4-(6,11-Dioxotetracen-5-yl)oxybenzoic acid | 287717-73-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 并四苯
• 英文名称: 4-(6,11-Dioxotetracen-5-yl)oxybenzoic acid
• 英文别名: 4-(6,11-dioxotetracen-5-yl)oxybenzoic acid
• CAS: 287717-73-1
• 化学式: C₂₅H₁₄O₅
• 分子量: 394.383
• InChiKey: RAXMUBBUHVTISM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  30
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.7
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4-(6,11-Dioxotetracen-5-yl)oxybenzoic acid 在 氯化亚砜 作用下， 生成
  参考文献：
  名称：

  Porphyrinic phenoxynaphthacenequinones

  摘要：

  The photophysical properties of porphyrinic phenoxynaphthacenequinones 1 and 2 were investigated to assess their potential use as gated photoinduced electron transfer systems. Although the photophysical properties of the porphyrin chromophores remain unaltered upon derivatization, the photochemical isomerization of the naphthace-nequinone fragment is shut down due to its intimacy with the porphyrin. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)00503-7
• 作为产物：
  描述：

  6-chloro-5,12-naphthacenequinone 在 sodium hydroxide 、 potassium carbonate 作用下， 以 四氢呋喃 、 1,4-二氧六环 为溶剂， 反应 5.0h， 生成 4-(6,11-Dioxotetracen-5-yl)oxybenzoic acid
  参考文献：
  名称：

  控制氢键结合的卟啉-苯氧基萘并苯醌光致变色系统中的光诱导电子转移。

  摘要：

  DOI：

  10.1021/ja002733p

文献信息

• Controlling Photoinduced Electron Transfer within a Hydrogen-Bonded Porphyrin−Phenoxynaphthacenequinone Photochromic System
  作者：Andrew J. Myles、Neil R. Branda

  DOI：10.1021/ja002733p

  日期：2001.1.1
• Porphyrinic phenoxynaphthacenequinones
  作者：Andrew J Myles、Neil R Branda

  DOI：10.1016/s0040-4039(00)00503-7

  日期：2000.5

  The photophysical properties of porphyrinic phenoxynaphthacenequinones 1 and 2 were investigated to assess their potential use as gated photoinduced electron transfer systems. Although the photophysical properties of the porphyrin chromophores remain unaltered upon derivatization, the photochemical isomerization of the naphthace-nequinone fragment is shut down due to its intimacy with the porphyrin. (C) 2000 Elsevier Science Ltd. All rights reserved.