(4-Tert-butylphenoxy)-dichloro-sulfanylidene-lambda5-phosphane | 68591-35-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (4-Tert-butylphenoxy)-dichloro-sulfanylidene-lambda5-phosphane
• 英文别名: (4-tert-butylphenoxy)-dichloro-sulfanylidene-λ5-phosphane
• CAS: 68591-35-5
• 化学式: C₁₀H₁₃Cl₂OPS
• 分子量: 283.158
• InChiKey: SCVUKIGSQCMWPQ-UHFFFAOYSA-N

物化性质

• 沸点：
  324.9±35.0 °C(Predicted)
• 密度：
  1.296±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  41.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (4-Tert-butylphenoxy)-dichloro-sulfanylidene-lambda5-phosphane 在 水 、 zinc(II) chloride 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 24.0h， 生成
  参考文献：
  名称：

  Synthesis, structural and spectroscopic characterization of thiophosphorodiamidates and effect of ZnCl2 on the hydrolysis of the P–N bond

  摘要：

  New N,N'-dibenzylthiophosphorodiamidate derivatives were synthesized from the corresponding thiophosphorodichloridate intermediates and benzylamine. Several compounds with formula 2-MeC6H4OP(S)(NHBn)(2) (6), 2-FC6H4OP(S)(NHBn)(2) (7), 2-ClC6H4OP(S)(NHBn)(2) (8), 4-MeC6H4OP(S)(NHBn)(2) (9) and 4-t-BuC6H4OP(S)(NHBn)(2) (10) were synthesized and characterized by H-1, C-13, P-31 NMR, IR, mass spectroscopy and elemental analysis. The single crystal X-ray diffraction studies of 6 and 7 have been described. ZnCl2 assisted P-N bond hydrolysis of thiophosphorodiamidates was investigated. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.07.033
• 作为产物：
  描述：

  三氯硫磷 、 4-叔丁基苯酚 在 sodium hydroxide 、 四丁基溴化铵 作用下， 以 水 、 二氯甲烷 为溶剂， 反应 5.0h， 以81%的产率得到(4-Tert-butylphenoxy)-dichloro-sulfanylidene-lambda5-phosphane
  参考文献：
  名称：

  Synthesis, structural and spectroscopic characterization of thiophosphorodiamidates and effect of ZnCl2 on the hydrolysis of the P–N bond

  摘要：

  New N,N'-dibenzylthiophosphorodiamidate derivatives were synthesized from the corresponding thiophosphorodichloridate intermediates and benzylamine. Several compounds with formula 2-MeC6H4OP(S)(NHBn)(2) (6), 2-FC6H4OP(S)(NHBn)(2) (7), 2-ClC6H4OP(S)(NHBn)(2) (8), 4-MeC6H4OP(S)(NHBn)(2) (9) and 4-t-BuC6H4OP(S)(NHBn)(2) (10) were synthesized and characterized by H-1, C-13, P-31 NMR, IR, mass spectroscopy and elemental analysis. The single crystal X-ray diffraction studies of 6 and 7 have been described. ZnCl2 assisted P-N bond hydrolysis of thiophosphorodiamidates was investigated. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.07.033

文献信息

• DZHUNDUBAEV, K. D.;ASHYMBAEVA, B.;TOKTOBEKOVA, T.;SULAJMANOV, A. S., VINITI 1156-84
  作者：DZHUNDUBAEV, K. D.、ASHYMBAEVA, B.、TOKTOBEKOVA, T.、SULAJMANOV, A. S.

  DOI：——

  日期：——
• US3957798A
  申请人：——

  公开号：US3957798A

  公开（公告）日：1976-05-18
• US3984348A
  申请人：——

  公开号：US3984348A

  公开（公告）日：1976-10-05
• Synthesis, structural and spectroscopic characterization of thiophosphorodiamidates and effect of ZnCl2 on the hydrolysis of the P–N bond
  作者：Payal Malik、Debashis Chakraborty

  DOI：10.1016/j.poly.2012.07.033

  日期：2013.3

  New N,N'-dibenzylthiophosphorodiamidate derivatives were synthesized from the corresponding thiophosphorodichloridate intermediates and benzylamine. Several compounds with formula 2-MeC6H4OP(S)(NHBn)(2) (6), 2-FC6H4OP(S)(NHBn)(2) (7), 2-ClC6H4OP(S)(NHBn)(2) (8), 4-MeC6H4OP(S)(NHBn)(2) (9) and 4-t-BuC6H4OP(S)(NHBn)(2) (10) were synthesized and characterized by H-1, C-13, P-31 NMR, IR, mass spectroscopy and elemental analysis. The single crystal X-ray diffraction studies of 6 and 7 have been described. ZnCl2 assisted P-N bond hydrolysis of thiophosphorodiamidates was investigated. (C) 2012 Elsevier Ltd. All rights reserved.