2-(7-bromo-9,9-dimethyl-9H-fluorene-2-carbonyl)benzoic acid | 1196107-72-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(7-bromo-9,9-dimethyl-9H-fluorene-2-carbonyl)benzoic acid
• 英文别名: 2-(7-bromo-9,9-dimethylfluorene-2-carbonyl)benzoic acid
• CAS: 1196107-72-8
• 化学式: C₂₃H₁₇BrO₃
• 分子量: 421.29
• InChiKey: OCMUBUOOMGSPEQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  27
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  54.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(7-bromo-9,9-dimethyl-9H-fluorene-2-carbonyl)benzoic acid 在 HI 、 PPA 、 碘 作用下， 以 水 、 溶剂黄146 、 甲苯 为溶剂， 生成 2-溴-13,13-二甲基-13H-茚并[1,2-b]蒽
  参考文献：
  名称：

  AMINOANTHRACENE DERIVATIVE AND AN ORGANIC ELECTROLUMINESCENT ELEMENT EMPLOYING THE SAME

  摘要：

  揭示了一种新型氨基蒽衍生物及其所使用的有机电致发光器件。具体来说，所揭示的氨基蒽衍生物具有一个核心（例如，吲哚蒽核心），该核心是蒽基（具有高设备特性）连接到萘基（具有高荧光特性），其中核心被至少一个由化学式2表示的胺基取代，所揭示的有机电致发光器件使用氨基蒽衍生物作为发光层材料，以提高效率、工作电压和寿命。

  公开号：

  US20120161615A1
• 作为产物：
  描述：

  苯酐 、 9,9-二甲基-2-溴芴 在 aluminum chloride 作用下， 以 正己烷 、 二氯甲烷 为溶剂， 以60%的产率得到2-(7-bromo-9,9-dimethyl-9H-fluorene-2-carbonyl)benzoic acid
  参考文献：
  名称：

  AMINOANTHRACENE DERIVATIVE AND AN ORGANIC ELECTROLUMINESCENT ELEMENT EMPLOYING THE SAME

  摘要：

  揭示了一种新型氨基蒽衍生物及其所使用的有机电致发光器件。具体来说，所揭示的氨基蒽衍生物具有一个核心（例如，吲哚蒽核心），该核心是蒽基（具有高设备特性）连接到萘基（具有高荧光特性），其中核心被至少一个由化学式2表示的胺基取代，所揭示的有机电致发光器件使用氨基蒽衍生物作为发光层材料，以提高效率、工作电压和寿命。

  公开号：

  US20120161615A1

文献信息

• ANTHRACENE DERIVATIVES AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME
  申请人：LEE Eunjung

  公开号：US20110057182A1

  公开（公告）日：2011-03-10

  Provided are a novel anthracene derivative and an organic light-emitting device using the same, and more particularly, an anthracene derivative having a core (e.g., an indenoanthracene core) where an anthracene moiety with excellent device characteristics is fused with a fluorene moiety or the like with excellent fluorescent properties, wherein an aryl group is introduced at the core, and an organic light-emitting device using the anthracene derivative, which is enhanced in efficiency, operating voltage, lifetime, etc.

  提供了一种新的蒽衍生物和使用该蒽衍生物的有机发光器件，更具体地说，一种具有核心（例如，吲哚蒽核心）的蒽衍生物，其中具有出色器件特性的蒽基与具有出色荧光特性的萘基或类似基团融合在一起，并且在核心引入芳基团，以及使用该蒽衍生物的有机发光器件，其在效率、工作电压、寿命等方面得到增强。
• ANTHRACENE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE ELEMENT USING THE SAME
  申请人：Shin Chang-Ju

  公开号：US20110210320A1

  公开（公告）日：2011-09-01

  The present invention relates to an anthracene derivative and an organic electroluminescent device using the same. More specifically, the present invention relates to: a novel compound which has a core (for example, an indenoanthracene core) where both an anthracene moiety with excellent device characteristics and a fluorene moiety with excellent fluorescent properties are fused, wherein substituents (for example, a heterocyclic group such as a benzimidazole group, a benzothiazole group, a benzoxazole group, a pyridinyl group or a bipyridinyl group) with an electron transfer capacity are substituted to the core; and an organic electroluminescence element which has improved luminous efficiency, brightness, thermal stability, driving voltage, and lifetime, by comprising an organic layer which is positioned between a positive electrode and negative electrode and contains the novel compound.

  本发明涉及一种蒽衍生物及其应用于有机电致发光器件中。更具体地，本发明涉及一种新型化合物，其具有一个核心（例如，一个茚并蒽核心），其中蒽基具有优异的器件特性，荧光基团具有优异的荧光性能，并且向核心取代基（例如，带有电子转移能力的杂环基团，如苯并咪唑基团、苯并噻唑基团、苯并噁唑基团、吡啶基团或联吡啶基团）被取代；以及一种有机电致发光元件，通过包含新型化合物的有机层位于正电极和负电极之间，其具有改善的发光效率、亮度、热稳定性、驱动电压和寿命。
• Anthracene derivatives and organic electroluminescent device using same
  申请人：Lee Eunjung

  公开号：US08395144B2

  公开（公告）日：2013-03-12

  Provided are a novel anthracene derivative and an organic light-emitting device using the same, and more particularly, an anthracene derivative having a core (e.g., an indenoanthracene core) where an anthracene moiety with excellent device characteristics is fused with a fluorene moiety or the like with excellent fluorescent properties, wherein an aryl group is introduced at the core, and an organic light-emitting device using the anthracene derivative, which is enhanced in efficiency, operating voltage, lifetime, etc.

  提供了一种新的蒽衍生物和使用该衍生物的有机发光器件，更具体地说，该蒽衍生物具有一个核（例如，一个吲哚蒽核），其中具有优异器件特性的蒽基与具有优异荧光性能的芴基或类似结构融合，核中引入了芳基基团，并使用该蒽衍生物的有机发光器件，在效率、工作电压、寿命等方面得到了提高。
• Anthracene derivative and organic electroluminescence element using the same
  申请人：Shin Chang-Ju

  公开号：US08525158B2

  公开（公告）日：2013-09-03

  The present invention relates to an anthracene derivative and an organic electroluminescent device using the same. More specifically, the present invention relates to: a novel compound which has a core (for example, an indenoanthracene core) where both an anthracene moiety with excellent device characteristics and a fluorene moiety with excellent fluorescent properties are fused, wherein substituents (for example, a heterocyclic group such as a benzimidazole group, a benzothiazole group, a benzoxazole group, a pyridinyl group or a bipyridinyl group) with an electron transfer capacity are substituted to the core; and an organic electroluminescence element which has improved luminous efficiency, brightness, thermal stability, driving voltage, and lifetime, by comprising an organic layer which is positioned between a positive electrode and negative electrode and contains the novel compound.

  本发明涉及一种蒽衍生物及其在有机电致发光器件中的应用。更具体地说，本发明涉及一种新型化合物，其具有一个核心（例如，一个茚并蒽核心），其中蒽基具有优异的器件特性，荧光基具有优异的荧光性能，并且核心上取代基（例如，具有电子转移能力的杂环基，如苯并咪唑基、苯并噻唑基、苯并噁唑基、吡啶基或联吡啶基）被取代；以及一种有机电致发光元件，其通过包含所述新型化合物的有机层，位于正极和负极之间，从而提高了发光效率、亮度、热稳定性、驱动电压和寿命。
• Aminoanthracene derivative and an organic electroluminescent element employing the same
  申请人：Hong Jin-Seok

  公开号：US09115112B2

  公开（公告）日：2015-08-25

  Disclosed are a novel amino anthracene derivative and an organic electro-luminescence device using the same. More specifically, the disclosed amino anthracene derivative has a core (e.g., indenoanthracene core) of an anthracene moiety (with a high device characteristic) linked to a fluorene moiety (with a high fluorescence characteristic), in which in the core is substituted with at least one amine group represented by Formula 2 and the disclosed organic electro-luminescence device uses the amino anthracene derivative as a light emitting layer material so as to be enhanced in efficiency, operating voltage, and life span.

  本发明涉及一种新型氨基蒽衍生物及其所使用的有机电致发光器件。具体而言，所披露的氨基蒽衍生物具有蒽基（具有高器件特性）的核心（例如，茚蒽核心）与芴基（具有高荧光特性）连接，其中该核心被至少一个由公式2表示的胺基取代，所披露的有机电致发光器件使用该氨基蒽衍生物作为发光层材料，以提高效率、工作电压和寿命。