Acrylic acid 3-dimethylamino-phenyl ester | 4513-45-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: Acrylic acid 3-dimethylamino-phenyl ester
• 英文别名: [3-(Dimethylamino)phenyl] prop-2-enoate
• CAS: 4513-45-5
• 化学式: C₁₁H₁₃NO₂
• 分子量: 191.23
• InChiKey: MCUSVUGKVLTTBA-UHFFFAOYSA-N

物化性质

• 沸点：
  312.9±21.0 °C(Predicted)
• 密度：
  1.082±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  苯甲醛 、 Acrylic acid 3-dimethylamino-phenyl ester 在 三乙烯二胺 作用下， 反应 20.0h， 以61%的产率得到3-phenyl-3-hydroxy-2-methylene-propanoic acid m-dimethylaminophenyl ester
  参考文献：
  名称：

  The ‘Baylis - Hillman Reaction’ mechanism and applications revisited

  摘要：

  It is shown that reaction of aryl, benzyl, alkyl and functionalised alkyl acrylic esters with benzaldehyde, in the presence of 1,4-diazabicyclo[2.2.2] octane, strongly depends upon the electronic and steric effects of the ester part. This influence is also observed in condensation of furfuraldehyde. Moreover, for the first time, it is shown that the overall condensation is equilibrated.

  DOI：

  10.1016/s0040-4020(01)88227-2
• 作为产物：
  描述：

  丙烯酰氯 、 3-羟基-N,N-二甲基苯胺 在 三乙胺 作用下， 以 氯仿 为溶剂， 反应 12.0h， 生成 Acrylic acid 3-dimethylamino-phenyl ester
  参考文献：
  名称：

  The ‘Baylis - Hillman Reaction’ mechanism and applications revisited

  摘要：

  It is shown that reaction of aryl, benzyl, alkyl and functionalised alkyl acrylic esters with benzaldehyde, in the presence of 1,4-diazabicyclo[2.2.2] octane, strongly depends upon the electronic and steric effects of the ester part. This influence is also observed in condensation of furfuraldehyde. Moreover, for the first time, it is shown that the overall condensation is equilibrated.

  DOI：

  10.1016/s0040-4020(01)88227-2

文献信息

• POWDER PAINT, METHOD OF MANUFACTURING THE SAME, AND METHOD OF PAINTING USING THE PAINT
  申请人：NIPPON CARBIDE KOGYO KABUSHIKI KAISHA

  公开号：EP0751192A1

  公开（公告）日：1997-01-02

  The present invention provides a powder coating comprising associated particles having an average particle diameter of 3-70 µm, said associated particles containing fine polymer particles having an average particle diameter of 0.01-2 µm. The powder coating of the present invention comprises powder coating particles which have a relatively narrow particle size distribution, which have a relatively small average particle diameter, and which are controlled in shape. Moreover, the powder coating can be produced at a high yield, is greatly superior in fluidity and electrifiability as compared with conventional powder coatings; gives a coating film having excellent luster and sufficient smoothness; and can be applied in a thin film.

  本发明提供了一种粉末涂料，包括平均颗粒直径为 3-70 微米的相关颗粒，所述相关颗粒包含平均颗粒直径为 0.01-2 微米的细聚合物颗粒。 本发明的粉末涂料包含粒径分布相对较窄、平均粒径相对较小且形状可控的粉末涂料颗粒。此外，本发明的粉末涂料产量高，与传统的粉末涂料相比，流动性和可电性大大提高，涂膜具有极佳的光泽和足够的平滑度，并且可以薄膜涂覆。
• Undercoat solution, ink-jet recording method and ink-jet recording device
  申请人：FUJIFILM Corporation

  公开号：EP1955858A1

  公开（公告）日：2008-08-13

  The present invention provides an undercoat solution including a radical-polymerizable compound having a phosphoric acid group, an ink-jet recording method including applying an undercoat solution containing a radical-polymerizable compound having a phosphoric acid group; partially curing the applied undercoat solution; and discharging an ink, which is curable by irradiation with an active energy ray, onto the partially cured undercoat solution to record an image, and an ink-jet recording device including an undercoat solution application unit which applies an undercoat solution containing a radical-polymerizable compound having a phosphoric acid group; an undercoat solution curing unit which partially cures the undercoat solution; and an image recording unit which discharges an ink onto the partially cured undercoat solution to record an image.

  本发明提供了一种包含具有磷酸基团的可自由基聚合的化合物的底层涂料溶液，喷墨记录方法包括涂敷含有具有磷酸基团的可自由基聚合的化合物的底层涂料溶液；部分固化涂敷的底层涂料溶液；一种喷墨记录方法，包括涂敷含有具有磷酸基团的可自由基聚合的化合物的底层涂料溶液；部分固化涂敷的底层涂料溶液；以及在部分固化的底层涂料溶液上涂敷墨水（墨水可通过活性能量射线照射固化）以记录图像；以及一种喷墨记录装置，包括底层涂料溶液涂敷单元，该单元涂敷含有具有磷酸基团的可自由基聚合的化合物的底层涂料溶液；底层涂料溶液固化单元，该单元部分固化底层涂料溶液；以及图像记录单元，该单元在部分固化的底层涂料溶液上涂敷墨水以记录图像。
• Undercoat liquid, in jet recording method and ink jet recording apparatus
  申请人：Fujifilm Corporation

  公开号：EP1958782A1

  公开（公告）日：2008-08-20

  The ink jet recording method of the invention includes providing a recording medium with an undercoat liquid containing a polymer and an oligomer, semi-curing the provided undercoat liquid, and recording an image by discharging an ink curable by irradiation onto the semi-cured undercoat liquid.

  本发明的喷墨记录方法包括为记录介质提供含有聚合物和低聚物的底层液体，半固化所提供的底层液体，并通过在半固化的底层液体上喷射可通过辐照固化的墨水来记录图像。
• Production method of electrostatic latent image developing toner
  申请人：——

  公开号：US20030129519A1

  公开（公告）日：2003-07-10

  A production method of electrostatic latent image developing toner, comprising: a colored particle forming step of forming colored particles in water-based medium; a first separation step of separating the colored particles from the water-based medium; a dispersing step of dispersing the colored particles into a washing medium; a skimming step of skimming impurities other than the colored particles together with at least a part of the washing medium, the impurities drifting on the washing medium; and a drying step of dry the colored particle so as to make the water content of the colored particles being 3% or less.

  一种静电潜影显影墨粉的生产方法，包括：在水基介质中形成有色颗粒的有色颗粒形成步骤；将有色颗粒从水基介质中分离出来的第一分离步骤；将有色颗粒分散到洗涤介质中的分散步骤；将有色颗粒以外的杂质连同至少一部分洗涤介质一起撇去的撇杂步骤，这些杂质漂流在洗涤介质上；以及干燥有色颗粒，使有色颗粒的含水量不超过 3%的干燥步骤。
• Responsive microgel and methods related thereto
  申请人：——

  公开号：US20030152623A1

  公开（公告）日：2003-08-14

  A responsive microgel is provided which responds volumetrically and reversibly to a change in one or more aqueous conditions selected from the group consisting of (temperature, pH, and ionic conditions) comprised of an ionizable network of covalently cross-linked homopolymeric ionizable monomers wherein the ionizable network is covalently attached to an amphiphilic copolymer to form a plurality of ‘dangling chains’ and wherein the ‘dangling chains’ of amphiphilic copolymer form immobile micelle-like aggregates in aqueous solution. A responsive microgel is further provided that comprises at least one therapeutic entity and delivers a substantially linear and sustained release of the therapeutic entity under physiological conditions.

  本发明提供了一种响应型微凝胶，该微凝胶可对选自由温度、pH 值和离子条件组成的组中的一种或多种水性条件的变化作出体积上和可逆的响应、和离子条件）组成的共价交联均聚可离子化单体的可离子化网络，其中可离子化网络与两性共聚物共价连接，形成多条 "悬链"，两性共聚物的 "悬链 "在水溶液中形成不动的胶束状聚集体。还提供了一种响应性微凝胶，它包含至少一种治疗实体，并能在生理条件下提供治疗实体的线性和持续释放。