2-bromo-5-(tert-butyldimethylsilyl)pyridine | 1093241-27-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2-bromo-5-(tert-butyldimethylsilyl)pyridine
• 英文别名: 2-bromo-5-tert-butyldimethylsilylpyridine；2-Bromo-5-tert-butyldimethylsilylpyridine；(6-bromopyridin-3-yl)-tert-butyl-dimethylsilane
• CAS: 1093241-27-0
• 化学式: C₁₁H₁₈BrNSi
• 分子量: 272.26
• InChiKey: ZGCOSMBPQGVMDH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.56
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-bromo-5-(tert-butyldimethylsilyl)pyridine 在 Ni(PPh₃)₂Br₂ 、 四乙基碘化铵 锌 作用下， 以 四氢呋喃 为溶剂， 反应 10.0h， 生成 5,5'-bis(tert-butyldimethylsilyl)-2,2'-bipyridine
  参考文献：
  名称：

  EP2192124

  摘要：

  公开号：
• 作为产物：
  描述：

  2,5-二溴吡啶 、 叔丁基二甲硅基三氟甲磺酸酯 在 正丁基锂 作用下， 以 乙醚 、 正己烷 为溶剂， 生成 2-bromo-5-(tert-butyldimethylsilyl)pyridine
  参考文献：
  名称：

  EP2172470

  摘要：

  公开号：

文献信息

• BIPYRIDINE COMPOUND, TRANSITION METAL COMPLEX, AND METHOD FOR PRODUCTION OF CONJUGATED AROMATIC COMPOUND USING THE TRANSITION METAL COMPLEX
  申请人：Asaumi Taku

  公开号：US20100184978A1

  公开（公告）日：2010-07-22

  A bipyridine compound represented by the formula (1): wherein R 1 , R 2 and R 3 each independently represent a C1-C10 alkyl group which may be substituted etc., and R 4 , R 5 , R 6 , R 7 and R 8 each independently represent a hydrogen atom etc., a transition metal complex obtained by contacting a bipyridine compound represented by the formula (1) with a compound of a transition metal belonging to Group 9, 10 or 11, and a method for production of a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups are bonded to an aromatic ring with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) being structurally different from the above-mentioned aromatic compound (A) and having one or two leaving groups bonded to an aromatic ring, in the presence of the transition metal complex.

  一种以式(1)表示的联吡啶化合物：其中R1、R2和R3各自独立地表示可以被取代的C1-C10烷基等，而R4、R5、R6、R7和R8各自独立地表示氢原子等，通过将式(1)表示的联吡啶化合物与属于9、10或11族过渡金属的化合物接触而获得的过渡金属配合物，以及一种制备共轭芳香化合物的方法，包括在过渡金属配合物的存在下，将一个或两个离去基团与芳环结合的芳香化合物（A）与具有与上述芳香化合物（A）相同结构的芳香化合物（A）或结构不同于上述芳香化合物（A）且具有一个或两个离去基团与芳环结合的芳香化合物（B）反应。
• TRANSITION METAL COMPLEX AND PROCESS FOR PRODUCING CONJUGATED AROMATIC COMPOUND USING THE TRANSITION METAL COMPLEX
  申请人：Asaumi Taku

  公开号：US20110046336A1

  公开（公告）日：2011-02-24

  A transition metal complex obtained by contacting a bipyridine compound represented by the formula (1): wherein R 1 , R 2 and R 3 represent a C1-C10 alkyl group which may be substituted, etc., and R 4 and R 5 represent a hydrogen atom etc., with a compound of a transition metal belonging to Group 9, 10 or 11, and a process for producing a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups are bonded to an aromatic ring with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) being structurally different from the above-mentioned aromatic compound (A) and having one or two leaving groups bonded to an aromatic ring, in the presence of said transition metal complex.

  通过将式（1）所表示的联吡啶化合物与属于9、10或11族的过渡金属化合物接触而获得的过渡金属配合物，其中R1、R2和R3代表C1-C10烷基，可以被取代等，而R4和R5代表氢原子等。制备共轭芳香化合物的方法包括，在所述过渡金属配合物的存在下，将一个芳香化合物（A），其中一个或两个离去基团与芳香环相键合，与具有与上述芳香化合物（A）相同结构的芳香化合物（A）或在结构上不同于上述芳香化合物（A）并且具有一个或两个离去基团与芳香环相键合的芳香化合物（B）反应。
• Transition metal complex and process for producing conjugated aromatic compound using the transition metal complex
  申请人：Sumitomo Chemical Company, Limited

  公开号：US08088883B2

  公开（公告）日：2012-01-03

  A transition metal complex obtained by contacting a bipyridine compound represented by the formula (1): wherein R1, R2 and R3 represent a C1-C10 alkyl group which may be substituted, etc., and R4 and R5 represent a hydrogen atom etc., with a compound of a transition metal belonging to Group 9, 10 or 11, and a process for producing a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups are bonded to an aromatic ring with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) being structurally different from the above-mentioned aromatic compound (A) and having one or two leaving groups bonded to an aromatic ring, in the presence of said transition metal complex.

  一种过渡金属配合物，通过将式（1）所代表的联吡啶化合物与属于9、10或11族过渡金属的化合物接触而获得，其中R1、R2和R3代表C1-C10烷基，可以被取代等，R4和R5代表氢原子等。一种制备共轭芳香化合物的方法，包括在上述过渡金属配合物的存在下，将一个芳香化合物（A）中与一个或两个离去基团结合的芳环与具有与上述芳香化合物（A）相同结构的芳香化合物（A）或结构不同于上述芳香化合物（A）且具有一个或两个离去基团结合的芳香化合物（B）反应。
• Bipyridine compound, transition metal complex, and method for production of conjugated aromatic compound using the transition metal complex
  申请人：Sumitomo Chemical Company, Limited

  公开号：US08293905B2

  公开（公告）日：2012-10-23

  A bipyridine compound represented by the formula (1): wherein R1, R2 and R3 each independently represent a C1-C10 alkyl group which may be substituted etc., and R4, R5, R6, R7 and R8 each independently represent a hydrogen atom etc., a transition metal complex obtained by contacting a bipyridine compound represented by the formula (1) with a compound of a transition metal belonging to Group 9, 10 or 11, and a method for production of a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups are bonded to an aromatic ring with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) being structurally different from the above-mentioned aromatic compound (A) and having one or two leaving groups bonded to an aromatic ring, in the presence of the transition metal complex.

  一种由式（1）表示的双吡啶化合物：其中R1、R2和R3各自独立地表示C1-C10烷基，可以被取代等，而R4、R5、R6、R7和R8各自独立地表示氢原子等，通过将由式（1）表示的双吡啶化合物与属于第9、10或11族的过渡金属化合物接触而得到的过渡金属配合物，以及一种制备共轭芳香化合物的方法，包括在过渡金属配合物的存在下，将一个芳香化合物（A），其中一个或两个离去基团与芳香环结合，与具有与上述芳香化合物（A）相同结构的芳香化合物（A）或结构不同于上述芳香化合物（A）并且有一个或两个离去基团与芳香环结合的芳香化合物（B）反应。