocarbyl, hetero hydrocarbyl, or substituted heterohydrocarbyl. According to the oligomerization method of the present disclosure, in the distribution of the produced α-olefins, C10″-C12″ α-olefins care highly distributed, the produced α-olefins have a remarkably high purity.
• CATALYST SYSTEM FOR ETHYLENE OLIGOMERIZATION AND METHOD FOR PRODUCING ETHYLENE OLIGOMERIZATION USING THE SAME
  申请人：HANWHA TOTAL PETROCHEMICAL CO., LTD.

  公开号：US20180169642A1

  公开（公告）日：2018-06-21

  The present disclosure relates to a catalyst system for ethylene oligomerization and a method for producing ethylene oligomerization using the same and more particularly, to a catalyst system for ethylene oligomerization including a transition metal or transition metal precursor with a new structure, a ligand with a backbone structure expressed by the following Chemical Formula 1 or Chemical Formula 2, and a co-catalyst for providing an ethylene oligomer and a method for producing ethylene oligomerization using the same. [Chemical Formula 1] R 1 —OC(═O)—Y 1 —C(═O)OR 2 Herein, R 1 , R 2 are each independently hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl, or substituted heterohydrocarbyl, and Y 1 represents a group connecting CO(═O). [Chemical Formula 2] R 1 —O—Y 2 —O—R 2 Herein, R 1 , R 2 are each independently hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl, or substituted heterohydrocarbyl, and Y 2 represents a group connecting O and is a linear, branched, or cyclic alkyl group having 3 or more carbon atoms, or hetero hydrocarbyl, or substituted heterohydrocarbyl. The catalyst system of the present disclosure has an excellent catalytic activity and in the distribution of the produced α-olefins, C8″-C18″ α-olefins are highly distributed.