[Me2Si(η(5)-C5Me4)2]YCH(SiMe3)2 | 177912-67-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: [Me2Si(η(5)-C5Me4)2]YCH(SiMe3)2
• 英文别名: (Me2Si(C5Me4)2)YCH(TMS)2；dimethyl-bis(2,3,4,5-tetramethylcyclopenta-2,4-dien-1-yl)silane;trimethyl(trimethylsilylmethyl)silane;yttrium(3+)
• CAS: 177912-67-3；138286-11-0
• 化学式: C₂₇H₄₉Si₃Y
• 分子量: 546.848
• InChiKey: XDHGGASIWFZVHU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  氢气 、 [Me2Si(η(5)-C5Me4)2]YCH(SiMe3)2 以 petroleum ether 为溶剂， 以99%的产率得到Y2[μ2-((η(5)-C5Me4)SiMe2(η(5)-C5Me4))]2(μ2-H)2
  参考文献：
  名称：

  Coughlin, E. Bryan; Henling, Lawrence M.; Bercaw, John E., Inorganica Chimica Acta, 1996, vol. 242, # 1-2, p. 205 - 210

  摘要：

  DOI：
• 作为产物：
  描述：

  bis(trimethylsilyl)methyllithium 、 ((η(5)-C5Me4)2SiMe2)Y(μ-Cl)2Li(OEt2)2 以 甲苯 为溶剂， 以33%的产率得到[Me2Si(η(5)-C5Me4)2]YCH(SiMe3)2
  参考文献：
  名称：

  Coughlin, E. Bryan; Henling, Lawrence M.; Bercaw, John E., Inorganica Chimica Acta, 1996, vol. 242, # 1-2, p. 205 - 210

  摘要：

  DOI：

文献信息

• Ancillary Ligand Effects on Organo-f-Element Reactivity. <i>ansa</i>-Metallocenes with Bridge-Tethered Donors
  作者：Peter W. Roesky、Charlotte L. Stern、Tobin J. Marks

  DOI：10.1021/om970483o

  日期：1997.10.1

  The synthesis and reactivity of ansa-metallocenes based upon the new ligand system R(Me)SiCp ''(2-)(2)(Cp '' = C5Me4 and R = (CH2)(n)OMe, n = 3-5) is reported. The tethered donor functionality, which is appended via varying chain lengths to the silicon bridge, is introduced to examine possible intramolecular reactivity modifications. The key step of the ligand synthesis is the hydrosilylative fusion of the donor functionality R to the silicon center. The complexes [R(Me)SiCp ''(2)]LnCH(SiMe3)(2) (Ln = Y, Sm) were synthesized to investigate the influence of the tethered ether group on the reactivity and catalytic properties. Catalytic reactions in which the substrate is a relatively weak donor, such as in olefin hydrogenation, exhibit depressed turnover frequencies, presumably reflecting competition between the substrate and donor functionality for the empty coordination site at the metal center. In contrast, for amino-alkene hydroamination/cyclization in which a strong amine donor is the substrate, catalytic activity is significantly enhanced while diastereoselectivity is essentially unchanged. The molecular structure of the precatalyst [MeO(CH2)(5)(Me)SiCp ''(2)]YCH(SiMe3)(2) has been determined by X-ray diffraction.