cis-WCl4(2,6-diphenylphenoxide) | 103230-41-7

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: cis-WCl4(2,6-diphenylphenoxide)
• 英文别名: W(2,6-diphenylphenoxide)2Cl4；W(O-2,6-C6H3Ph2)2Cl4
• CAS: 103230-41-7；111465-08-8
• 化学式: C₃₆H₂₆Cl₄O₂W
• 分子量: 816.263
• InChiKey: PQRQCMXHYXQLBU-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  12.48
• 重原子数：
  43.0
• 可旋转键数：
  8.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  cis-WCl4(2,6-diphenylphenoxide) 在 MgC₄H₆(OC₄H₈) 作用下， 以 苯 为溶剂， 以30%的产率得到
  参考文献：
  名称：

  Kerschner, Judith L.; Fanwick, Phillip E.; Rothwell, Ian P., Inorganic Chemistry, 1989, vol. 28, # 4, p. 780 - 786

  摘要：

  DOI：
• 作为产物：
  描述：

  2,6-二苯基苯酚 、 六氯化钨 以 四氯化碳 为溶剂， 以80%的产率得到cis-WCl4(2,6-diphenylphenoxide)
  参考文献：
  名称：

  W(O-2,6-C6H3X2)2Cl4/Bu4Sn as metathesis catalyst of 1-alkenes

  摘要：

  Tungsten compounds with aryloxo ligands, i.e., W(O-2,6-C6H3X2)(2)Cl-4 (X = Cl,Ph) and Bu,Sn, were investigated as catalytic systems for the metathesis of l-alkenes of varying carbon lenghts. The catalytic system was activated at 85 degrees C for 20 min prior to use. Optimum metathesis activity with l-alkenes was observed at 85 degrees C and a Sn/W molar ratio = 3. The W(O-2,6-C6H3X2)(2)Cl-4/Bu4Sn catalytic system is very active for the metathesis of l-alkenes with a carbon chain length of about six to eight and it favours a more polar solvent such as chlorobenzene. (C) 1998 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(98)00120-4

文献信息

• Synthesis and catalytic properties of W(OAr)2Cl2(CHCMe3)(OR2) and W(OAr)2Cl(CHCMe3)(CH2CMe3)(OR2)(Ar = 2,6-disubstituted phenyl; R = Et or Pri), new uni-component catalysts for metathesis of acyclic and cyclic olefins, with or without functional groups
  作者：Francoise Quignard、Michel Leconte、Jean-Marie Basset

  DOI：10.1039/c39850001816

  日期：——

  The synthesis of W(OAr)2Cl(CHR)(CH2R1)(OR22)(Ar = 2,6-disubstituted phenyl; R2= Et or Pri) illustrates one of the first examples of a well defined, Lewis acid free, homogeneous olefin metathesis catalyst, for which the activity and stereoselectivity can be governed by the nature of the aryloxide ligands and of the co-ordinated ether and which shows a wide range of potential applications.

  W（OAr）2 Cl（CHR）（CH 2 R 1）（OR 2 2）（Ar = 2,6-二取代苯基; R 2 = Et或Pr i）的合成说明了孔的第一个例子定义为无路易斯酸的均相烯烃复分解催化剂，其活性和立体选择性可以由芳基氧化物配体和配位醚的性质决定，并显示出广泛的潜在应用。
• Kerschner, Judith L.; Rothwell, Ian P.; Huffman, John C., Organometallics, 1988, vol. 7, # 8, p. 1871 - 1873
  作者：Kerschner, Judith L.、Rothwell, Ian P.、Huffman, John C.、Streib, William E.

  DOI：——

  日期：——
• Kerschner, Judith L.; Fanwick, Philip E.; Rothwell, Ian P., Organometallics, 1989, vol. 8, # 6, p. 1431 - 1438
  作者：Kerschner, Judith L.、Fanwick, Philip E.、Rothwell, Ian P.、Huffman, John C.

  DOI：——

  日期：——
• Quignard, Francoise; Leconte, Michel; Basset, Jean-Marie, Inorganic Chemistry, 1987, vol. 26, # 25, p. 4272 - 4277
  作者：Quignard, Francoise、Leconte, Michel、Basset, Jean-Marie、Hsu, Leh-Yeh、Alexander, John J.、Shore, Sheldon G.

  DOI：——

  日期：——
• The metathesis of polyunsaturated fatty esters using the homogeneousW(O-2,6-C6H3X2)2Cl4/Me4Sn catalytic systems
  作者：B Marvey

  DOI：10.1016/j.molcata.2003.11.026

  日期：2004.4.13

  Promoted with a small amount of Me4Sn, W(O-2,6-C6H3X2)(2)Cl-4 (X = Ph, Cl) complexes are highly active metathesis catalysts for polyunsaturated fatty esters. Upon metathesis of methyl linoleate, substrate conversions of ca. 95 and 78% were obtained in 2h with the W(O-2,6-C6H3Ph2)(2)Cl-4/Me4Sn and W(O-2,6-C6H3Cl2)(2)Cl-4/Me4Sn catalytic systems respectively. ne lower activity of the W(O-2,6-C6H3Cl2)(2)Cl-4/Me4Sn catalytic system was attributed to the highly deactivating nature of the Cl substituents on the o,o'-position of the aryloxide ligand. Highly electron-withdrawing Cl substituents cause the tungsten atom to be electron-deficient and thus more susceptible to attack by the electron-rich ester groups. However, the W(O-2,6-C6H3Cl2)(2)Cl-4/Me4Sn system was more selective towards dicarboxylic esters. The latter are interesting starting materials for the synthesis of polyesters and polyamides. The W(O-2,6-C6H3X2)(2)Cl-4/Me4Sn catalytic systems were rapidly deactivated by bromine-containing olefinic esters. Deactivation was attributed to a side reaction between the Br-group and the electron-deficient W-centre. (C) 2003 Elsevier B.V. All rights reserved.