trans-1,2,3,3,3-Pentafluoro-1-phenoxypropene | 56436-73-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-1,2,3,3,3-Pentafluoro-1-phenoxypropene
• 英文别名: trans-1,2,3,3,3-Pentafluor-1-phenoxy-propen-(1)；[(E)-1,2,3,3,3-pentafluoroprop-1-enoxy]benzene
• CAS: 56436-73-8
• 化学式: C₉H₅F₅O
• 分子量: 224.13
• InChiKey: RNSJSCNGQYXLKT-FPLPWBNLSA-N

物化性质

• 沸点：
  159.2±40.0 °C(Predicted)
• 密度：
  1.342±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  sodium phenoxide 、 六氟丙烯 、 二氧化碳 生成 trans-1,2,3,3,3-Pentafluoro-1-phenoxypropene
  参考文献：
  名称：

  ARNOLD-STANTON, REGINA;LEMAL, DAVID M., J. ORG. CHEM., 56,(1991) N, C. 151-157

  摘要：

  DOI：

文献信息

• Tandem nucleophilic additions of aryloxides
  作者：Regina Arnold-Stanton、David M. Lemal

  DOI：10.1021/jo00001a031

  日期：1991.1

  Hydroquinone disodium salt added sequentially to tetrafluoroethylene and carbon dioxide to yield a symmetrical dicarboxylic acid, which was transformed into the corresponding dimethyl ester, diol, diamide, and diamine. Chlorotrifluoroethylene in analogous reactions gave the corresponding diester and diol in excellent yield. When this kind of transformation was attempted on phloroglucinol, the Kolbe-Schmitt carboxylation reaction intervened. Despite serious competition from addition/elimination processes under typical reaction conditions, the tandem addition of phenoxide ion to hexafluoropropene and carbon dioxide was carried out successfully at lower temperatures and higher carbon dioxide pressures.
• US5032301A
  申请人：——

  公开号：US5032301A

  公开（公告）日：1991-07-16
• US5104559A
  申请人：——

  公开号：US5104559A

  公开（公告）日：1992-04-14
• [EN] FLUORINATED AROMATICS AND METHODS OF USING SAME<br/>[FR] COMPOSÉS AROMATIQUES FLUORÉS ET LEURS PROCÉDÉS D'UTILISATION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2020250104A1

  公开（公告）日：2020-12-17

  An apparatus for heat transfer includes a device and a mechanism for transferring heat to or from the device. The mechanism includes a working fluid that includes a fluorinated aromatic compound having structural formula (I): where Q is a carbon atom or a nitrogen atom; G is an oxygen atom or a sulfur atom; each R1 is, independently, a fluoroalkenyl group having 2 to 11 carbon atoms and optionally comprises one or more catenated heteroatoms; each R2 is, independently, (i) a hydrogen atom or a fluorine atom; or (ii) a fluoroalkyl group or a fluoroalkenyl group having 1 to 9 carbon atoms and optionally comprises one or more catenated heteroatoms; each R3 is, independently, a hydrogen atom or a fluorine atom; x is 1-3; a is 1-2; y is 1-5; when Q is a carbon atom, z = 6-y-a; and when Q is a nitrogen atom, z =5-y-a.
• ARNOLD-STANTON, REGINA;LEMAL, DAVID M., J. ORG. CHEM., 56,(1991) N, C. 151-157
  作者：ARNOLD-STANTON, REGINA、LEMAL, DAVID M.

  DOI：——

  日期：——