三正丁基锡丙酸盐 | 5863-72-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 三正丁基锡丙酸盐
• 英文名称: tributyltin propionate
• 英文别名: Tributylzinnpropionat；Propanoate;tributylstannanylium
• CAS: 5863-72-9
• 化学式: C₁₅H₃₂O₂Sn
• 分子量: 363.128
• InChiKey: AHIXTTGLRFPWJF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.29
• 重原子数：
  18
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  三正丁基锡丙酸盐 在 溴硅 作用下， 反应 0.02h， 生成 Silyl propionate
  参考文献：
  名称：

  Preparation of some silyl esters and study of their vibration spectra in gas and condensed phases

  摘要：

  DOI：

  10.1007/bf00938727
• 作为产物：
  描述：

  tributyl(4-chlorobutoxy)stannane 生成 三正丁基锡丙酸盐
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Comp.12, 1.4.1.1.1.5.2.1.1, page 38 - 56

  摘要：

  DOI：

文献信息

• Process for Production of Alkyl Tin Alkoxide Compound, and Process for Production of Carbonic Acid Ester Using the Compound
  申请人：Shinohata Masaaki

  公开号：US20100292496A1

  公开（公告）日：2010-11-18

  The present invention provides a process for producing: a compound represented by XOR 2 ; a dialkyl tin dialkoxide compound having one tin atom, two Sn—R 1 bonds and two Sn—OR 2 bonds; and/or a tetraalkyl dialkoxy distannoxane compound having one Sn—O—Sn bond, in which each tin atom of the tetraalkyl dialkoxy distannoxane compound has two Sn—R 1 bonds and one Sn—OR 2 bond, the process comprising reacting in the absence of a catalyst at least one alkyl tin compound selected from the group consisting of i) and ii) below: i) a dialkyl tin compound having one tin atom, two Sn—R 1 (wherein R 1 represents an alkyl group) bonds, and two Sn—OX bonds (wherein OX is a group in which HOX that is a conjugate acid of OX is a Bronsted acid having a pKa of from 0 to 6.8); and ii) a tetraalkyl distannoxane compound having one Sn—O—Sn bond, in which each tin atom of the tetraalkyl distannoxane compound has two Sn—R 1 bonds and one Sn—OX bond (wherein OX is a group in which HOX that is a conjugate acid of OX is a Bronsted acid having a pKa of from 0 to 6.8); and a carbonic acid ester represented by R 2 OCOOR 2 (wherein R 2 represents a linear or branched, saturated or unsaturated hydrocarbon group, a hydrocarbon group having a saturated or unsaturated cyclic hydrocarbon substituent, or a Y—CH 2 — group (wherein Y represents an alkyl polyalkylene group, an aromatic group or a cyclic saturated or unsaturated alkylene ether group)), and/or an alcohol represented by R 2 OH (wherein R 2 is the same as defined above).

  本发明提供了一种生产过程：产生一个由XOR表示的化合物；具有一个锡原子、两个Sn—R1键和两个Sn—OR2键的二烷基锡二烷氧化合物；和/或具有一个Sn—O—Sn键的四烷基二烷氧基二锡烷氧化合物，其中四烷基二烷氧基二锡烷氧化合物的每个锡原子具有两个Sn—R1键和一个Sn—OR2键，所述过程包括在缺乏催化剂的情况下反应以下所述组中选择的至少一种烷基锡化合物： i) 具有一个锡原子、两个Sn—R1（其中R1代表烷基基团）键和两个Sn—OX键（其中OX是HOX的共轭酸，HOX是具有从0到6.8的pKa的Bronsted酸的群）的二烷基锡化合物；和 ii) 具有一个Sn—O—Sn键的四烷基二锡烷氧化合物，其中四烷基二锡烷氧化合物的每个锡原子具有两个Sn—R1键和一个Sn—OX键（其中OX是HOX的共轭酸，HOX是具有从0到6.8的pKa的Bronsted酸的群）；和 由R2OCOOR2（其中R2代表线性或支链、饱和或不饱和碳氢基团、具有饱和或不饱和环烃取代基的碳氢基团，或Y—CH2—基团（其中Y代表烷基多聚烯基基团、芳香基团或环状饱和或不饱和烷基醚基团））表示的碳酸酯；和/或 由R2OH（其中R2与上述定义相同）表示的醇。
• Synthesis of phenacyl esters via an organotin route
  作者：S.T. Vijayaraghavan、T.R. Balasubramanian

  DOI：10.1016/0022-328x(85)87139-4

  日期：1985.2

  A facile and convenient method for the synthesis of phenacyl esters using organostannyl carboxylates and phenacyl bromides in the presence of quaternary ammonium salts is reported. In the absence of the quaternary ammonium salt the yields are poor and the reaction is incomplete.

  报道了在季铵盐存在下使用有机锡烷基羧酸盐和苯甲酰溴合成苯甲酸酯的简便方法。在没有季铵盐的情况下，收率很低并且反应不完全。
• Preparation and Some Properties of Acyltin Compounds
  作者：Masanori Kosugi、Hiroyuki Naka、Hiroshi Sano、Toshihiko Migita

  DOI：10.1246/bcsj.60.3462

  日期：1987.9

  According to Quintard’s method, acyltin compounds were prepared by the reaction of tributylstannylmagnesium chloride with an excess of aldehyde, and their physical data were described. These compounds were sensitive to oxygen air to give the corresponding tributyltin carboxylates. Free radical chain mechanism was suggested.

  根据Quintard的方法，通过氯化三丁基锡基镁与过量的醛反应制备酰基锡化合物，并描述了它们的物理数据。这些化合物对氧气敏感，得到相应的羧酸三丁基锡。提出了自由基链机制。
• PROCESS FOR PRODUCTION OF ALKYL TIN ALKOXIDE COMPOUND, AND PROCESS FOR PRODUCTION OF CARBONATE ESTER USING THE COMPOUND
  申请人：Asahi Kasei Chemicals Corporation

  公开号：EP2226328B1

  公开（公告）日：2012-12-26
• Yamaji, Y.; Moriguchi, J.; Matsuda, H., Kogyo Kagaku zasshi / Journal of the Society of Chemical Industry, 1970, vol. 73, p. 1013 - 1017
  作者：Yamaji, Y.、Moriguchi, J.、Matsuda, H.、Matsuda, S.

  DOI：——

  日期：——