[ReH2(nitrosyl)(triphenylphosphine)3] | 58694-74-9

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物
• 英文名称: [ReH2(nitrosyl)(triphenylphosphine)3]
• 英文别名: [ReH2(NO)(PPh3)3]
• CAS: 58694-74-9
• 化学式: C₅₄H₄₇NOP₃Re
• 分子量: 1005.1
• InChiKey: HFQUTGDOSFDJQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [ReH2(nitrosyl)(triphenylphosphine)3] 在 PPh₃ 、 HCl 作用下， 以 乙醇 为溶剂， 以95%的产率得到nitrosotris(triphenyl-l5-phosphaneyl)rhenium(VI) chloride
  参考文献：
  名称：

  Stanley Cameron; Grundy, Kevin R.; Robertson, Katherine N., Inorganic Chemistry, 1982, vol. 21, # 12, p. 4149 - 4155

  摘要：

  DOI：
• 作为产物：
  描述：

  methoxy(nitroso)bis(triphenyl-l5-phosphaneyl)rhenium(VI) chloride 、 sodium tetrahydroborate 在 PPh₃ 作用下， 以 乙醇 为溶剂， 以91%的产率得到[ReH2(nitrosyl)(triphenylphosphine)3]
  参考文献：
  名称：

  Stanley Cameron; Grundy, Kevin R.; Robertson, Katherine N., Inorganic Chemistry, 1982, vol. 21, # 12, p. 4149 - 4155

  摘要：

  DOI：

文献信息

• Classical and Nonclassical Nitrosyl Hydride Complexes of Rhenium in Various Oxidation States
  作者：Dimitri Gusev、Angela Llamazares、Georg Artus、Heiko Jacobsen、Heinz Berke

  DOI：10.1021/om980630y

  日期：1999.1.1

  The paramagnetic rhenium complex [NEt4]2[Re(Br)5(NO)] (1) has been used to prepare a series of novel mononitrosyl hydride and dihydrogen rhenium complexes:  [Re(Br)2(NO)(η2-H2)(PR3)2] (R = iPr, 2a; Cy, 2b) and [Re(H)(BH4)(NO)(PR3)2] (R = iPr, 3a; Cy, 3b). The coordinated BH3 of the derivatives 3 can be replaced by the H2 or the NO ligand, thus leading to the tetrahydride and dinitrosyl species [Re(H)4(NO)L2]

  顺磁铼络合物[净4 ] 2 [回复（BR）5（NO）]（1）已被用于制备一系列新mononitrosyl氢化物和二氢铼配合物：[再（BR）2（NO）（η 2 -H 2）（PR 3）2 ]（R = i Pr，2a ; Cy，2b）和[Re（H）（BH 4）（NO）（PR 3）2 ]（R = i Pr，3a ; Cy ，3b）。衍生物3的配位BH 3可以被H取代2或NO配体，从而生成四氢化物和二亚硝酰基物质[Re（H）4（NO）L 2 ]（R = i Pr，4a ; Cy，4b）或[Re（H）（NO）2（PR 3）2 ]（R = i Pr，5a ; Cy，5b）。尽管[Re（H）4（NO）（PPh 3）2 ]似乎不稳定，但是[Re（H）（NO）2（PPh 3）2 ]（5c）的获得方式与[Re（H）（BH）的反应制备3a，b4）（NO）（PPh 3）2 ]和NOBF 4。对3a，b与NOBF 4
• Preparation of bis(aryldiazene) and new aryldiazenido complexes of rhenium
  作者：Gabriele Albertin、Stefano Antoniutti、Fabio Bredariol

  DOI：10.1016/s0022-328x(03)00589-8

  日期：2003.8

  (μ-HNNArArNNH)](BPh 4 ) 4 complexes (ArAr=4,4′-C 6 H 4 C 6 H 4 , 4,4′-C 6 H 4 CH 2 C 6 H 4 ) were also prepared. The reaction of the triphenylphosphine ReH 2 (NO)(PPh 3 ) 3 complex with aryldiazonium cations was studied and led exclusively to mono-aryldiazene [ReH(ArNNH)(NO)(PPh 3 ) 3 ]BPh 4 and [ReH(NO)(PPh 3 ) 3 } 2 (μ-HNNArArNNH)](BPh 4 ) 2 derivatives. The complexes were characterised spectroscopically

  摘要 通过与ReH 2 (NO)(PPh 3 ) 3 反应制备混合配体氢化物ReH 2 (NO)L(PPh 3 ) 2 配合物[L=P(OEt) 3 或PPh(OEt) 2 ]。含有过量的亚磷酸盐。用等摩尔量的芳基重氮阳离子 ArN 2 + 处理 ReH 2 (NO)L(PPh 3 ) 2 氢化物得到单芳基重氮[ReH(ArNNH)(NO)L(PPh 3 ) 2 ]BPh 4 配合物( Ar=C 6 H 5 , 4-CH 3 C 6 H 4 )，而用过量的ArN 2 + 处理产生双(芳基重氮) [Re(ArNNH) 2 (NO)L(PPh 3 ) 2 ]( BPh 4 ) 2 衍生物。双核[ReH(NO)L(PPh 3 ) 2 } 2 (μ-HNNArArNNH)](BPh 4 ) 2 和[Re(4-CH 3 C 6 H 4 NNH)( NO)L(PPh 3 ) 2 } 2
• Preparation of rhenium hydride complexes with pyrazole and pyrazolato ligands
  作者：Gabriele Albertin、Stefano Antoniutti、Alessia Bacchi、Giancarlo Pelizzi、Marika Tollon

  DOI：10.1016/j.jorganchem.2005.07.010

  日期：2005.11

  pyrazolato and the pyrazole ligands was established both in the solid state and in solution. Protonation reaction with Brønsted acid of compound 1 was studied and led to the unstable bis(pyrazole) [ReH(Hpz)2(NO)(PPh3)2]+ cation. Acetylide-pyrazolato Re(CCAr)(Rpz)(HRpz)(NO)(PPh3)2 (3, 4) complexes (Ar = Ph, p-tolyl; R = H, 5-Me) were also prepared by reacting hydride ReH(Rpz)(HRpz)(NO)(PPh3)2 species with terminal

  通过允许ReH 2（NO）（PPh 3）制备氢化物-吡唑啉酮ReH（R PZ）（H R PZ）（NO）（PPh 3）2配合物（R  = H（1），5-Me（2）））3衍生物在回流的甲苯中与吡唑（H R PZ）反应。通过光谱（IR和NMR数据）表征复合物，并通过X射线晶体结构测定ReH（5-MePZ）（H-5-MePZ）（NO）（PPh 3）2衍生物。吡唑并与吡唑配体之间的分子内氢键N–H⋯N既处于固态也处于溶液状态。研究了与化合物1的布朗斯台德酸的质子化反应，并生成了不稳定的双（吡唑）[ReH（HPZ）2（NO）（PPh 3）2 ] +阳离子。乙炔化-pyrazolato的Re（CCAR）（- [R PZ）（H - [R PZ）（NO）（PPH 3）2（3，4）配合物（AR = PH，p ;甲苯基- [R 还制备= H，5-Me）的通过使氢化物ReH（R PZ）（H R PZ）（NO）（PPh）反应3）2种具有在回流的1
• Insertion of heteroallenes into the rhenium–hydride bond
  作者：Gabriele Albertin、Stefano Antoniutti、Giovanni Roveda

  DOI：10.1016/j.ica.2005.04.026

  日期：2005.7

  Dithioformato [Reeta(2)-SC(H)S}(NO)P-3]BPh4 (1), thioformamido [Reeta(2)-RNC(H)S}(NO)P-3]BPh4 (2) (R = Et, p-tolyl), form-amido [Reeta(2)-PhNC(H)O}(NO)P-3]BPh4 (3) and formamidinato [Reeta(2)-p-tolylNC(H)Np-tolyl}(NO)P-3]BPh4 (4) (P = PPh2OEt) complexes were prepared by allowing the hydride ReH2(NO)P-3 to react first with triflic acid and then with the appropriate heteroallene CS2, RNCS, PhNCO and p-tolyINCNp-tolyl. Treatment of the ReH2(NO)L(PPh3)(2) [L = P(OEt)(3), PPh(OEt)(2)] and ReH2(NO) (PPh3)(3) hydrides first with triflic acid and then with isothiocyanate RNCS (R = Et, p-tolyl) gave the [Reeta(2)-RNC(H)S}(NO) P(OEt)(3)}(PPh3)(2)]BPh4 (5, 6) and [Re(eta(2)-RNC(H)S)(NO)(PPh3)(3)]BPh4 (7) derivatives. Depending on the nature of the phosphite, instead, the reaction of ReH2(NO)L(PPh3)(2) and ReH2(NO)(PPh3)(3) hydrides first with CF3SO3H and then with isocyanate RINCO (R1 = Ph, p-tolyl) gave the chelate [Reeta(2)-R1NC(H)O}(NO)P(OEt)(3)}(PPh3)(2)]BPh4 (8) and [Reeta(2)-RINC(H)O} (NO)(PPh3)(3)]BPh4 (10) complexes with P(OEt)(3) or PPh3, while the eta(1)-coordinate [Reeta(1)-RNC(H)S}(NO)PPh(OEt)(2)}(2)(PPh3)(2)]BPh4 (9) derivative was obtained with the PPh(OEt)(2) phosphite ligand. eta(1)-Coordinate dithioformato [Reeta(1)-SC(H)=S}(NO) PPh(OEt)(2)}(2)(PPh3)(2)]BPh4 (11) and formato [Reeta(1)-OC(H)=O}(NO)PPh(OEt)(2)}(2)(PPh3)(2)]BPh4 (12) complexes, as well as the formamidinato [Reeta(2)-p-tolylNC(H)Np-tolyl}(NO)P(OEt)(3)}(PPh3)(2)]BPh4 (13) derivative were also prepared. (c) 2005 Elsevier B.V. All rights reserved.
• Grundy, Kevin R.; Robertson, Katherine N., Inorganic Chemistry, 1985, vol. 24, # 23, p. 3898 - 3903
  作者：Grundy, Kevin R.、Robertson, Katherine N.

  DOI：——

  日期：——