2-(环己基硫代)乙胺 | 67215-19-4

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 中文名称: 2-(环己基硫代)乙胺
• 中文别名: 2-(硫代环己基)乙胺
• 英文名称: 2-(cyclohexylthio)ethylamine
• 英文别名: 2-(cyclohexylsulfanyl)ethylamine；2-(cyclohexylthio)ethanamine；2-cyclohexylmercapto-ethylamine；2-Cyclohexylmercapto-aethylamin；2-cyclohexylsulfanylethanamine
• CAS: 67215-19-4
• 化学式: C₈H₁₇NS
• mdl: MFCD09034635
• 分子量: 159.296
• InChiKey: MDNQNAWXAWNTFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  51.3
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 海关编码：
  2930909090

反应信息

• 作为反应物：
  描述：

  2-(环己基硫代)乙胺 、 2-溴丙酸 生成 3-(2-cyclohexylsulfanyl-ethyl)-4-methyl-sydnone
  参考文献：
  名称：

  抗炎性sydnones。2。

  摘要：

  DOI：

  10.1021/jm00235a011
• 作为产物：
  描述：

  2-唑烷酮 、 环己硫醇 在 NaOPr 作用下， 以 丙醇 为溶剂， 反应 6.0h， 以74%的产率得到2-(环己基硫代)乙胺
  参考文献：
  名称：

  A Simple Synthesis of β-Amino Sulfides

  摘要：

  硫醇在醇盐的存在下与2-噁唑烷酮反应，得到高产率的β-氨基硫醚。该方法被应用于合成5,6-二氢-1,4-噻嗪-3(2H)-酮。

  DOI：

  10.1055/s-1997-971

文献信息

• Synthesis, Characterization, and Highly Selective Ethylene Dimerization to 1-Butene of [O−NX]Ni(II) Complexes
  作者：Chongjie Xu、Qi Shen、Xiuli Sun、Yong Tang

  DOI：10.1002/cjoc.201100443

  日期：2012.5

  series of nickel(II) complexes have been synthesized and characterized. Molecular structure analysis exhibits that a square planar geometry around nickel is adopted. Upon activation with MAO, these nickel(II) complexes are efficient in catalyzing the ethylene dimerization, providing 1‐butene with an activity of up to 1.4×107 g/(mol·h·atm). The heteroatoms of the sidearm in the complexes were proved to

  已经合成和表征了一系列镍（II）配合物。分子结构分析表明，采用了围绕镍的正方形平面几何形状。通过MAO活化后，这些镍（II）络合物可有效催化乙烯二聚，从而提供1-丁烯，其活性最高可达1.4×10 7 g /（mol·h·atm）。络合物中侧臂的杂原子被证明对1-丁烯的活性和选择性有很大的影响。
• The Castagnoli-Cushman reaction in a three-component format
  作者：Evgeny Chupakhin、Dmitry Dar'in、Mikhail Krasavin

  DOI：10.1016/j.tetlet.2018.05.066

  日期：2018.6

  The first example of the Castagnoli-Cushman reaction of homophthalic acid with an amine and an aldehyde conducted in a three-component format is reported. This new protocol employs no dehydrating agents and, unlike the traditional Castagnoli-Cushman reaction of homophthalic anhydride, allows simultaneous mixing of all three reagents and provides good to excellent yields of trans-configured tetrahydroisoquinolonic

  报道了以三组分形式进行的高邻苯二甲酸与胺和醛的Castagnoli-Cushman反应的第一个实例。该新方案不使用脱水剂，并且与传统的邻苯二甲酸酐的Castagnoli-Cushman反应不同，它允许同时混合所有三种试剂，并提供反式构型的四氢异喹啉酸的良好或极佳的收率。
• Quinoline derivative and use of same
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0818512A1

  公开（公告）日：1998-01-14

  Quinoline compound, zinc halogenide complex and zinc complex suited for use in an electro-luminescence element, a fluorescent material and an ultraviolet absorption material, and a preparation process for these compounds are described. These compounds and a tautomer of the same has a strong luminescent intensity and is used for an EL material, the compound of zinc halogenide complex and zinc complex and a tautomer of the same has absorption at a wave length of 400nm or less and is used for an ultraviolet absorption material, and further the quinoline compound and a tautomer has a strong luminescent intensity and is used for a fluorescent material. The zinc halogenide complex and zinc complex can be prepared by each other related preparation processes directly from a quinoline derivative and a phthalimide derivative, or by way of the quinoline compound which is obtained from these derivatives.

  描述了适用于电致发光元件、荧光材料和紫外线吸收材料的喹啉化合物、卤化锌络合物和锌络合物，以及这些化合物的制备工艺。 这些化合物及其同系物具有很强的发光强度，可用于电致发光材料；卤化锌络合物和锌络合物的化合物及其同系物在波长为 400nm 或以下时有吸收，可用于紫外线吸收材料；此外，喹啉化合物及其同系物具有很强的发光强度，可用于荧光材料。 卤化锌络合物和锌络合物可以直接从喹啉衍生物和邻苯二甲酰亚胺衍生物，或通过从这些衍生物中得到的喹啉化合物，通过彼此相关的制备工艺制备。
• COMPOSITION FOR OPTICAL MATERIAL
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP1426392A1

  公开（公告）日：2004-06-09

  The composition for optical materials of the present invention comprises a compound having in one molecule at least one structure represented by the following formula (1): wherein R1, R2, R3, R4, X, Y and n are as defined in the disclosure, an amine compound and an isocyanate compound. Resins obtained by curing the composition by polymerization are useful as well-balanced optical materials having a high impact resistance, a high refractive index and a sufficiently high Abbe's number.

  本发明的光学材料组合物包括在一个分子中至少具有下式（1）所代表的一种结构的化合物： 其中 R1、R2、R3、R4、X、Y 和 n 如公开资料中所定义；胺化合物和异氰酸酯化合物。通过聚合固化组合物得到的树脂可用作具有高抗冲击性、高折射率和足够高的阿贝数的均衡光学材料。
• Composition for optical material
  申请人：——

  公开号：US20040147708A1

  公开（公告）日：2004-07-29

  The composition for optical materials of the present invention comprises a compound having in one molecule at least one structure represented by the following formula (1): 1 wherein R 1 , R 2 , R 3 , R 4 , X, Y and n are as defined in the disclosure, an amine compound and an isocyanate compound. Resins obtained by curing the composition by polymerization are useful as well-balanced optical materials having a high impact resistance, a high refractive index and a sufficiently high Abbe's number.

  本发明的光学材料组合物包括一种化合物，其一个分子中至少有一个结构由下式（1）表示： 1 其中 R 1 , R 2 , R 3 , R 4 X、Y 和 n 的定义、胺化合物和异氰酸酯化合物。通过聚合固化组合物得到的树脂可用作具有高抗冲击性、高折射率和足够高阿贝数的均衡光学材料。