Methylphenylaminyloxid (Radikal) | 6146-29-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Methylphenylaminyloxid (Radikal)
• 英文别名: phenyl methyl nitroxide；N-Methyl-N-phenyl-N-oxid；N-Methylphenylnitroxid
• CAS: 6146-29-8
• 化学式: C₇H₈NO
• 分子量: 122.147
• InChiKey: OGGPWWVCWJIPBT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  4.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  Brenzcatechyl-phosphorigsaureester-N-methylanilid 在 叔丁基过氧化氢 作用下， 以 苯 为溶剂， 生成 Methylphenylaminyloxid (Radikal)
  参考文献：
  名称：

  Tkac, Alexander; Rueger, Claus; Schwetlick, Klaus, Collection of Czechoslovak Chemical Communications, 1980, vol. 45, # 4, p. 1182 - 1196

  摘要：

  DOI：

文献信息

• The photochemically induced oxidation of aniline by hydroperoxides: An electron paramagnetic resonance study. Part II.
  作者：Loris Grossi

  DOI：10.1016/s0040-4020(01)85525-3

  日期：——

  The oxidation reaction of aniline by tertiary hydroperoxides, induced photochemically, was studied. The peculiar radical intermediates, nitroxides and peroxy radicals, involved in the reaction mechanism were detected and identified by EPR spectroscopy. The presence of these intermediates confirm that PhNO is the first product of the oxidation of aniline and the PhNH· radical as its precursor.

  研究了光化学诱导的叔氢过氧化物对苯胺的氧化反应。通过EPR光谱法检测并鉴定了参与反应机理的特殊自由基中间体，氮氧化物和过氧自由基。这些中间体的存在证实了PhNO是苯胺和PhNH·自由基作为其前体氧化的第一产物。
• Radical transformations of some N-alkylanilines by their oxidation with different agents: an EPR study
  作者：Lenka Šafaříková、Ladislav Omelka、Petr Majzlík、Jan Světlík

  DOI：10.1007/s00706-012-0874-6

  日期：2013.2

  N-Alkylanilines X-NH-Ph (Ph = substituted phenyl ring) with two different types of alkyl substituent X [X = C2H5-CO-CH2CH(Ph), X = CH3, C2H5, CH(CH3)(2), CH2C6H5] were oxidized using different agents. While oxidation with 3-chloroperbenzoic acid leads to production of the corresponding aminoxyl radicals X-NOaEuro cent-Ph, it was confirmed that application of PbO2 resulted in the formation of aminyl radicals X-N-aEuro cent-Ph, as indirectly proved by the spin-trapping method. Contrary to those transformations, with employment of either Pb(OAc)(4) or t-BuO (2) (aEuro cent) radical, reactions taking place on the alkyl substituent were also observed.