1-十二烷基吡啶-1-鎓碘化物 | 3026-66-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 1-十二烷基吡啶-1-鎓碘化物
• 中文别名: 氯化[2-[乙基[3-甲基-4-[(3-苯基-1,2,4-噻二唑-5-基)偶氮]苯基]氨基]乙基]三甲基铵
• 英文名称: N-Dodecylpyridinium iodide
• 英文别名: 1-dodecylpyridinium iodide；1-dodecyl-pyridinium; iodide；1-Dodecyl-pyridinium; Jodid；Dodecylpyridinium iodide；1-dodecylpyridin-1-ium;iodide
• CAS: 3026-66-2
• 化学式: C₁₇H₃₀N*I
• 分子量: 375.336
• InChiKey: GZNACENTEXAZDR-UHFFFAOYSA-M

物化性质

• 熔点：
  93 °C

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  19
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  3.9
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2933399090

反应信息

• 作为反应物：
  描述：

  1-十二烷基吡啶-1-鎓碘化物 、 溴 以 氯仿 为溶剂， 生成 N-dodecylpyridinium iododibromide
  参考文献：
  名称：

  Electrolytes for Dye-Sensitized Solar Cells Based on Interhalogen Ionic Salts and Liquids

  摘要：

  In this paper, we report on the preparation of interhalogen ionic liquids of the general formula [K+]XY2-, where K+ = 1,3-dialkylimidazolium, 1,2,3-trialkylimidazolium, or N-alkylpyridinium; XY2- = IBr2- or I2Br-. These compounds were characterized in solution and the solid state by NMR, IR, Raman, and mass spectroscopy. The crystal structure of the compound [Me(2)BuIm]IBr2 (7) shows that the IBr2- anion has a linear Br-I-Br structure. Indications of an equilibrium between different forms of XY2- anions in solution are observed. Interhalogen ionic salts and liquids were used as electrolyte components for encapsulated monolithic dye-sensitized solar cells. Overall light-to-electricity conversion efficiencies up to 6.4%, 5.0%, and 2.4% at 1000 W/m(2) were achieved by using electrolytes based on interhalogen ionic salts and gamma-butyrolactone, glutaronitrile, or native ionic liquids as solvents, respectively. Moreover, in terms of stability, the cell performance lost 9-14% of the initial performance after 1000 h illumination at 350 W/m(2).

  DOI：

  10.1021/ic062244b
• 作为产物：
  描述：

  吡啶 、 1-碘十二烷 反应 3.0h， 生成 1-十二烷基吡啶-1-鎓碘化物
  参考文献：
  名称：

  Effect of Ionic Liquids with Different Cations in I^-/I₃^-Redox Electrolyte on the Performance of Dye-sensitized Solar Cells

  摘要：

  研究了添加具有四种不同阳离子（咪唑鎓、吡咯烷鎓、哌啶鎓和吡啶鎓）的离子液体对基于含有叔丁基吡啶（TBP）的3-甲氧基丙腈（MPN）电解质的染料敏化$TiO_2$太阳能电池性能的影响。本研究中共使用了18种单、二和三烷基衍生物的离子液体，其中具有单烷基的吡啶鎓阳离子显示出比其他离子液体更高的电池效率。使用1-己基吡啶碘化物获得了最佳的光电转换效率，为7.213%，其开路光电压（$V_{oc}$）= 0.731 V，短路光电流密度（$J_{sc}$）= 16.175 $mA/cm^2$，填充因子（ff）= 0.610，在AM1.5和100 $mW/cm^2$光照下。

  DOI：

  10.5012/bkcs.2011.32.6.2058

文献信息

• Activation of tetrabutylammonium hydrogen difluoride with pyridine: A mild and efficient procedure for nucleophilic fluorination
  作者：Khadija Moughamir、Aziz Atmani、Hélène Mestdagh、Christian Rolando、Charlette Francesch

  DOI：10.1016/s0040-4039(98)01564-0

  日期：1998.10

  The nucleophilic fluorination of alkyl iodides, bromides and tosylates and of α-bromo- or α-chloroketones is smoothly effected by tetrabutylammonium hydrogen difluoride in the presence of pyridine, in dioxane or THF, with good or satisfying substitution-to-elimination ratio.

  烷基碘，溴化物和甲苯磺酸盐以及α-溴代或α-氯代酮的亲核氟化反应在吡啶存在下，在二恶烷或THF中用四丁基铵二氟化氢以良好或令人满意的取代-消除比率平滑地进行。
• Very Facile Polarity Umpolung and Noncovalent Functionalization of Inorganic Nanoparticles: A Tool Kit for Supramolecular Materials Chemistry
  作者：Lukas Zeininger、Stefanie Petzi、Jörg Schönamsgruber、Luis Portilla、Marcus Halik、Andreas Hirsch

  DOI：10.1002/chem.201501682

  日期：2015.9.28

  form the outer second shell of [TiO2PAC16]@shell 1–7. The tailor‐designed dendritic building blocks 3–5 contain negative and positive charges in the same molecule, and ligands 6 and 7 contain a perylenetetracarboxylic acid dimide (PDI) core (6/7) as a photoactive reporter component. In the redox and photoactive system [TiO2PAC16]@shell 7, electronic communication between the inorganic core to the PDI

  的组件壳由壳（SBS）的容易的涂覆的纳米颗粒[二氧化钛2  PAC 16 ] @shell  1 - 7（PAC 16 =十六烷基膦酸），其可溶于水，并且可以分离为稳定的固体，则报告。在这些功能结构，分散性极性转换（有机非极性相对于水）通过非共价配体的结合来实现1 - 7至纳米二氧化钛[的TiO 2  PAC 16含有与PAC的第一共价涂层16。配体1 – 7是两亲性的，形成[TiO]的第二个外层壳2  PAC 16 ] @shell  1 - 7。裁缝设计的树枝状积木3 - 5含有在同一分子中的负电荷和正电荷，和配体6和7包含苝四羧酸dimide（PDI）芯（6 / 7），为光活性报告组分。在氧化还原和光活性体系[的TiO 2  PAC 16 ] @shell  7，观察到无机核心到PDI配体之间的电子通信。
• COMPOSITIONS AND VACCINES COMPRISING VESICLES AND METHODS OF USING THE SAME
  申请人：University of Maryland, College Park

  公开号：US20140356415A1

  公开（公告）日：2014-12-04

  The disclosure relates to compositions, pharmaceutical compositions, vaccines, and methods of making and using the same. The compositions of the disclosure are useful to stimulate an antigen-specific immune response and, in some embodiments, a protective immune response in an animal after challenge to pathogens. The compositions of the disclosure are also useful for treatment and prevention of disease in a subject such as cancer.

  本公开涉及组合物、制药组合物、疫苗以及制作和使用它们的方法。本公开所述的组合物可用于刺激动物的抗原特异性免疫反应，在某些实施例中，在动物受到病原体挑战后产生保护性免疫反应。本公开所述的组合物也可用于治疗和预防动物的疾病，例如癌症。
• Method for the formation of silica film, silica film, insulating film, and semiconductor device
  申请人：JSR Corporation

  公开号：EP1267395A2

  公开（公告）日：2002-12-18

  A method for the formation of a silica film which comprises treating a film in a supercritical medium, the film comprising (A) a siloxane compound and (B) at least one member selected from the group consisting of (B-1) a compound compatible with or dispersible in ingredient (A) and having a boiling or decomposition temperature of from 150 to 500°C and (B-2) a surfactant. The silica film has excellent mechanical strength showing a dielectric constant of generally 2.2 or lower, and hence is useful as a dielectric film in semiconductor devices and the like.

  一种形成二氧化硅薄膜的方法，包括在超临界介质中处理薄膜，该薄膜包括(A)硅氧烷化合物和(B)至少一种选自以下组别的成员：(B-1)与成分(A)相容或可分散在成分(A)中且沸腾或分解温度为 150 至 500°C 的化合物和(B-2)表面活性剂。二氧化硅薄膜具有优异的机械强度，介电常数一般为 2.2 或更低，因此可用作半导体设备等的介电薄膜。
• COMPOSITION AND METHOD FOR TEMPORARILY FIXING SOLID
  申请人：JSR Corporation

  公开号：EP1522567A1

  公开（公告）日：2005-04-13

  The present invention relates to a method of temporarily and firmly fixing two solids to each other and to a composition used in the method, which is a method of temporarily fixing, comprising temporarily fixing the two solids to each other with a liquid crystal compound or a composition comprising the liquid crystal compound. This method is used for a method of temporarily fixing a pad for chemical mechanical polishing, for example, to polish a wafer for a semiconductor device fixed on a surface of a base plate, when one solid is a pad for chemical mechanical polishing of a wafer for a semiconductor device and the other is a base plate to fix the pad.

  本发明涉及一种将两个固体暂时牢固地相互固定的方法以及用于该方法的组合物，该方法是一种暂时固定的方法，包括用液晶化合物或包含液晶化合物的组合物将两个固体暂时相互固定。该方法用于临时固定化学机械抛光垫的方法，例如，用于抛光固定在底板表面上的半导体器件晶片，其中一个固体是用于半导体器件晶片化学机械抛光的垫，另一个固体是用于固定垫的底板。