4-[2-(4-甲基吡啶-2-基)吡啶-4-基]丁烷-2-醇 | 870078-13-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 4-[2-(4-甲基吡啶-2-基)吡啶-4-基]丁烷-2-醇
• 英文名称: 4-(4'-methyl-[2,2']bipyridynyl-4-yl)butan-2-ol
• 英文别名: 4-(4'-Methyl-[2,2'-bipyridin]-4-yl)butan-2-ol；4-[2-(4-methylpyridin-2-yl)pyridin-4-yl]butan-2-ol
• CAS: 870078-13-0
• 化学式: C₁₅H₁₈N₂O
• 分子量: 242.321
• InChiKey: UZBGOAGTUKTUBX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  46
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 海关编码：
  2933399090
• 储存条件：
  存储条件：2-8°C，密封保存，并保持干燥。

反应信息

• 作为反应物：
  描述：

  4-[2-(4-甲基吡啶-2-基)吡啶-4-基]丁烷-2-醇 、 exo-5-norbornene-2-carboxylic acid 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 以42%的产率得到exo-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid 1-methyl-3-(4'-methyl-[2,2']bipyridinyl-4-yl)propyl ester
  参考文献：
  名称：

  Phosphorescent Side-Chain Functionalized Poly(norbornene)s Containing Iridium Complexes

  摘要：

  Norbornenes containing phosphorescent iridium complexes based on Ir(ppy)(3) and Ir(ppy)(2)-(bpy)(PF6) were synthesized and copolymerized with alkylnorbornenes via ring-opening metathesis polymerization in nonpolar solvents using ruthenium initiators. The luminescent properties of the resulting polymers both in solution and in the solid state were tested. The polymers were found to retain the optical properties of the phosphorescent small molecule analogues with emission maxima in the yellow/green, quantum yields from 0.23 to 0.24 for Ir(ppy)(2)(bpy)(PF6) analogues, 0.02 to 0.03 for mer-Ir(ppy)(3) analogues, and 0.20 to 0.24 for fac-Ir(ppy)(3) analogues, and lifetimes of 0.41 to 0.55 mu s for Ir(ppy)(2)(bpy)(PF6) analogues, 0.22 to 0.62 mu s for mer-Ir(ppy)(3) analogues, and 1.28 to 1.48 mu s for fac-Ir(ppy)(3) analogues. By combining the phosphorescent properties of these emissive molecules with the solution processability and ease of synthesis of polynorbornene backbones, these materials might be highly useful in the field of light-emitting devices and emissive display technology.

  DOI：

  10.1021/ma0512298
• 作为产物：
  描述：

  4,4'-二甲基-2,2'-联吡啶 、 methyloxirane 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 1.0h， 以73%的产率得到4-[2-(4-甲基吡啶-2-基)吡啶-4-基]丁烷-2-醇
  参考文献：
  名称：

  Phosphorescent Side-Chain Functionalized Poly(norbornene)s Containing Iridium Complexes

  摘要：

  Norbornenes containing phosphorescent iridium complexes based on Ir(ppy)(3) and Ir(ppy)(2)-(bpy)(PF6) were synthesized and copolymerized with alkylnorbornenes via ring-opening metathesis polymerization in nonpolar solvents using ruthenium initiators. The luminescent properties of the resulting polymers both in solution and in the solid state were tested. The polymers were found to retain the optical properties of the phosphorescent small molecule analogues with emission maxima in the yellow/green, quantum yields from 0.23 to 0.24 for Ir(ppy)(2)(bpy)(PF6) analogues, 0.02 to 0.03 for mer-Ir(ppy)(3) analogues, and 0.20 to 0.24 for fac-Ir(ppy)(3) analogues, and lifetimes of 0.41 to 0.55 mu s for Ir(ppy)(2)(bpy)(PF6) analogues, 0.22 to 0.62 mu s for mer-Ir(ppy)(3) analogues, and 1.28 to 1.48 mu s for fac-Ir(ppy)(3) analogues. By combining the phosphorescent properties of these emissive molecules with the solution processability and ease of synthesis of polynorbornene backbones, these materials might be highly useful in the field of light-emitting devices and emissive display technology.

  DOI：

  10.1021/ma0512298

文献信息

• Phosphorescent Side-Chain Functionalized Poly(norbornene)s Containing Iridium Complexes
  作者：Joseph R. Carlise、Xian-Yong Wang、Marcus Weck

  DOI：10.1021/ma0512298

  日期：2005.11.1

  Norbornenes containing phosphorescent iridium complexes based on Ir(ppy)(3) and Ir(ppy)(2)-(bpy)(PF6) were synthesized and copolymerized with alkylnorbornenes via ring-opening metathesis polymerization in nonpolar solvents using ruthenium initiators. The luminescent properties of the resulting polymers both in solution and in the solid state were tested. The polymers were found to retain the optical properties of the phosphorescent small molecule analogues with emission maxima in the yellow/green, quantum yields from 0.23 to 0.24 for Ir(ppy)(2)(bpy)(PF6) analogues, 0.02 to 0.03 for mer-Ir(ppy)(3) analogues, and 0.20 to 0.24 for fac-Ir(ppy)(3) analogues, and lifetimes of 0.41 to 0.55 mu s for Ir(ppy)(2)(bpy)(PF6) analogues, 0.22 to 0.62 mu s for mer-Ir(ppy)(3) analogues, and 1.28 to 1.48 mu s for fac-Ir(ppy)(3) analogues. By combining the phosphorescent properties of these emissive molecules with the solution processability and ease of synthesis of polynorbornene backbones, these materials might be highly useful in the field of light-emitting devices and emissive display technology.