[4-(4-甲基苯氧基)苯基]-苯基甲酮 | 95523-77-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: [4-(4-甲基苯氧基)苯基]-苯基甲酮
• 英文名称: 4-p-tolyloxy-benzophenone
• 英文别名: 4-p-Tolyloxy-benzophenon；[4-(4-Methylphenoxy)phenyl](phenyl)methanone；[4-(4-methylphenoxy)phenyl]-phenylmethanone
• CAS: 95523-77-6
• 化学式: C₂₀H₁₆O₂
• 分子量: 288.346
• InChiKey: QLXLIQMODUNZBV-UHFFFAOYSA-N

物化性质

• 沸点：
  426.0±28.0 °C(Predicted)
• 密度：
  1.133±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-甲基二苯基醚 、 苯甲酰氯 在 二硫化碳 、 三氯化铝 作用下， 生成 [4-(4-甲基苯氧基)苯基]-苯基甲酮
  参考文献：
  名称：

  Dilthey et al., Journal fur praktische Chemie (Leipzig 1954), 1927, vol. <2>117, p. 359

  摘要：

  DOI：

文献信息

• Sulphonium Salt Initiators
  申请人：Wolf Jean-Pierre

  公开号：US20090208872A1

  公开（公告）日：2009-08-20

  Compounds of the formula (I), (II), (III), (IV) and wherein, R is hydrogen, C 1 -C 20 alkyl; C 2 -C 20 alkyl interrupted by one or more O; is -L-X—R 2 or -L-R 2 ; R 1 has for example one of the meanings as given for R; R 2 is a monovalent sensitizer or photoinitiator moiety; Ar 1 and Ar 2 for example independently of one another are phenyl substituted by C 1 -C 20 alkyl, halogen or OR 3 ; or are unsubstituted naphthyl, anthryl, phenanthryl or biphenylyl; or are naphthyl, anthryl, phenanthryl or biphenylyl substituted by C 1 -C 20 alkyl, OH or OR 3 ; or are —Ar 4 -A-Ar 3 ; Ar 3 is unsubstituted phenyl naphthyl, anthryl, phenanthryl or biphenylyl; or is phenyl, naphthyl, anthryl, phenanthryl or biphenylyl substituted by C 1 -C 20 alkyl, OR 3 or benzoyl; Ar 4 is phenylene, naphthylene, anthrylene or phenanthrylene; A is a direct bond, S, O or C 1 -C 20 alkylene; X is CO, C(O)O, OC(O), O, S or NR 3 ; L is C 1 -C 20 alkylene or C 2 -C 20 alkylene interrupted by one or more O; R 3 is C 1 -C 20 alkyl or C 1 -C 20 hydroxyalkyl; and Y is an anion, are suitable as photolatent acid generators.

  公式（I），（II），（III），（IV）的化合物，其中R是氢，C1-C20烷基; C2-C20烷基中断一个或多个O;为-L-X—R2或-L-R2; R1例如具有给定为R的含义之一; R2是单价敏化剂或光引发剂基团; Ar1和Ar2例如独立地是被C1-C20烷基，卤素或OR3取代的苯基;或未取代的萘基，蒽基，菲基或联苯基;或被C1-C20烷基，OH或OR3取代的萘基，蒽基，菲基或联苯基;或是-Ar4-A-Ar3; Ar3是未取代的苯基，萘基，蒽基，菲基或联苯基;或是被C1-C20烷基，OR3或苯甲酰取代的苯基，萘基，蒽基，菲基或联苯基; Ar4是苯撑，萘撑，蒽撑或菲撑; A是直接键，S，O或C1-C20烷基; X是CO，C（O）O，OC（O），O，S或NR3; L是C1-C20烷基或C2-C20烷基中断一个或多个O; R3是C1-C20烷基或C1-C20羟基烷基; Y是阴离子，适用作光潜酸发生剂。
• Ink composition and inkjet recording method
  申请人：FUJIFILM Corporation

  公开号：EP2302007A1

  公开（公告）日：2011-03-30

  An ink composition is provided that includes (A) a monofunctional monomer comprising an acrylate monomer represented by Formula (I) and (B) a photopolymerization initiator represented by Formula (II), the monofunctional monomer (A) having a content of 30 to 90 wt %. There is also provided an inkjet recording method that includes (a1) a step of discharging onto a recording medium the ink composition according to any one of Claims 1 to 11; and (b1) a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation.

  提供了一种墨水组合物，它包括(A)由式(I)表示的丙烯酸酯单体组成的单官能团单体和(B)由式(II)表示的光聚合引发剂，单官能团单体(A)的含量为30至90重量％。还提供了一种喷墨记录方法，它包括(a1)将根据权利要求 1 至 11 中任一项所述的墨水组合物排放到记录介质上的步骤；和(b1)通过用阳极辐射照射排放的墨水组合物来固化墨水组合物的步骤。
• Compound, photopolymerization initiator, photocurable composition and cured product thereof, and photocurable ink and print using the same
  申请人：DIC Corporation

  公开号：US11479569B2

  公开（公告）日：2022-10-25

  There are provided a compound represented by general formula (1), a photopolymerization initiator comprising this compound, a photocurable composition having this photopolymerization initiator and a photocurable compound as essential components, and a cured product formed by curing this photocurable composition, wherein in formula (1), R1 and R2 each independently represents an alkyl group or the like; R3 to R5 each independently represent a hydrogen atom, an alkyl group or the like; X1 represents a single bond or an alkylene group; and X2 represents a bonding group represented by general formulas (2) to (4), and wherein n represents an integer of 1 to 6, when n is an integer of 1, Y represents an alkyl group, an aryl group or the like.

  本发明提供了通式(1)表示的化合物、包含该化合物的光聚合引发剂、以该光聚合引发剂和光固化化合物为主要成分的光固化组合物，以及通过固化该光固化组合物形成的固化产物，其中在式(1)中，R1和R2各自独立地代表烷基或类似物；R3 至 R5 各自独立地代表氢原子、烷基或类似物；X1 代表单键或亚烷基；X2 代表通式（2）至（4）所代表的键合基团，其中 n 代表 1 至 6 的整数，当 n 为 1 的整数时，Y 代表烷基、芳基或类似物。
• SULPHONIUM SALT INITIATORS
  申请人：BASF SE

  公开号：EP1902019B1

  公开（公告）日：2010-07-07
• INK COMPOSITION AND INKJET RECORDING METHOD
  申请人：ARAKI Kenjiro

  公开号：US20110074897A1

  公开（公告）日：2011-03-31

  An ink composition is provided that includes (A) a monofunctional monomer comprising an acrylate monomer represented by Formula (I) and (B) a photopolymerization initiator represented by Formula (II), the monofunctional monomer (A) having a content of 30 to 90 wt %. There is also provided an inkjet recording method that includes (a 1 ) a step of discharging onto a recording medium the ink composition according to any one of Claims 1 to 11; and (b 1 ) a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation.