5-methyl-2-phenyl-2-hexanol | 89444-36-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-methyl-2-phenyl-2-hexanol
• 英文别名: 5-methyl-2-phenylhexan-2-ol；methyl-isopentyl-phenyl-carbinol；1¹-Oxy-1-(1¹.1⁴-dimetho-pentyl)-benzol；ε-Oxy-β-methyl-ε-phenyl-hexan；Methyl-isoamyl-phenyl-carbinol
• CAS: 89444-36-0
• 化学式: C₁₃H₂₀O
• 分子量: 192.301
• InChiKey: OBKBBVYHPPETJT-UHFFFAOYSA-N

物化性质

• 沸点：
  135-137 °C(Press: 15 Torr)
• 密度：
  0.9608 g/cm3(Temp: 0 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  5-methyl-2-phenyl-2-hexanol 生成 2-methyl-5-phenylhexane
  参考文献：
  名称：

  Carbenes from Derivatives of Ethynylcarbinols. The Synthesis of Alkenylidenecyclopropanes¹

  摘要：

  DOI：

  10.1021/ja01485a025
• 作为产物：
  描述：

  magnesium,2-methylbutane,bromide 、 苯乙酮 以 乙醚 为溶剂， 以100%的产率得到5-methyl-2-phenyl-2-hexanol
  参考文献：
  名称：

  铜催化的有氧脂肪族 CH 与氢过氧化物的氧化。

  摘要：

  我们在此报告了铜催化的脂肪族 CH 键与氢过氧化物的有氧氧化，其通过源自氢过氧化物的假定氧中心自由基（O 自由基）的 1,5-H 自由基位移进行，然后捕获所得的碳中心自由基与分子氧。

  DOI：

  10.3762/bjoc.9.138

文献信息

• Convenient preparation of metals deposited on solid supports and their use in organic synthesis
  作者：Mieczyslaw Ma̧kosza、Piotr Nieczypor、Karol Grela

  DOI：10.1016/s0040-4020(98)00625-5

  日期：1998.9

  “High-surface alkali metals” can be conveniently prepared via deposition of corresponding metals on various supports such as sodium chloride, polyethylene, polypropylene and cross-linked polystyrene from their solutions in liquid ammonia. Alkali metals deposited on polymeric supports can be stored in form of stable suspensions in inert solvents and used for the acyloin and Dieckmann condensations and

  “高表面碱金属”可通过将相应的金属从其在液氨中的溶液沉积在各种载体（例如氯化钠，聚乙烯，聚丙烯和交联的聚苯乙烯）上而方便地制备。沉积在聚合物载体上的碱金属可以在惰性溶剂中以稳定的悬浮液形式存储，并用于酰基环和Dieckmann缩合反应以及有机锂的制备。将负载的碱金属的悬浮液添加到氯化锌溶液中，可以在聚合物载体上得到活性锌，可以将其用于Reformatski和Barbier反应。
• Hair Processing Agent And Method For Permanent Waving Hair
  申请人：Shibuya Akira

  公开号：US20080085251A1

  公开（公告）日：2008-04-10

  Provided are hair processing agents capable of permanent waving hair even at a neutral to weakly acidic pH range that causes less irritation to the skin, and hair processing agents in which an unpleasant odor is masked. Hair processing agents contain at least one compound represented by the formula (2). Hair processing agents contain a compound of the formula (2) and at least one compound (ii) selected from thioglycolic acid, thiolactic acid, cysteine, acetylcysteine, cysteamine, acylcysteamine, salts thereof and ester derivatives thereof. Hair processing agents contain a compound of the formula (2), a surfactant and water, and are emulsified. Hair processing agents contain a compound of the formula (2) and a specific perfume. wherein X is a structure selected from —O—, —S—, —NH— and —NR 1 —; R 1 is an alkyl group of 1 to 6 carbon atoms; Y is an oxygen atom or a sulfur atom; in the formula (1), Z is a divalent organic residue having at least one mercapto group; in the formula (2), R is a divalent organic residue optionally having a mercapto group; and R 2 is a hydrogen atom or an alkyl group of 1 to 6 carbon atoms.

  提供了能够在中性至微酸性pH范围内进行永久性卷发的头发处理剂，其对皮肤刺激较小，并且掩盖了不愉快的气味。头发处理剂包含至少一种由公式（2）表示的化合物。头发处理剂包含公式（2）的化合物和至少一种从巯基乙酸，巯基乳酸，半胱氨酸，乙酰半胱氨酸，半胱氨醇，酰基半胱氨醇，其盐和酯衍生物中选择的化合物（ii）。头发处理剂包含公式（2）的化合物，表面活性剂和水，并且是乳化的。头发处理剂包含公式（2）的化合物和特定香水。其中X是从-O-，-S-，-NH-和-NR1-选择的结构；R1是1到6个碳原子的烷基；Y是氧原子或硫原子；在公式（1）中，Z是具有至少一个巯基的二价有机残基；在公式（2）中，R是二价的有机残基，可选地具有巯基；R2是氢原子或1到6个碳原子的烷基。
• DEODORANT COMPOSITION
  申请人：Takasago International Corporation

  公开号：EP1561476A1

  公开（公告）日：2005-08-10

  It is intended to provide a novel deodorant composition which is excellent in the deodorizing effect, is capable of affording a deodorant composition by a convenient method, and shows no decrease in the deodorizing performance even after a long period of time, once the deodorant being prepared. Specifically, there is provided a deodorant composition containing, as the active component, a colored compound obtainable by reacting a polyphenol in a solvent showing alkalinity in the coexistence of an oxygen molecule at a reaction pH value of 6.5 or more. As a substitute for a polyphenol, use can be made of a plant extract containing a polyphenol but containing substantially no amino acid. It is also possible to further employ an amino acid. Furthermore, use can be made of a plant extract and/or a plant body containing a polyphenol and an amino acid.

  本发明旨在提供一种新型除臭剂组合物，该除臭剂组合物除臭效果极佳，能够通过简便的方法获得除臭剂组合物，并且在制备除臭剂后，即使经过很长时间，除臭效果也不会降低。具体来说，本发明提供了一种除臭剂组合物，该组合物含有一种有色化合物作为活性成分，该有色化合物可通过在反应 pH 值为 6.5 或更高时，使多酚在与氧分子共存的显碱性溶剂中发生反应而获得。作为多酚的替代品，可以使用含有多酚但基本上不含氨基酸的植物提取物。也可以进一步使用氨基酸。此外，还可以使用含有多酚和氨基酸的植物提取物和/或植物体。
• Deodorant composition
  申请人：Hiramoto Tadahiro

  公开号：US20060165622A1

  公开（公告）日：2006-07-27

  It is intended to provide a novel deodorant composition which is excellent in the deodorizing effect, is capable of affording a deodorant composition by a convenient method, and shows no decrease in the deodorizing performance even after a long period of time, once the deodorant being prepared. Specifically, there is provided a deodorant composition containing, as the active component, a colored compound obtainable by reacting a polyphenol in a solvent showing alkalinity in the coexistence of an oxygen molecule at a reaction pH value of 6.5 or more. As a substitute for a polyphenol, use can be made of a plant extract containing a polyphenol but containing substantially no amino acid. It is also possible to further employ an amino acid. Furthermore, use can be made of a plant extract and/or a plant body containing a polyphenol and an amino acid.

  本发明旨在提供一种新型除臭剂组合物，该除臭剂组合物除臭效果极佳，能够通过简便的方法获得除臭剂组合物，并且在制备除臭剂后，即使经过很长时间，除臭效果也不会降低。具体来说，本发明提供了一种除臭剂组合物，该组合物含有一种有色化合物作为活性成分，该有色化合物可通过在反应 pH 值为 6.5 或更高时，使多酚在与氧分子共存的显碱性溶剂中发生反应而获得。作为多酚的替代品，可以使用含有多酚但基本上不含氨基酸的植物提取物。也可以进一步使用氨基酸。此外，还可以使用含有多酚和氨基酸的植物提取物和/或植物体。
• Sodium- and Potassium-Catalyzed Reactions of Toluene, Ethylbenzene, and Isopropylbenzene with Isoprene^1,2
  作者：Herman Pines、Norman C. Sih

  DOI：10.1021/jo01012a067

  日期：1965.1