三苯氧基(苯基)硅烷 | 1173-15-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 三苯氧基(苯基)硅烷
• 英文名称: Triphenoxy-phenyl-silan
• 英文别名: Phenyl-triphenoxy-silan；Phenyl-tri(phenoxy)silane；triphenoxy(phenyl)silane
• CAS: 1173-15-5
• 化学式: C₂₄H₂₀O₃Si
• 分子量: 384.507
• InChiKey: IXJNGXCZSCHDFE-UHFFFAOYSA-N

物化性质

• 熔点：
  56 °C
• 沸点：
  435 °C(Press: 761 Torr)
• 密度：
  1.18±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.07
• 重原子数：
  28
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2931900090

反应信息

• 作为产物：
  描述：

  triphenoxychlorosilane 在 苯基溴化镁 作用下， 以 not given 为溶剂， 生成 三苯氧基(苯基)硅烷
  参考文献：
  名称：

  Joerg, H.; Stetter, J., Journal fur praktische Chemie (Leipzig 1954), 1927, vol. 117, p. 305 - 310

  摘要：

  DOI：

文献信息

• Two Faces of the Bi−O Bond: Photochemically <i>and</i> Thermally Induced Dehydrocoupling for Si−O Bond Formation
  作者：Jacqueline Ramler、Johannes Schwarzmann、Andreas Stoy、Crispin Lichtenberg

  DOI：10.1002/ejic.202100934

  日期：2022.3.9

  A bismuth(III) compound with a reactive (aryl)2Bi−OPh functional group has been synthesized, isolated, and characterized. It has been investigated as a catalyst using the dehydrocoupling of silanes with alcohols or TEMPO as model reactions. In contrast to bismuth compounds with (aryl)2Bi−EPh functional groups (E=S, Se, Te), it shows catalytic activity in thermally- and photochemically-initiated transformations

  合成、分离并表征了具有反应性（芳基） 2 Bi-OPh 官能团的铋（III）化合物。已使用硅烷与醇或 TEMPO 的脱氢偶联作为模型反应，对其作为催化剂进行了研究。与具有（芳基） 2 Bi−EPh 官能团（E=S、Se、Te）的铋化合物相比，它在热和光化学引发的转化中表现出催化活性，解决了不同的反应途径。
• A Highly Active Manganese Precatalyst for the Hydrosilylation of Ketones and Esters
  作者：Tufan K. Mukhopadhyay、Marco Flores、Thomas L. Groy、Ryan J. Trovitch

  DOI：10.1021/ja4116346

  日期：2014.1.22

  The reduction of ((PDI)-P-Ph2PPr)MnCl2 allowed the preparation of the formally zerovalent complex, ((PDI)-P-Ph2PPr)Mn, which features a pentadentate bis(imino)pyridine chelate. This complex is a highly active precatalyst for the hydrosilylation of ketones, exhibiting TOFs of up to 76,800 h(-1) in the absence of solvent. Loadings as low as 0.01 mol % were employed, and ((PDI)-P-Ph2PPr)Mn was found to mediate the atom-efficient utilization of Si-H bonds to form quaternary silane products. ((PDI)-P-Ph2PPr)Mn was also shown to catalyze the dihydrosilylation of esters following cleavage of the substrate acyl C-O bond. Electronic structure investigation of ((PDI)-P-Ph2PPr)Mn revealed that this complex possesses an unpaired electron on the metal center, rendering it likely that catalysis takes place following electron transfer to the incoming carbonyl substituent.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 76, page 212 - 214
  作者：

  DOI：——

  日期：——
• Prokhorova,V.A.; Reikhsfel'd,V.O., Journal of general chemistry of the USSR, 1963, vol. 33, p. 2551 - 2559
  作者：Prokhorova,V.A.、Reikhsfel'd,V.O.

  DOI：——

  日期：——
• Staudinger, H.; Hahn, W., 1953, vol. 11, p. 24 - 50
  作者：Staudinger, H.、Hahn, W.

  DOI：——

  日期：——