4-N,6-N-bis(3-aminophenyl)-2-N-methyl-2-N-phenyl-1,3,5-triazine-2,4,6-triamine | 47661-75-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-N,6-N-bis(3-aminophenyl)-2-N-methyl-2-N-phenyl-1,3,5-triazine-2,4,6-triamine
• CAS: 47661-75-6
• 化学式: C₂₂H₂₂N₈
• 分子量: 398.47
• InChiKey: CFWALLPDFJZRJS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  118
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  4-N,6-N-bis(3-aminophenyl)-2-N-methyl-2-N-phenyl-1,3,5-triazine-2,4,6-triamine 、 bis-(4,6-dichloro-[1,3,5]triazin-2-yl)-p-tolyl-amine 在 potassium carbonate 作用下， 以 丙酮 为溶剂， 反应 1.5h， 以41%的产率得到11,17-Dichlor-29-(N-methyl-N-phenyl)amino-14-(p-tolyl)-2,8,10,12,14,16,18,20,26,28,30,31,33,34-tetradecaazahexacyclo[25.3.1.1^3,7.1^9,13.1^15,19.1^21,25]pentatriaconta-1(31),3,5,7(35),9,11,13(34),15,17,19(33),21,23,25(32),27,29-pentadecaene
  参考文献：
  名称：

  Polyazacalix[5]arene - Synthese und NMR-Untersuchungen

  摘要：

  The polyazacalix[5]arenes 5a-f were easily prepared by cyclisation of cyanuric chloride derivatives 3a-d und 4a-b. These macrocycles contain two phenylene and three 1,3,5-triazine units. The derivatisation of reactive chlorine-containing macrocycles 5 with amines, diamines and methanol gave compounds 6a-e. The structures and conformations of these novel macrocyclic ring systems have been investigated by various NMR methods.

  DOI：

  10.1002/prac.19973390147
• 作为产物：
  描述：

  2,6-dichloro-4-N-methyl-phenylamino-1,3,5-triazine 、 间苯二胺 在 sodium carbonate 作用下， 以 1,4-二氧六环 为溶剂， 以82%的产率得到4-N,6-N-bis(3-aminophenyl)-2-N-methyl-2-N-phenyl-1,3,5-triazine-2,4,6-triamine
  参考文献：
  名称：

  Polyazacalix[5]arene - Synthese und NMR-Untersuchungen

  摘要：

  The polyazacalix[5]arenes 5a-f were easily prepared by cyclisation of cyanuric chloride derivatives 3a-d und 4a-b. These macrocycles contain two phenylene and three 1,3,5-triazine units. The derivatisation of reactive chlorine-containing macrocycles 5 with amines, diamines and methanol gave compounds 6a-e. The structures and conformations of these novel macrocyclic ring systems have been investigated by various NMR methods.

  DOI：

  10.1002/prac.19973390147

文献信息

• Polyimide precursor, polyimide, varnish, polyimide film, and substrate
  申请人：Ube Industries, Ltd.

  公开号：US10174166B2

  公开（公告）日：2019-01-08

  A polyimide precursor comprising a repeating unit represented by the following chemical formula (1): in which A is a divalent group of an aromatic diamine or an aliphatic diamine, from which amino groups have been removed; and X1 and X2 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms, wherein the polyimide precursor comprises at least one type of repeating unit represented by the chemical formula (1) in which A is a group represented by chemical formula (2) or (3): in which m independently represents 0 to 3 and n independently represents 0 to 3; Y1, Y2 and Y3 each independently represent at least one selected from the group consisting of hydrogen atom, methyl group and trifluoromethyl group; and Q and R each independently represent direct bond, or at least one of —NHCO—, —CONH—, —COO— and —OCO—, in which Z and W each independently represent a divalent aromatic group having 6 to 18 carbon atoms; and Y4 represents hydrogen atom, or a monovalent organic group.

  一种聚酰亚胺前体，包含由以下化学式（1）表示的重复单元： 其中，A 是芳香族二胺或脂肪族二胺的二价基团，其中的氨基已被去除；X1 和 X2 各自独立地是氢、具有 1 至 6 个碳原子的烷基或具有 3 至 9 个碳原子的烷基硅基、 其中聚酰亚胺前体包括至少一种由化学式（1）表示的重复单元，其中 A 是由化学式（2）或（3）表示的基团： 其中 m 独立地代表 0 至 3，n 独立地代表 0 至 3；Y1、Y2 和 Y3 各自独立地代表至少一个选自氢原子、甲基和三氟甲基的基团；以及 Q 和 R 各自独立地代表直接键或 -NHCO-、-CONH-、-COO- 和 -OCO- 中的至少一种、 其中 Z 和 W 各自独立地代表具有 6 至 18 个碳原子的二价芳香基团；Y4 代表氢原子或一价有机基团。
• US20140255710A1
  申请人：——

  公开号：US20140255710A1

  公开（公告）日：2014-09-11
• POLYIMIDE PRECURSOR, POLYIMIDE, VARNISH, POLYIMIDE FILM, AND SUBSTRATE
  申请人：UBE INDUSTRIES, LTD.

  公开号：US20150361222A1

  公开（公告）日：2015-12-17

  A polyimide precursor comprising a repeating unit represented by the following chemical formula (1): in which A is a divalent group of an aromatic diamine or an aliphatic diamine, from which amino groups have been removed; and X 1 and X 2 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms, wherein the polyimide precursor comprises at least one type of repeating unit represented by the chemical formula (1) in which A is a group represented by chemical formula (2) or (3): in which m independently represents 0 to 3 and n independently represents 0 to 3; Y 1 , Y 2 and Y 3 each independently represent at least one selected from the group consisting of hydrogen atom, methyl group and trifluoromethyl group; and Q and R each independently represent direct bond, or at least one of —NHCO—, —CONH—, —COO— and —OCO—, in which Z and W each independently represent a divalent aromatic group having 6 to 18 carbon atoms; and Y 4 represents hydrogen atom, or a monovalent organic group.
• US3943107A
  申请人：——

  公开号：US3943107A

  公开（公告）日：1976-03-09
• US3944525A
  申请人：——

  公开号：US3944525A

  公开（公告）日：1976-03-16