tert-butyl N-(2-phenylanilino)carbamate | 155347-58-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tert-butyl N-(2-phenylanilino)carbamate
• CAS: 155347-58-3
• 化学式: C₁₇H₂₀N₂O₂
• 分子量: 284.358
• InChiKey: AUHCNXIQRJAPCT-UHFFFAOYSA-N

物化性质

• 密度：
  1.125±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  21
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  50.4
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  tert-butyl N-(2-phenylanilino)carbamate 在 palladium on activated charcoal 作用下， 以 甲苯 为溶剂， 反应 4.0h， 以92%的产率得到tert-butyl N-(2-phenylphenyl)iminocarbamate
  参考文献：
  名称：

  Synthesis and miticidal activity of o-biphenyldiazenecarboxylates.

  摘要：

  Nine o-biphenyldiazenecarboxylates were obtained in excellent yields by the air oxidation of o-biphenylhydrazinecarboxylates, catalyzed by palladium on charcoal. The miticidal activity of the new compounds was evaluated against Tetranychus urticae. Structure-activity relationships for the screened compounds are discussed. Some of the compounds displayed greater activity than did the commercial miticide propargite.

  DOI：

  10.1021/jf00054a055
• 作为产物：
  描述：

  2-氨基联苯 在 吡啶 、 盐酸 、 tin(ll) chloride 、 sodium nitrite 作用下， 生成 tert-butyl N-(2-phenylanilino)carbamate
  参考文献：
  名称：

  Synthesis and miticidal activity of o-biphenyldiazenecarboxylates.

  摘要：

  Nine o-biphenyldiazenecarboxylates were obtained in excellent yields by the air oxidation of o-biphenylhydrazinecarboxylates, catalyzed by palladium on charcoal. The miticidal activity of the new compounds was evaluated against Tetranychus urticae. Structure-activity relationships for the screened compounds are discussed. Some of the compounds displayed greater activity than did the commercial miticide propargite.

  DOI：

  10.1021/jf00054a055

文献信息

• Synthesis and Miticidal and Insecticidal Activities of Biphenylhydrazinecarboxylates
  作者：Mark A. Dekeyser、Paul T. McDonald、Gilbert W. Jr. Angle

  DOI：10.1021/jf00042a022

  日期：1994.6

  Ten biphenylhydrazinecarboxylates were obtained by the condensation of o-biphenylhydrazine with alkyl chloroformates. The miticidal and insecticidal activities of the new compounds were evaluated against Tetranychus urticae and Sogatodes orizicola. Structure-activity relationships for the screened compounds are discussed. Some of the compounds displayed greater activity than did the commercial standards, propargite and carbofuran.
• Synthesis and miticidal activity of o-biphenyldiazenecarboxylates.
  作者：Mark A. Dekeyser、Paul T. McDonald、Gilbert W. Angle

  DOI：10.1021/jf00054a055

  日期：1995.6

  Nine o-biphenyldiazenecarboxylates were obtained in excellent yields by the air oxidation of o-biphenylhydrazinecarboxylates, catalyzed by palladium on charcoal. The miticidal activity of the new compounds was evaluated against Tetranychus urticae. Structure-activity relationships for the screened compounds are discussed. Some of the compounds displayed greater activity than did the commercial miticide propargite.