3,3,7,7-tetramethyl-1 methoxy-2,8 dioxa-5 aza-1 phosphaV[3,3,0]bicyclooctane | 118065-57-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环化合物
• 英文名称: 3,3,7,7-tetramethyl-1 methoxy-2,8 dioxa-5 aza-1 phosphaV[3,3,0]bicyclooctane
• 英文别名: 3,3,7,7-tetramethyl-1 methoxy-2,8 dioxa-5 aza-1 phospha^V<3,3,0>bicyclooctane；3,3,7,7-tetramethyl 1-methoxy 2,8-dioxa 5-aza 1-phospha(V)bicyclo<3.3.0>octane；3,3,7,7-tetramethyl 1-methoxy 2,8-dioxa 5-aza 1-phospha(V)bicyclo[3.3.0]octane
• CAS: 118065-57-9
• 化学式: C₉H₂₀NO₃P
• 分子量: 221.236
• InChiKey: WTRSACNXCJWTJD-UHFFFAOYSA-N

物化性质

• 密度：
  1.24±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.96
• 重原子数：
  14.0
• 可旋转键数：
  1.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  30.93
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  3,3,7,7-tetramethyl-1 methoxy-2,8 dioxa-5 aza-1 phosphaV[3,3,0]bicyclooctane 在 1,2,3,4,5,6,7,8-八硫杂环辛烷 作用下， 反应 24.0h， 以100%的产率得到5,5-dimethyl 3-<2-methyl 2-hydroxymethyl> 2-methoxy 2-thio 1,3,2-oxazaphospholidine
  参考文献：
  名称：

  Duthu, Brigitte; Houalla, Douraid; Wolf, Robert, Phosphorus, Sulfur and Silicon and the Related Elements, 1990, vol. 51/52, p. 531 - 534

  摘要：

  DOI：
• 作为产物：
  描述：

  3,3,7,7-tetramethyl-1 isopropyloxy-2,8 dioxa-5 aza-1 phosphaV[3,3,0]bicyclooctane 、 甲醇 生成 3,3,7,7-tetramethyl-1 methoxy-2,8 dioxa-5 aza-1 phosphaV[3,3,0]bicyclooctane
  参考文献：
  名称：

  DUTHU, BRIGITTE;HOUALLA, DOURAID;WOLF, ROBERT, CAN. J. CHEM., 66,(1988) N2, C. 2965-2974

  摘要：

  DOI：

文献信息

• Duthu, Brigitte; Houalla, Douraid; Wolf, Robert, Canadian Journal of Chemistry, 1988, vol. 66, p. 2965 - 2974
  作者：Duthu, Brigitte、Houalla, Douraid、Wolf, Robert

  DOI：——

  日期：——
• Bounja, Zouhair; Houalla, Douraid; Revel, Monique, Phosphorus, Sulfur and Silicon and the Related Elements, 1992, vol. 69, # 1-2, p. 43 - 62
  作者：Bounja, Zouhair、Houalla, Douraid、Revel, Monique、Taieb, Maarouf

  DOI：——

  日期：——
• On the extension of the atherton-todd reaction to the 1-organyloxy 1-hydridobicyclophosphoranes
  作者：Douraid Houalla、Zouhair Bounja、Saïd Skouta、Lothar Riesel、Dirk Lindemann

  DOI：10.1016/s0040-4039(00)78867-8

  日期：1992.5

  The 1-methoxy 1-hydridobicyclophosphorane 1 undergoes oxidation reactions with CCl4 in basic solutions which allow the replacement of the hydrogen linked to phosphorus by several nucleophile groups . The same reaction carried out with the bicyclophosphorane 8 leads to a new compound 10 in which two P(v) atoms are included in a ten membered ring.
• Houalla, Douraid; Bounja, Zouhair; Skouta, Said, Phosphorus, Sulfur and Silicon and the Related Elements, 1993, vol. 77, # 1-4, p. 216
  作者：Houalla, Douraid、Bounja, Zouhair、Skouta, Said、Riesel, Lothar、Lindemann, Dirk

  DOI：——

  日期：——
• Bounja, Zouhair; Houalla, Douraid; Revel, Monique, Canadian Journal of Chemistry, 1992, vol. 70, # 4, p. 1105 - 1113
  作者：Bounja, Zouhair、Houalla, Douraid、Revel, Monique、Wolf, Robert

  DOI：——

  日期：——