N-benzoyl-N'-(3-nitro-benzenesulfonyl)-hydrazine

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-benzoyl-N'-(3-nitro-benzenesulfonyl)-hydrazine
• 英文别名: N-Benzoyl-N'-(3-nitro-benzolsulfonyl)-hydrazin；N'-(3-nitrophenyl)sulfonylbenzohydrazide
• 化学式: C₁₃H₁₁N₃O₅S
• 分子量: 321.313
• InChiKey: AQXOZVAXBGXSFA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  130
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  3-硝基苯磺酰氯 在 乙醇 、 一水合肼 、 苯 作用下， 生成 N-benzoyl-N'-(3-nitro-benzenesulfonyl)-hydrazine
  参考文献：
  名称：

  Witte, Recueil des Travaux Chimiques des Pays-Bas, 1932, vol. 51, p. 299,316

  摘要：

  DOI：

文献信息

• Kustova; Kuritsyn, Russian Journal of General Chemistry, 1999, vol. 69, # 2, p. 280 - 282
  作者：Kustova、Kuritsyn

  DOI：——

  日期：——
• Solvent Effect on the Kinetics of Arylsulfonation of Benzhydrazide with 3-Nitrobenzenesulfonyl Chloride in Aqueous-Organic Solutions
  作者：T. P. Kustova、N. A. Sundeeva

  DOI：10.1023/b:rugc.0000031865.01147.b4

  日期：2004.4

  A comparative study is made of the solvent effect on the kinetics of arylsulfonation of benzhydrazide with 3-nitrobenzenesulfonyl chloride in aqueous-organic solutions (water-2-propanol, water-di-oxane, water-tetrahydrofuran, and water-acetonitrile) at 298 K. The arylsulfonation product can be obtained in nearly theoretical yield at the initial reactant concentrations of 0.1 M in the water-dioxane, water-MeCN, and water-THF mixtures containing above 30 wt % water.
• Optimization of conditions for synthesizing sulfonated hydrazides of benzoic and benzenesulfonic acids
  作者：T. P. Kustova、A. A. Kruglyakova、M. S. Gruzdev、L. B. Kochetova

  DOI：10.1134/s1070427216040145

  日期：2016.4

  The kinetic relationships of arenesulfonation of benzoic and benzenesulfonic acid hydrazides were studied. Based on the data obtained, the conditions for synthesizing these products were optimized. The synthesis can be performed using aqueous-organic solvents containing 2-propanol, 1,4-dioxane, or tetrahydrofuran as nonaqueous component. The thermal stability of benzenesulfohydrazide and its sulfonation product was compared on the basis of data of gas chromatography-mass spectrometry. The fragmentation pathways of the reactants and target product, sulfonated benzenesulfohydrazide, were suggested.
• Witte, Recueil des Travaux Chimiques des Pays-Bas, 1932, vol. 51, p. 299,316
  作者：Witte

  DOI：——

  日期：——