3-(4-Ethoxyphenyl)-3-methyl-2-butanone | 89765-17-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-(4-Ethoxyphenyl)-3-methyl-2-butanone
• 英文别名: 3-(p-ethoxyphenyl)-3-methyl-2-butanone；2-(4-ethoxyphenyl)-2-methyl-3-butanone；2-Butanone, 3-(4-ethoxyphenyl)-3-methyl-；3-(4-ethoxyphenyl)-3-methylbutan-2-one
• CAS: 89765-17-3
• 化学式: C₁₃H₁₈O₂
• 分子量: 206.285
• InChiKey: JPOPBFXQDOKVGJ-UHFFFAOYSA-N

物化性质

• 沸点：
  115 °C(Press: 4 Torr)
• 密度：
  0.981±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-(4-Ethoxyphenyl)-3-methyl-2-butanone 生成 1-(3-phenoxy-4-fluorophenyl)-4-(4-ethoxyphenyl)-4-methyl-1-penten-3-one
  参考文献：
  名称：

  NAKATANI, KIYOSHI;NUMATA, SATOSHI;KODAKA, KENJI;ODA, KENGO;SHIRAISHI, SHI+

  摘要：

  DOI：
• 作为产物：
  描述：

  硫酸二乙酯 、 3-(p-hydroxyphenyl)-3-methyl-2-butanone 在 sodium hydroxide 作用下， 以80%的产率得到3-(4-Ethoxyphenyl)-3-methyl-2-butanone
  参考文献：
  名称：

  3-(对烷氧基苯基)-3-甲基-2-丁酮的简便合成

  摘要：

  摘要 描述了一种通过简单的 AlCl3 催化对乙氧基新戊苯酮的重排制备 3-(对羟基苯基)-3-甲基-2-丁酮的新方法，收率极好。已经通过酚类化合物的 O-烷基化合成了各种 3-(对烷氧基苯基)-3-甲基-2-丁酮。

  DOI：

  10.1080/00397919508011795

文献信息

• Certain aryl-alkane-2-pyridyloxy-phenyl derivatives having insecticidal
  申请人：Mitsui Toatsu Chemicals, Inc.

  公开号：US04661501A1

  公开（公告）日：1987-04-28

  The present invention relates to novel aromatic alkane derivatives represented by the following general formula (I): ##STR1## wherein Ar stands for a substituted or unsubstituted phenyl or naphthyl group, R.sup.1 stands for a methyl, ethyl or isopropyl group and R.sup.2 stands for a hydrogen atom or a methyl group, or R.sup.1 and R.sup.2 together with the carbon to which they are attached jointly represent a substituted or unsubstituted cycloalkyl group and R.sup.3, stands for a fundamental group of an alcohol which is usually used in a form of R.sup.3 OH as to natural or synthetic pyrethroids, and also to the uses of these compounds. These compounds of the present invention have excellent insecticidal and acaricidal activities while the toxicities of these compounds are very low.

  本发明涉及一种新的芳香族烷基衍生物，其通式如下（I）：##STR1## 其中，Ar代表取代或未取代的苯基或萘基，R1代表甲基、乙基或异丙基基团，R2代表氢原子或甲基基团，或者R1和R2与它们连接的碳原子共同表示取代或未取代的环烷基团，R3代表通常以R3OH形式使用的醇基团，用于天然或合成拟除虫菊酯，以及这些化合物的用途。本发明的这些化合物具有优异的杀虫和杀螨活性，而这些化合物的毒性非常低。
• 1,4-diaryl alkane derivatives having insecticidal and acaricidal activity
  申请人：Mitsui Toatsu Chemicals, Inc.

  公开号：US04814340A1

  公开（公告）日：1989-03-21

  The present invention relates to novel aromatic alkane derivatives represented by the following general formula (I): ##STR1## wherein Ar stands for a substituted or unsubstituted phenyl or naphtyl group, R.sup.1 stands for a methyl, ethyl or isopropyl group and R.sup.2 stands for a hydrogen atom or a methyl group, or R.sup.1 and R.sup.2 together with the carbon to which they are attached jointly represent a substituted or unsubstituted cycloalkyl group, and R.sup.3 stands for a fundamental group of an alcohol which is usually used in a form of R.sup.3 OH as to natural or synthetic pyrethroids, and also to processes for the preparation of these compounds and the uses of these compounds. These compounds of the present invention have excellent insecticidal and acaricidal activities while the toxicities of these compounds are very low.

  本发明涉及以下一般式（I）所表示的新颖芳香族烷衍生物：##STR1## 其中，Ar代表取代或未取代的苯基或萘基，R1代表甲基、乙基或异丙基基团，R2代表氢原子或甲基基团，或者R1和R2与它们所连接的碳原子共同表示取代或未取代的环烷基团，R3代表通常以R3OH形式使用的醇的基团，用于天然或合成拟除虫菊酯的制备过程和这些化合物的用途。本发明的这些化合物具有优异的杀虫和杀螨活性，而这些化合物的毒性非常低。
• Gopalakrishnan, Geetha; Kasinath, Viswanathan; Singh, N. D. Pradeep, Organic Letters, 2002, vol. 4, # 5, p. 781 - 782
  作者：Gopalakrishnan, Geetha、Kasinath, Viswanathan、Singh, N. D. Pradeep

  DOI：——

  日期：——
• Novel synthesis and insecticidal activity of MTI-800, desfluoro MTI-800 and their intermediates
  作者：Geetha Gopalakrishnan、G. Suresh、S. Anandhi

  DOI：10.1002/ps.2780450411

  日期：1995.12

  AbstractA new route to the synthesis of 2‐(4‐ethoxyphenyl)‐2‐methyl‐5‐(3‐phe‐noxyphenyl)pentane (desfluoro MTI‐800) and 2‐(4‐ethoxyphenyl)‐2‐methyl‐5‐(4‐fluoro‐3‐phenoxyphenyl)pentane (MTI‐800) and the insecticidal activities of these compounds and some of the synthetic intermediates against the tobacco caterpillar Spodoptera litura (F.) is reported.
• NAKATANI, KIESI
  作者：NAKATANI, KIESI

  DOI：——

  日期：——