1,2,4-tris-(3-chloro-3-thia-propyl)cyclohexane | 1225201-62-6

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫基化合物
• 英文名称: 1,2,4-tris-(3-chloro-3-thia-propyl)cyclohexane
• 英文别名: 2-[2,4-Bis(2-chlorosulfanylethyl)cyclohexyl]ethyl thiohypochlorite；2-[2,4-bis(2-chlorosulfanylethyl)cyclohexyl]ethyl thiohypochlorite
• CAS: 1225201-62-6
• 化学式: C₁₂H₂₁Cl₃S₃
• 分子量: 367.856
• InChiKey: CKQUADCRMJCUPQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  75.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1,2,4-tris-(3-chloro-3-thia-propyl)cyclohexane 、 sodium 4-methylbenzenesulfinate 以 四氯化碳 为溶剂， 以100%的产率得到toluene-4-thiosulfonic acid S-{2-[2,4-bis(2-toluene-4-sulfonylsulfanylethyl)cyclohexyl]ethyl} ester
  参考文献：
  名称：

  JP5681635

  摘要：

  公开号：
• 作为产物：
  描述：

  S,S,S-[2,2,2-(1,2,4-cyclohexanetriyl)triethyl]tristhioacetate 在 sodium ethanolate 、 氯 作用下， 以 四氯化碳 、 乙醇 为溶剂， 反应 2.9h， 生成 1,2,4-tris-(3-chloro-3-thia-propyl)cyclohexane
  参考文献：
  名称：

  JP5681635

  摘要：

  公开号：

文献信息

• [EN] THIOCARBAMOYLDISULFANYL-FUNCTIONAL CYCLOALIPHATIC COMPOUND, PROCESS FOR ITS PREPARATION, FILLED SULFUR-VULCANIZABLE ELASTOMER COMPOSITION CONTAINING SAME AND ARTICLES FABRICATED THEREFROM<br/>[FR] COMPOSÉ CYCLOALIPHATIQUE À FONCTION THIOCARBAMOYLDISULFANYLE, SON PROCÉDÉ DE SYNTHÈSE, COMPOSITION ÉLASTOMÈRE VULCANISABLE SULFURÉE CHARGÉE L'INCLUANT ET ARTICLES FABRIQUÉS À PARTIR DE LADITE COMPOSITION
  申请人：MOMENTIVE PERFORMANCE MAT INC

  公开号：WO2010051396A1

  公开（公告）日：2010-05-06

  A thiocarbamoyldisulfanyl-functional cycloaliphatic compound, useful as a crosslinker for filled sulfur-vulcanizable elastomer compositions, is represented by the general formula: G[-CaH2a-S-S-C(=S)NR2]n wherein G is a saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen or a saturated monocyclic silicone [RSiO-]n [R2SiO-]p group of valence n; each R independently is a hydrogen or a monovalent hydrocarbon of up to 20 carbon atoms; each occurrence of subscripts a independently is an integer wherein a is 2 to 6; n is an integer of from 3 to 6; and, p is an integer of from 0 to 3.

  一种含有硫代氨基二硫基的环脂化合物，通式为G[-CaH2a-S-S-C(=S)NR2]n，用作填充硫化橡胶组合物的交联剂。其中，G是一个饱和的、含有5到12个碳原子的价态为n的单环脂肪基，可以选择性地含有至少一个卤素或价态为n的饱和单环硅氧[RSiO-]n [R2SiO-]p基团；每个R独立地是氢或具有最多20个碳原子的一价碳氢化合物；每个下标a的出现独立地是一个整数，其中a为2到6；n是从3到6的整数，p是从0到3的整数。
• SULFUR-CONTAINING CYCLOALIPHATIC COMPOUND, PROCESS FOR ITS PREPARATION, FILLED SULFUR-VULCANIZABLE ELASTOMER COMPOSITION CONTAINING SAME AND ARTICLES FABRICATED THEREFROM
  申请人：Momentive Performance Materials Inc.

  公开号：EP2342275A1

  公开（公告）日：2011-07-13
• Sulfur-containing cycloaliphatic compound, process for its preparation, filled sulfur-vulcanizable elastomer composition containing same and articles fabricated therefrom
  申请人：O'Brien Michael Joseph

  公开号：US20100113681A1

  公开（公告）日：2010-05-06

  A sulfur-containing cycloaliphatic compound, useful as a crosslinker for filled sulfur-vulcanizable elastomer compositions, is represented by the general formula: G[—C a H 2a —S—S(═O) b —R] n wherein G is a saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen or a saturated monocyclic silicone [RSiO—] n [R 2 SiO—] p group of valence n; each R independently is a monovalent hydrocarbon of up to 20 carbon atoms; each occurrence of subscripts a and b independently is an integer wherein a is 2 to 6 and b is 1 or 2; n is an integer of from 3 to 6; and p is an integer of from 0 to 3.
• US8334340B2
  申请人：——

  公开号：US8334340B2

  公开（公告）日：2012-12-18
• [EN] SULFUR-CONTAINING CYCLOALIPHATIC COMPOUND, PROCESS FOR ITS PREPARATION, FILLED SULFUR-VULCANIZABLE ELASTOMER COMPOSITION CONTAINING SAME AND ARTICLES FABRICATED THEREFROM<br/>[FR] COMPOSÉ CYCLOALIPHATIQUE CONTENANT DU SOUFRE, SON PROCÉDÉ DE FABRICATION, COMPOSITION ÉLASTOMÈRE CHARGÉE VULCANISABLE PAR LE SOUFRE CONTENANT CE COMPOSÉ ET ARTICLES FABRIQUÉS À PARTIR DE CETTE COMPOSITION
  申请人：MOMENTIVE PERFORMANCE MAT INC

  公开号：WO2010059363A1

  公开（公告）日：2010-05-27

  A sulfur-containing cycloaliphatic compound, useful as a crosslinker for filled sulfur-vulcanizable elastomer compositions, is represented by the general formula:G[-CaH2a-S-S(=O)b-R]n wherein G is a saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen or a saturated monocyclic silicone [RSiO-]n[R2SiO-]p group of valence n; each R independently is a monovalent hydrocarbon of up to 20 carbon atoms; each occurrence of subscripts a and b independently is an integer wherein a is 2 to 6 and b is 1 or 2; n is an integer of from 3 to 6; and p is an integer of from 0 to 3.