2,6-二甲基-4-乙烯基吡啶 | 102547-79-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 2,6-二甲基-4-乙烯基吡啶
• 英文名称: 2,6-dimethyl-4-vinyl-pyridine
• 英文别名: 2,6-Dimethyl-4-vinyl-pyridin；4-Ethenyl-2,6-dimethylpyridine
• CAS: 102547-79-5
• 化学式: C₉H₁₁N
• 分子量: 133.193
• InChiKey: AHTKGFIYHBHGAM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,6-二甲基-4-乙烯基吡啶 、 (1,3-dimethylimidazol-2-ylidene)borane 在 tetrakis(tetrabutylammonium)decatungstate(VI) 、 三苯甲硫醇 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 以48 %的产率得到
  参考文献：
  名称：

  N-杂环卡宾硼烷通过硼中心自由基的选择性多功能化

  摘要：

  通过十钨酸盐和硫醇的协同催化，实现了N-杂环卡宾（NHC）硼烷与烯烃的选择性双官能化。该催化系统还允许逐步三官能化，从而产生具有三个不同官能团的复杂 NHC 硼烷，这对于通过其他方法制备具有挑战性。激发态十钨酸盐的强吸氢能力使得单取代和双取代硼烷产生硼基自由基，从而实现硼烷多功能化。这项原理验证研究为制造不对称硼烷和开发硼原子经济合成提供了新的机会。

  DOI：

  10.1039/d3sc01132a
• 作为产物：
  描述：

  2,4,6-三甲基吡啶 在 sodium hydroxide 、 水 作用下， 生成 2,6-二甲基-4-乙烯基吡啶
  参考文献：
  名称：

  Lukes; Galik, Collection of Czechoslovak Chemical Communications, 1958, vol. 23, p. 1083,1087

  摘要：

  DOI：

文献信息

• [EN] ALKYL PYRROLOPYRIMIDINE ANALOGS AND METHODS OF MAKING AND USING SAME<br/>[FR] ANALOGUES D'ALKYLE PYRROLOPYRIMIDINE ET LEURS PROCÉDÉS DE PRÉPARATION ET D'UTILISATION
  申请人：UNIV NORTH CAROLINA CHAPEL HILL

  公开号：WO2018094227A1

  公开（公告）日：2018-05-24

  The present disclosure is concerned with benzo annulene compounds that are capable of inhibiting a Mer tyrosine kinase and/or a Tyro3 tyrosine kinase and methods of treating a bacterial infection, a viral infection, and/or a disorder of uncontrolled cellular proliferation such as, for example, a cancer, using these compounds. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

  本公开涉及能够抑制Mer酪氨酸激酶和/或Tyro3酪氨酸激酶的苯并环戊二烯化合物，以及使用这些化合物治疗细菌感染、病毒感染和/或细胞不受控制增殖的疾病，例如癌症的方法。本摘要旨在作为在特定领域搜索的扫描工具，并不意在限制本发明。
• Radiation-sensitive compositions of polymers containing a pi-metal carbonyl complex of conjugated polyolefin
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0095269A2

  公开（公告）日：1983-11-30

  Radiation-sensitive polymeric compositions containing metal-carbonyl complexes and the cured insoluble crosslinked resin produced therefrom are disclosed. When coated as a layer on a substrate, the composition is useful as an element in the graphic arts.

  本发明公开了含有金属-羰基络合物的辐射敏感聚合物组合物以及由此产生的固化不溶性交联树脂。当该组合物作为一层涂覆在基材上时，可用作图形艺术中的元素。
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2383814A1

  公开（公告）日：2011-11-02

  An organic electroluminescent device in which an organic layer containing a metal coordination compound represented by the following formula (1) is sandwiched between the pair of electrodes composed of an anode and a cathode,         MLaXb     (1) wherein M is an ion of a metal of Group 11 of the Periodic Table, L is a ligand represented by the formula (2) shown below, X is an anion, and a and b are defined in the specification, wherein A is a divalent group formed by removing two hydrogen atoms from the formula (3) or (4) shown below, and D1, k1, m1, A, D1, Q1, and Q2 are defined in the specification, wherein X1, X2, X3, X4, X5, R1, R5, R6, and R9 are defined in the specification.

  一种有机电致发光装置，在由阳极和阴极组成的一对电极之间夹有一个含有下式（1）所代表的金属配位化合物的有机层、 MLaXb (1) 其中 M 是元素周期表第 11 族金属的离子，L 是由下式（2）表示的配位体，X 是阴离子，a 和 b 在说明书中定义、 其中 A 是通过从下式（3）或（4）中去除两个氢原子而形成的二价基团，D1、k1、m1、A、D1、Q1 和 Q2 的定义见说明书、 其中 X1、X2、X3、X4、X5、R1、R5、R6 和 R9 的定义见说明书。
• Polymers, methods for preparing same, and uses thereof particularly for metal capture
  申请人：UNIVERSITE PARIS-SACLAY

  公开号：US11332566B2

  公开（公告）日：2022-05-17

  Disclosed are novel polymers that contain monomer units derived from 4-vinylpyridine and monomer units derived from a co-monomer. The polymers may be complexed with a metal, and linear or crosslinked. Also disclosed are methods for preparing these polymers by radical polymerization, as well as to their use for metal capture in aqueous media, particularly uranium capture in seawater or in final nuclear waste from nuclear power plants.

  所公开的新型聚合物含有源自 4-乙烯基吡啶的单体单元和源自共聚单体的单体单元。这些聚合物可与金属络合，也可线性或交联。还公开了通过自由基聚合制备这些聚合物的方法，以及它们在水介质中的金属捕获用途，特别是海水中的铀捕获或核电厂最终核废料中的铀捕获。
• NOVEL POLYMERS, METHODS FOR PREPARING SAME, AND USES THEREOF PARTICULARLY FOR METAL CAPTURE
  申请人：UNIVERSITE PARIS-SACLAY

  公开号：US20200231729A1

  公开（公告）日：2020-07-23

  Disclosed are novel polymers that contain monomer units derived from 4-vinylpyridine and monomer units derived from a co-monomer. The polymers may be complexed with a metal, and linear or crosslinked. Also disclosed are methods for preparing these polymers by radical polymerization, as well as to their use for metal capture in aqueous media, particularly uranium capture in seawater or in final nuclear waste from nuclear power plants.