Pd(SC6F5)2dppm | 77462-39-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Pd(SC6F5)2dppm
• CAS: 77462-39-6
• 化学式: C₃₇H₂₂F₁₀P₂PdS₂
• 分子量: 889.065
• InChiKey: MXFUIWHDNUSUQF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  11.08
• 重原子数：
  52.0
• 可旋转键数：
  8.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  cis-[(pentafluorophenyl)2 (tetrahydrofurane)2 platinum(II)] 、 Pd(SC6F5)2dppm 以 二氯甲烷 为溶剂， 以72%的产率得到{dppmPd(μ-SC6F5)2Pt(C6F5)2}
  参考文献：
  名称：

  Stereospecific reactions of the “M(C6F5)2” (M  Pd or Pt synthons towards cis-dithiolato complexes

  摘要：

  Complexes of the general formula cis-[M(SC6F5)2L2] (M = Ni, Pd, or Pt; L2 = dppm [bis(diphenylphosphino)methane], dppe [1,2-bis(diphenylphosphino)ethane], or 2PPh3) were synthesized by the reaction (1: 2) between the corresponding cis-[MCl2L2] and Tl(SC6F5). When treated with cis-[M(C6F5)2(THF)2] (M = Pd or Pt; THF = OC4H8) they yield geminal homo- or hetero-binuclear compounds, which were characterized by IR, NMR and mass spectroscopy.

  DOI：

  10.1016/0022-328x(93)80283-h
• 作为产物：
  描述：

  (bis(diphenylphosphino)methane)palladium(II) dichloride 在 TlSC₆F₅ 作用下， 以 丙酮 为溶剂， 以84%的产率得到Pd(SC6F5)2dppm
  参考文献：
  名称：

  Stereospecific reactions of the “M(C6F5)2” (M  Pd or Pt synthons towards cis-dithiolato complexes

  摘要：

  Complexes of the general formula cis-[M(SC6F5)2L2] (M = Ni, Pd, or Pt; L2 = dppm [bis(diphenylphosphino)methane], dppe [1,2-bis(diphenylphosphino)ethane], or 2PPh3) were synthesized by the reaction (1: 2) between the corresponding cis-[MCl2L2] and Tl(SC6F5). When treated with cis-[M(C6F5)2(THF)2] (M = Pd or Pt; THF = OC4H8) they yield geminal homo- or hetero-binuclear compounds, which were characterized by IR, NMR and mass spectroscopy.

  DOI：

  10.1016/0022-328x(93)80283-h

文献信息

• Synthesis and characterisation of mono- and binuclear palladium and platinum complexes with organochalcogenides
  作者：Anshu Singhal、Vimal K. Jain、Babu Varghese、Edward R.T. Tiekink

  DOI：10.1016/s0020-1693(98)00335-1

  日期：1999.2

  Mononuclear palladium and platinum complexes of the type M(ER)(2)((PP)-P-boolean AND) [M = Pd or Pt; ER = SPh, SC6H4Cl-4, SC6H4Me-4, SC6F5, SePh, TeC6H4OEt-4; (PP)-P-boolean AND = dppm or dppe] have been prepared and their ability to form dinuclear metal species has been demonstrated. All complexes have been characterised by multinuclear magnetic resonance (H-1, C-13, Se-77, Pt-195) spectral data. The effects of phosphine ligands and organochalcogenides are reflected in the Se-77 and Pt-195 NMR shifts. The shielding of Pt-195 NMR chemical shifts has been interpreted in terms of their binding ability to platinum. The structures of two derivatives, namely [Pd(SC6F5)(2)(dppe)] and [Pd(SePh)(2)(dppe)], have been established by X-ray crystallography. The palladium atom in each of the monomeric structures exists in a square planar geometry. (C) 1999 Elsevier Science S.A. All rights reserved.
• Hunt, Catherine T.; Balch, Alan L., Inorganic Chemistry, 1981, vol. 20, # 7, p. 2267 - 2270
  作者：Hunt, Catherine T.、Balch, Alan L.

  DOI：——

  日期：——
• Usón, Rafael; Forniés, Juan; Falvello, Larry R., Inorganic Chemistry, 1993, vol. 32, # 7, p. 1066 - 1067
  作者：Usón, Rafael、Forniés, Juan、Falvello, Larry R.、Usón, Miguel A.、Usón, Isabel、Herrero, Santiago

  DOI：——

  日期：——