bis(phenyltelluro)methane | 55136-88-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(phenyltelluro)methane
• 英文别名: 1,1'-(Methyleneditellanyl)dibenzene；phenyltellanylmethyltellanylbenzene
• CAS: 55136-88-4
• 化学式: C₁₃H₁₂Te₂
• 分子量: 423.438
• InChiKey: HSZRXWGZAYDCJJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.42
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  bis(phenyltelluro)methane 生成 二苄基甲酮
  参考文献：
  名称：

  Uemura, Sakae; Ohe, Kouichi; Sugita, Nobuyuki, Journal of the Chemical Society. Perkin transactions I, 1990, # 6, p. 1697 - 1703

  摘要：

  DOI：
• 作为产物：
  描述：

  苯基锂 以 乙醚 为溶剂， 生成 bis(phenyltelluro)methane
  参考文献：
  名称：

  Seebach,D.; Beck,A.K., Chemische Berichte, 1975, vol. 108, p. 314 - 321

  摘要：

  DOI：

文献信息

• OLEFIN SYNTHESIS BY REACTION OF ALKYL PHENYL TELLURIDES WITH CHLORAMINE-T
  作者：Tetsuo Otsubo、Fumio Ogura、Hachiro Yamaguchi、Hiroyuki Higuchi、Yoshiteru Sakata、Soichi Misumi

  DOI：10.1246/cl.1981.447

  日期：1981.4.5

  Alkyl phenyl tellurides reacted with chloramine-T in refluxing tetrahydrofuran to give olefins in high yields.

  烷基苯基碲化物与氯胺-T 在回流的四氢呋喃中反应，以高产率得到烯烃。
• Hoffmann, Reinhard W.; Dress, Ruprecht K.; Ruhland, Thomas, Chemische Berichte, 1995, vol. 128, # 9, p. 861 - 870
  作者：Hoffmann, Reinhard W.、Dress, Ruprecht K.、Ruhland, Thomas、Wenzel, Andreas

  DOI：——

  日期：——
• Lipase-catalyzed kinetic resolution of (RS)-hydroxy tellurides
  作者：Alcindo A. Dos Santos、Carlos E. Da Costa、Jefferson L. Princival、João V. Comasseto

  DOI：10.1016/j.tetasy.2006.07.024

  日期：2006.9

  The enzymatic resolution of racemic mixtures of hydroxy tellurides with a range of lipases has been investigated. Lipase-B from Candida antarctica (CALB) gave the best conversions, providing both enantiomers with high enantiomeric purity. A comparative study of the effect of solvent and substrate on the enzymatic kinetic resolution was performed. (c) 2006 Elsevier Ltd. All rights reserved.
• Synthesis and characterization of bis(aryltelluro)methanes
  作者：Libardo Torres C.

  DOI：10.1016/0022-328x(90)85450-d

  日期：1990.1
• Synthesis and characterization of the complexes of trimethylplatinum(IV) iodide with some ditellurides and ditelluroethers: The crystal structure of [(PtIMe3)2(p-MeOC6H4Te)2]
  作者：Harkesh B. Singh、Anna Regini、Jerry P. Jasinski、Ernest S. Paight、Ray J. Butcher

  DOI：10.1016/0022-328x(94)88057-3

  日期：1994.2

  Trimethylplatinum(IV) iodide reacts with ditellurides, R(2)Te(2), to give bimetallic complexes of the type [(PtIMe(3))(2)(Te(3)R(2))] (R = Me, p-MeOC(6)H(4), p-EtOC(6)H(4)) Ditelluroethers, RTeCH(2)TeR, react with trimethylpiatinum(IV) iodide to give the bimetallic complex [(PtIMe(3))(2)RTeCH(2)TeR)] (R = p-MeOC(6)H(4)) or the mononuclear complexes, [(PtIMe(3))(RTeCH(2)TeR)] and[(PtIMe(3))(RTeCH(2)TeR)(2)] (R = C6H5). The crystal structure of [(PtIMe(3))(2)(p-MeOC(6)H(4)Te)(2)] has been determined.