[Fe(octaethylporphyrin)(piperidine)2][ClO4] | 1365453-20-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: [Fe(octaethylporphyrin)(piperidine)2][ClO4]
• CAS: 1365453-20-8
• 化学式: C₄₆H₆₆FeN₆*ClO₄
• 分子量: 858.368
• InChiKey: OIYIRUWMZPSEKR-NKACYDBVSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Fe(octaethylporphyrin)(piperidine)2][ClO4] 以 二氯甲烷 为溶剂， 生成 哌啶 、 (octaethylporphinato)iron(III) perchlorate
  参考文献：
  名称：

  Axial ligation of iron(III) porphyrin with a series of aliphatic bases: Piperazine, Piperidine and Pyrrolidine

  摘要：

  The binding of a series of nitrogen donor ligands (Piperazine (Pipz), Piperidine (Pip) and Pyrrolidine (Pyr)) to iron porphyrin, OEPFeClO4, where OEP is octaethylporphyrin, has been characterized by electronic spectroscopy in CH2Cl2. In nonaqueous media, in the presence of a neutral ligand, the equilibria observed are: OEPFeClO4 + 2L reversible arrow [OEPFeL2]+ClO4- (beta(2)) where the product is an ion pair and in some cases: OEPFeClO4 + L reversible arrow OEPFeLClO4 (K-1), where the product may either be the six-coordinate or the five-coordinate [OEPFeL]+ClO4- ion pair, that L denotes neutral N-donor ligands. This behavior for the nitrogen donor ligands (L = Pipz, Pip, Pyr) is confirmed by spectrophotometric titrations data and the binding constants for the substitution reaction have been reported.

  DOI：

  10.1134/s0036023612010184
• 作为产物：
  描述：

  哌啶 、 (octaethylporphinato)iron(III) perchlorate 以 二氯甲烷 为溶剂， 生成 [Fe(octaethylporphyrin)(piperidine)2][ClO4]
  参考文献：
  名称：

  Axial ligation of iron(III) porphyrin with a series of aliphatic bases: Piperazine, Piperidine and Pyrrolidine

  摘要：

  The binding of a series of nitrogen donor ligands (Piperazine (Pipz), Piperidine (Pip) and Pyrrolidine (Pyr)) to iron porphyrin, OEPFeClO4, where OEP is octaethylporphyrin, has been characterized by electronic spectroscopy in CH2Cl2. In nonaqueous media, in the presence of a neutral ligand, the equilibria observed are: OEPFeClO4 + 2L reversible arrow [OEPFeL2]+ClO4- (beta(2)) where the product is an ion pair and in some cases: OEPFeClO4 + L reversible arrow OEPFeLClO4 (K-1), where the product may either be the six-coordinate or the five-coordinate [OEPFeL]+ClO4- ion pair, that L denotes neutral N-donor ligands. This behavior for the nitrogen donor ligands (L = Pipz, Pip, Pyr) is confirmed by spectrophotometric titrations data and the binding constants for the substitution reaction have been reported.

  DOI：

  10.1134/s0036023612010184