1-benzoyloxy-2-(N,N-diethylamino)-ethane | 2572-39-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-benzoyloxy-2-(N,N-diethylamino)-ethane
• 英文别名: 2-(N,N-diethylamino)ethyl benzoate；N-Diethylaminoethylbenzoat；1-benzoyloxy-2-diethylamino-ethane；1-Benzoyloxy-2-diaethylamino-aethan；(β-Diaethylamino-aethyl)-benzoat；Benzoesaeure-(β-diaethylamino-aethyl)-ester；Benzoic acid, 2-(diethylamino)ethyl ester；2-(diethylamino)ethyl benzoate
• CAS: 2572-39-6
• 化学式: C₁₃H₁₉NO₂
• mdl: MFCD00452288
• 分子量: 221.299
• InChiKey: GEVPHAFTDXTZHY-UHFFFAOYSA-N

物化性质

• 沸点：
  140-142 °C(Press: 0.15 Torr)
• 密度：
  1.019±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.461
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-benzoyloxy-2-(N,N-diethylamino)-ethane 、 碘乙烷 生成 triethyl-(2-benzoyloxy-ethyl)-ammonium; iodide
  参考文献：
  名称：

  Fusco et al., Gazzetta Chimica Italiana, 1948, vol. 78, p. 511,513, 514

  摘要：

  DOI：
• 作为产物：
  描述：

  二乙氨基乙醇 生成 1-benzoyloxy-2-(N,N-diethylamino)-ethane
  参考文献：
  名称：

  YAMAGUTI, KEITI;XAYASI, AYAKO

  摘要：

  DOI：
• 作为试剂：
  描述：

  4,4-Dibrom-but-1-en 在 potassium osmate(VI) 、 1-benzoyloxy-2-(N,N-diethylamino)-ethane 、 N-甲基吗啉氧化物 作用下， 以 丙酮 为溶剂， 反应 3.0h， 以96%的产率得到4,4-dibromo-butane-1,2-diol
  参考文献：
  名称：

  3-烷氧基-1,1-二溴-烷烃的非对映选择性溴/锂交换反应

  摘要：

  研究了手性3-烷氧基-1,1-二溴代烷烃在溴/锂交换反应中的非对映选择性。如先前所推测的，发现两个非对映体溴原子的分化不仅仅取决于底物的构象预组织。显然，在δ中心的空间拥挤控制了在手性中心的C-3-氧取代基的空间取向，这可能是观察到的不对称诱导的原因。

  DOI：

  10.1016/0040-4020(96)00260-8

文献信息

• The Synthesis of <i>Ortho</i>-Substituted 2-Diethylaminoethyl Benzoates as Potential Local Anaesthetics
  作者：J Thomas、J Canty

  DOI：10.1111/j.2042-7158.1962.tb11143.x

  日期：2011.4.12

  A series of mono-ortho- and di-ortho- substituted benzoic esters of 2-diethylaminoethanol has been synthesised. Improved methods for the preparation of 2,6-difluorobenzoic acid and 2,6-dimethylbenzoic acid are reported. The preparation of esters of di-ortho- substituted benzoic acids is discussed and an efficient method of esterification of these acids is described.

  合成了一系列2-二乙氨基乙醇的单邻位和双邻位取代苯甲酸酯。报道了制备2,6-二氟苯甲酸和2,6-二甲基苯甲酸的改进方法。讨论了对二邻位取代苯甲酸酯的制备，并描述了一种高效的酯化这些酸的方法。

• Coating compositions
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0260842A2

  公开（公告）日：1988-03-23

  Photocurable coating compositions useful for coating optical glass fibres comprising: (a) a polyethylenically unsaturated polyurethane derived from a polyol having pendent fluoroalkyl groups; (b) an ethylenically unsaturated monomer which is a liquid solvent for the polyethylenically unsaturated polyurethane and is copolymerisable therewith, and (c) a photo-initiator composition.

  用于光学玻璃纤维涂层的光固化涂层组合物，包括：(a) 由具有悬垂氟烷基的多元醇衍生的聚乙烯不饱和聚氨酯；(b) 作为聚乙烯不饱和聚氨酯的液体溶剂并可与之共聚的乙烯不饱和单体，以及 (c) 光引发剂组合物。
• Optical fibre coatings and their production
  申请人：ZENECA LIMITED

  公开号：EP0539030A1

  公开（公告）日：1993-04-28

  The use of an ethylenically-terminated urethane oligomer for the provision of a radiation-cured coating material of an optical fibre, the urethane oligomer being derived from reactants which include a hydroxyl-terminated polyester polyol having dimer acid residues in its structure.

  使用乙烯基封端聚氨酯低聚物为光纤提供辐射固化涂层材料，该聚氨酯低聚物由反应物衍生而成，反应物包括羟基封端聚酯多元醇，其结构中含有二聚酸残基。
• Optical fibre assemblies and ducts therefor
  申请人：BICC Public Limited Company

  公开号：EP0752604A1

  公开（公告）日：1997-01-08

  An optical fibre assembly is described exhibiting antistatic behaviour comprising at least one optical fibre and having an external organic polymer-based coating which contains a non-aqueous, or substantially non-aqueous, antistatic composition comprising (a) an antistatic agent(s), and (b) an organic liquid(s) having a dielectric constant of ≥ 15 and a boiling point of ≥ 100°C. There is also described a duct of an optical fibre transmission line for carrying an optical fibre assembly and having an inner region which defines a tubular pathway for the optical fibre assembly, wherein the duct exhibits antistatic behaviour and has incorporated into at least the inner region thereof an antistatic composition as defined above.

  描述了一种具有抗静电性能的光纤组件，该组件包括至少一根光纤，并具有一个外部有机聚合物涂层，该涂层含有非水或基本非水的抗静电组合物，该组合物包括(a)抗静电剂和(b)介电常数≥15、沸点≥100°C的有机液体。 还描述了一种光纤传输线的导管，该导管用于承载光纤组件，并具有为光纤组件确定管状通路的内部区域，其中导管具有抗静电性能，并至少在其内部区域加入了如上定义的抗静电组合物。
• TREAD RUBBER COMPOSITION AND PNEUMATIC TIRE
  申请人：Sumitomo Rubber Industries, Ltd.

  公开号：EP2857446A1

  公开（公告）日：2015-04-08

  Provided are a tread rubber composition that can achieve a balanced improvement in fuel economy, wet-grip performance, and abrasion resistance, and a pneumatic tire including the composition. The tread rubber composition includes: a rubber component; silica; and a silane-coupling agent containing a mercapto group, the rubber component including per 100% by mass thereof 5% by mass or more of a conjugated diene polymer (A), the polymer (A) including a monomer unit derived from a conjugated diene, a monomer unit derived from a compound of formula (1), and a monomer unit derived from a compound of formula (2), at least one end of the copolymer (A) being modified by the following compound (G) or an alkoxysilane compound, the composition including 5-150 parts by mass of the silica per 100 parts by mass of the rubber component, Compound (G): at least one compound selected from the group consisting of compounds containing an optionally-substituted amino group and a carbonyl group and compounds containing an optionally-substituted amino group and a thiocarbonyl group,         V1-S1     (1)         V2-A2     (2) wherein V1 and V2 each represent a hydrocarbyl group containing a polymerizable carbon-carbon double bond; S1 represents a substituted silyl group, and A2 represents a substituted amino group or a nitrogen-containing heterocyclic group.

  本文提供了一种可均衡改善燃油经济性、湿抓地性能和耐磨性的胎面橡胶组合物，以及一种包含该组合物的充气轮胎。胎面橡胶组合物包括橡胶成分；白炭黑和含有巯基的硅烷偶联剂，橡胶成分包括每 100% 质量中 5%（质量）或更多的共轭二烯聚合物 (A)，聚合物 (A) 包括衍生自共轭二烯的单体单元、衍生自式 (1) 化合物的单体单元和源自式（2）化合物的单体单元，共聚物（A）的至少一端由下列化合物（G）或烷氧基硅烷化合物改性，该组合物包括每 100 份（质量）橡胶成分中含 5-150 份（质量）二氧化硅的化合物（G）：至少一种选自以下组别的化合物：含有任选取代的氨基和羰基的化合物，以及含有任选取代的氨基和硫代羰基的化合物、 V1-S1 (1) V2-A2 (2) 其中 V1 和 V2 分别代表含有可聚合碳碳双键的烃基，S1 代表取代的硅烷基，A2 代表取代的氨基或含氮杂环基。