sodium p-benzoylbenzoate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: sodium p-benzoylbenzoate
• 英文别名: sodium 4-benzoylbenzoate；Sodium;4-benzoylbenzoate
• 化学式: C₁₄H₉O₃*Na
• 分子量: 248.213
• InChiKey: YAPHJQHVHMBBDD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.71
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  57.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-溴壬烷 、 sodium p-benzoylbenzoate 以 N,N-二甲基甲酰胺 为溶剂， 生成 4-Benzoylbenzoesaeure-n-nonylester
  参考文献：
  名称：

  Phosphorescence of substituted benzophenones in solution. A probe of hydrocarbon chain conformation in three nonpolar solvents

  摘要：

  DOI：

  10.1021/ja00426a042

文献信息

• Intercalation of Aliphatic Carboxylates in Hydrotalcite Interlayers: Selective Photochemical Hydrogen Abstraction by Benzophenonecarboxylate
  作者：Katsuhiko Takagi、Naoya Saito、Tetsuya Shichi、Yasuhiko Sawaki

  DOI：10.1246/cl.1999.275

  日期：1999.4

  The photochemical hydrogen abstraction of p-benzoylbenzoate ions (BPC) from aliphatic carboxylate ions in LDH (hydrotalcite) interlayers yielded a series of their 1:1 adducts. The product distributions were rather selective as well as distinctive from those of sodium salts and methyl esters in homogeneous solutions without LDH. These results have been discussed on the basis of their mutual disposition

  从 LDH（水滑石）夹层中的脂肪族羧酸根离子对苯甲酰苯甲酸根离子 (BPC) 进行光化学氢提取，产生了一系列 1:1 的加合物。产物分布相当有选择性，并且与不含 LDH 的均相溶液中的钠盐和甲酯的分布不同。这些结果已根据它们在 LDH 层表面上的相互布置进行了讨论。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sc: MVol.D5, 1.4.29, page 308 - 310
  作者：

  DOI：——

  日期：——
• Energy Transfer between <i>p</i>‐Benzoylbenzoate and Europium Ethylenediaminetetraacetate in Water Solution
  作者：R. G. Charles、E. P. Riedel、P. G. Haverlack

  DOI：10.1063/1.1726865

  日期：1966.2.15

  Ultraviolet radiation absorbed by the p-benzoylbenzoate (p-BB−) ion in solution is transferred to an appreciable extent to the europium ethylenediaminetetraacetate (EuEDTA−) ion and is re-emitted as the visible red fluorescence characteristic of Eu3+. Fluorescence intensity is greater in D2O than in water. The fluorescence is quenched by dissolved O2. Although evidence for mixed ligand complexes involving p-BB− and EuEDTA− was obtained, fluorescence seems to result from ultraviolet absorption by free p-BB− ions followed by intermolecular energy transfer to free EuEDTA− ions. The analogous water systems containing o-BB− or m-BB− are nonfluorescent, although all three of the solid hydrated salts Eu(o-BB)3, Eu(m-BB)3, and Eu(p-BB)3 fluoresce brightly at room temperature.
• Organized Photocycloaddition of 4-Benzoylbenzoate with Unsaturated Carboxylates in Hydrotalcite Clay Interlayers
  作者：Tetsuya Shichi、Katsuhiko Takagi、Yasuhiko Sawaki

  DOI：10.1246/cl.1996.781

  日期：1996.9

  Photoirradiation of a mixture of 4-benzoylbenzoate (1) and 4-(2-phenylethenyl)benzoate yielded regioselective oxetanes in the presence of hydrotalcite clay. Similar irradiation of a mixture of 1 and cinnamate gave rise to β-truxinate, but not oxetane. The unexpected formation of oxetanes is understood by the favorable distance between C=O and C=C bonds packed in clay interlayers.
• US6410610B1
  申请人：——

  公开号：US6410610B1

  公开（公告）日：2002-06-25