tetra-para-tolylstiboniumbromide | 61705-01-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetra-para-tolylstiboniumbromide
• 英文别名: tetra(para-tolyl)antimony bromide；Tetra-p-tolylstiboniumbromid；tri(p-tolyl)antimony bromide；(4-CH3C6H4)4SbBr；Tetrakis(4-methylphenyl)stibanium bromide；tetrakis(4-methylphenyl)stibanium;bromide
• CAS: 61705-01-9
• 化学式: C₂₈H₂₈BrSb
• 分子量: 566.184
• InChiKey: FOEOAQXUDRNVPP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.14
• 重原子数：
  30
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  tetra-para-tolylstiboniumbromide 生成 三乙胺氢溴酸盐
  参考文献：
  名称：

  RAJ, PREM;RANJAN, ASHOK;SINGHAL, KIRAN;RASTOGI, RAJIV, SYNTH. AND REACT. INORG. AND METAL-ORG. CHEM., 1984, 14, N 2, 269-282

  摘要：

  DOI：
• 作为产物：
  描述：

  三(对甲基苯基)二溴化锑 、 对甲苯基溴化镁 以 not given 为溶剂， 生成 tetra-para-tolylstiboniumbromide
  参考文献：
  名称：

  Raj, Prem; Ranjan, Ashok; Singhal, Kiran, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1984, vol. 14, p. 269 - 282

  摘要：

  DOI：

文献信息

• Synthesis and structure of the rhodium complex [p-Tol4Sb(DMSO-O)] 2 + [trans-RhBr4(DMSO-S)2]–[cis-RhBr4(DMSO-S)2]–
  作者：V. V. Sharutin、O. K. Sharutina、V. S. Senchurin、N. V. Somov

  DOI：10.1134/s1070328416120058

  日期：2016.12

  The complex [p-(Tol)4Sb(DMSO-O) +2 [trans-RhBr4(DMSO-S)2]–[cis-RhBr4(DMSO-S)2]– (CIF file CCDC no. 1415243) was synthesized by the reaction of sodium hexabromorhodate with tetra(para-tolyl) stibonium bromide in DMSO and studied by X-ray diffraction. The antimony atoms in two types of crystallographically independent [p-Tol4Sb(DMSO-O)]+ cations have a distorted trigonal-bipyramidal coordination with

  复杂的[ p-（Tol）4 Sb（DMSO-O）+ 2 [反式-RhBr4（DMSO-S）2]-[顺式-RhBr 4（DMSO-S）2 ] -（CIF文件CCDC 1415243）通过六溴代钼酸钠与四（对甲苯基）溴化sti在DMSO中的反应合成合成X射线衍射。两种晶体学独立的[ p -Tol 4 Sb（DMSO-O）] +阳离子中的锑原子具有扭曲的三角-双锥体配位，且轴向排列有DMSO氧原子（Sb–C，2.088（9）–2.135（10） Å; Sb∙∙∙O，2.641（10），2.690（10）Å）。在八面体[ 反式-RhBr 4（DMSO-S）2 ] -和[顺式-RhBr 4（DMSO-S）2 ] -阴离子，二甲基亚砜配体通过硫原子与金属配位。反式异构体（2.333（2），2.339（2）Å）的Rh–S距离比顺式异构体（2.303（3），2.318（4）Å）长。
• Arylantimony Derivatives of Three-Coordinated Carbon
  作者：V. V. Sharutin、O. K. Sharutina、A. N. Efremov

  DOI：10.1134/s0036023620010155

  日期：2020.1

  AbstractNew ionic antimony complexes with a three-coordinated carbon atom in their cations, namely, [(Ph4SbO)3C]+[OSO2C6H3(NO2)2-2,4]– ⋅ 3PhH (32%) and [(p-Tol4SbO)3C]+Br– (traces), have been isolated when the products of reactions between pentaphenylantimony and 2,4-dinitrobenzenesulfonic acid and between penta(p-tolyl)antimony and hydrobromic acid were crystallized from a benzene–octane mixture in air

  摘要新型离子锑配合物在它们的阳离子的三配位碳原子上，即，[（PH 4非晶态SbO）3 C] + [OSO 2 C ^ 6 ħ 3（NO 2）2 -2,4] - ⋅3PhH（32％ ）和[（p -Tol 4 SbO）3 C] + Br –（痕量），是在五苯基锑和2,4-二硝基苯磺酸之间以及五（p在空气中从苯-辛烷混合物中结晶出甲苯基）锑和氢溴酸，以及目标产物，例如四苯基锑2,4-二硝基苯磺酸盐和四（对甲苯基）溴化锑。阳离子已基本为平面СO 3锑3核心。ОСО和COSb角接近120°，而C–O键的变化范围为1.277（4）–1.290（3）Å，Sb–O距离（2.266（2）–2.299（2）Å）超过锑和氧原子的共价半径之和。在实验上已经确定，由于上述反应的目标产物与双（四芳基锑）碳酸酯之间的相互作用而形成了这些络合物，所述碳酸双（四芳基锑）碳酸酯也是在这些反应的条件下由五芳基锑和大气二氧化碳形成的。
• Synthesis, characterization and structure of some arylantimony ferrocenylacrylates
  作者：Jin-Shan Li、Run-Chang Liu、Xin-Bao Chi、Guo-Cang Wang、Qun-Shen Guo

  DOI：10.1016/j.ica.2003.12.012

  日期：2004.5

  A series of arylantimony ferrocenylacrylates with the formula (C5H5FeC5H4CH=CHCO2)(n)SbAr(5-n) (n = 1, 2; Ar = C6H5, 4-CH3C6H4, 3-CH3C6H4, 2-CH3C6H4, 4-FC6H4) have been synthesized and characterized by elemental analysis, IR, H-1 NMR and mass spectra. The crystal structures of C5H5FeC5H4CH=CHCO2Sb(C6H5)(4) (I-1) and (C5H5FeC5H4CH=CHCO2)(2)Sb(C6H5)(3) (II1) have been determined by X-ray diffraction. (C) 2003 Elsevier B.V. All rights reserved.
• Synthesis, crystal structures and in vitro antitumor activities of some organoantimony arylhydroxamates
  作者：Guo-Cang Wang、Yong-Na Lu、Jian Xiao、Lin Yu、Hai-Bin Song、Jin-Shan Li、Jing-Rong Cui、Rui-Qing Wang、Fu-Xiang Ran

  DOI：10.1016/j.jorganchem.2004.09.002

  日期：2005.1

  A series of novel organoantimony arylhydroxamates with the formulae [Ar3SbL2,](-)[HNEt3](+) (LH = arylhydroxamic acid: Ar = C6H5. 4-CH3C6H4, 3-CH3C6H4, 4-ClC6H4, 4-FC6H4) and (4-CH3C6H4)(4)SbL were synthesized and characterized by elemental analysis, IR. H-1 NMR and mass spectroscopy. The crystal structures of (4-CH3C6H4)(4)SbL and [Ph3SbL2](-)[HNEt3](+) were determined by X-ray diffraction. The in vitro antitumor activities of all compounds against three human cancer cells are reported. (C) 2004 Published by Elsevier B.V..
• Sharutin; Sharutina; Senchurin, Russian Journal of General Chemistry, 2000, vol. 70, # 1, p. 64 - 65
  作者：Sharutin、Sharutina、Senchurin、Kovaleva、Shcherbakov、Gladyshev

  DOI：——

  日期：——