2-(2-噻吩甲基)噻吩 | 4341-34-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 中文名称: 2-(2-噻吩甲基)噻吩
• 英文名称: 2,2'-dithienylmethane
• 英文别名: bis(2-thienyl)methane；di(2-thienyl)methane；Di-[2]thienyl-methan；2-(thien-2-ylmethyl)thiophene；2-(thiophen-2-ylmethyl)thiophene
• CAS: 4341-34-8
• 化学式: C₉H₈S₂
• mdl: MFCD00041212
• 分子量: 180.295
• InChiKey: JZSRHKOFXIACDX-UHFFFAOYSA-N

物化性质

• 熔点：
  44.0 to 48.0 °C
• 沸点：
  267°C(lit.)
• 密度：
  1.219±0.06 g/cm3(Predicted)
• LogP：
  2.947 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.111
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2934999090
• 危险性防范说明：
  P261,P305+P351+P338
• 危险性描述：
  H302,H315,H319,H335
• 储存条件：
  存放于惰性气体中，避免与空气接触。

反应信息

• 作为反应物：
  描述：

  2-(2-噻吩甲基)噻吩 在 四氯化碳 、 N-溴代丁二酰亚胺(NBS) 、 氯仿 、 过氧化苯甲酰 作用下， 生成 N-[bis-(5-bromo-[2]thienyl)-methyl]-succinimide
  参考文献：
  名称：

  Gold'farb; Kirmalowa, Zhurnal Obshchei Khimii, 1956, vol. 26, p. 3409,3413

  摘要：

  DOI：
• 作为产物：
  描述：

  双(2-噻吩)酮 在 氢氧化钾 、 一水合肼 、 二乙二醇 作用下， 生成 2-(2-噻吩甲基)噻吩
  参考文献：
  名称：

  Buu-Hoi et al., Bulletin de la Societe Chimique de France, 1955, p. 1583,1585

  摘要：

  DOI：

文献信息

• [EN] INDOLINIUM-DERIVED THIOL/DISULFIDE DYE, DYE COMPOSITION COMPRISNG THIS DYE, PROCESS FOR LIGHTENING KERATIN MATERIALS USING THIS DYE<br/>[FR] COLORANT THIOL/DISULFURE DÉRIVÉ D'INDOLIUM, COMPOSITION COLORANTE COMPRENANT LEDIT COLORANT, PROCÉDÉ D'ÉCLAIRCISSEMENT DE MATÉRIAUX À BASE DE KÉRATINE AU MOYEN DE CE COLORANT
  申请人：OREAL

  公开号：WO2009037348A1

  公开（公告）日：2009-03-26

  The invention relates to the dyeing of keratin materials using indolinium-derived thiol and disulfide fluorescent dyes. The invention relates to a dye composition comprising an indolinium-derived-chromophore thiol or disulfide dye and to a dyeing process with a lightening effect on keratin fibers such as the hair, using said composition. It similarly relates to novel indolinium-derived-chromophore thiol dyes and to the uses thereof in lightening keratin materials. This composition makes it possible to obtain a coloring with a lightening effect which is particularly resistant and visible on dark keratin fibers.

  该发明涉及使用吲哚啉衍生硫醇和二硫化物荧光染料对角蛋白材料进行染色。该发明涉及一种染料组合物，包括一种吲哚啉衍生色团硫醇或二硫化物染料，以及使用该组合物对角蛋白纤维（如头发）进行具有减淡效果的染色过程。它还涉及新型吲哚啉衍生色团硫醇染料及其在减淡角蛋白材料中的用途。该组合物能够实现一种具有减淡效果的染色，特别是在深色角蛋白纤维上表现出耐久性和可见性。
• [EN] DYE COMPOSITION COMPRISING AT LEAST ONE COLORLESS DISULFIDE/THIOL PRECURSOR, AND DYEING PROCESS USING THE COMPOSITION<br/>[FR] COMPOSITION COLORANTE COMPRENANT AU MOINS UN PRÉCURSEUR DE DISULFURE/THIOL INCOLORE ET PROCÉDÉ DE TEINTURE UTILISANT LA COMPOSITION
  申请人：OREAL

  公开号：WO2009040354A1

  公开（公告）日：2009-04-02

  The present invention relates to the dyeing of keratin materials using two colorless dye precursors, at least one of which contains a disulfide/thiol unit, said precursors reacting together chemically to form the color in situ. The process according to the invention makes it possible in the context of certain variants to solve the problems caused by the color generated during the process, while at the same time not degrading the efficacy of the coloration, and especially of the lightening effect. The colorations obtained are moreover powerful, chromatic, sparingly selective, and fast with respect to external agents such as sunlight, perspiration and especially shampoo.

  本发明涉及使用两种无色染料前体对角蛋白材料进行染色，其中至少一种含有二硫化物/巯基单元，这些前体在化学上相互反应以在原位形成颜色。根据本发明的方法使得在某些变体情况下能够解决染色过程中产生的问题，同时不降低染色的功效，特别是减淡效果。所获得的染色品不仅强大、色彩鲜艳、选择性较少，而且对于阳光、汗水和尤其是洗发水等外部因素具有快速的耐久性。
• HEMICYANIN STYRYL THIOL/DISULFIDE DYE, COMPOSITION COMPRISING HEMICYANIN STYRYL THIOL/DISULFIDE DYE, AND METHOD FOR LIGHTENING KERATIN MATERIALS USING HEMICYANIN STYRYL THIOL/DISULFIDE DYE
  申请人：GREAVES Andrew

  公开号：US20090211038A1

  公开（公告）日：2009-08-27

  The present disclosure relates to a novel dye composition for the dyeing and/or lightening of keratin materials, such dye comprising a hemicyanin styryl chromophore thiol or disulfide dye of formula (I) or (II): the organic or mineral acid salts thereof, optical isomers and geometric isomers thereof, and the solvates thereof such as hydrates. The present disclosure further relates to a dyeing process with a lightening effect on keratin materials, in particular keratin fibers, including human keratin fibers such as the hair, using said composition. This composition makes it possible to obtain a coloring with a lightening effect which is particularly resistant and visible on dark keratin fibers.

  本公开涉及一种用于染色和/或轻化角蛋白材料的新型染料组合物，所述染料包括式(I)或(II)的半氰靛基苯乙烯色团硫醇或二硫化物染料：其有机或矿物酸盐、其光学异构体和几何异构体，以及其溶剂化合物，如水合物。本公开还涉及一种对角蛋白材料，特别是角蛋白纤维，包括人类角蛋白纤维如头发，在使用所述组合物时具有轻化效果的染色过程。该组合物能够获得一种特别耐用且在深色角蛋白纤维上可见的具有轻化效果的染色。
• ORGANIC SEMICONDUCTING COMPOUNDS AND RELATED OPTOELECTRONIC DEVICES
  申请人：Polyera Corporation

  公开号：US20170104160A1

  公开（公告）日：2017-04-13

  The present teachings relate to new organic semiconducting compounds and their use as active materials in organic and hybrid optical, optoelectronic, and/or electronic devices such as photovoltaic cells, light emitting diodes, light emitting transistors, and field effect transistors. The present compounds can provide improved device performance, for example, as measured by power conversion efficiency, fill factor, open circuit voltage, field-effect mobility, on/off current ratios, and/or air stability when used in photovoltaic cells or transistors. The present compounds can have good solubility in common solvents enabling device fabrication via solution processes.

  本教学涉及新的有机半导体化合物及其在有机和混合光学、光电子和/或电子器件中作为活性材料的用途，如光伏电池、发光二极管、发光晶体管和场效应晶体管。这些化合物可以提供改进的器件性能，例如通过光电转换效率、填充因子、开路电压、场效应迁移率、开/关电流比以及在光伏电池或晶体管中使用时的空气稳定性等指标来衡量。这些化合物在常见溶剂中具有良好的溶解性，可以通过溶液工艺进行器件制备。
• Base cleavage of substituted [phenyl(2-thienyl)methyl]- and [phenyl(2-furyl)methyl]-trimethylsilane. Stabilization of carbanionic centres by 2-thienyl and 2-furyl groups
  作者：Colin Eaborn、Graziella Pirazzini、Giancarlo Seconi、Alfredo Ricci

  DOI：10.1016/s0022-328x(00)81224-3

  日期：1980.6

  Ph(2-furyl)CH2, 29.6; (2-thienyl)2CH2, 27.1. The effect of the 2-Cl substituent in the thiophen ring is close to that of the p-Cl substituent in the benzene ring, and the effects of the p-Me substituents on the benzene ring are very close to those of the 2-Me substituents on the thiophen or furan rings. The product and rate isotope effects (determined by use of MeOD) are consistent with separation of the

  已确定（2-噻吩基）2 CHSiMe 3和化合物Ph（2-噻吩基）CHSiMe 3和Ph（2-呋喃基）CHSiMe 3及其某些衍生物在25°C下的NaOMEMeOH在25°C的裂解速率。在苯基的m-或p-位或杂环基的5-位上的取代基。结果表明，2-噻吩基和2-呋喃基比苯基更有效地稳定了碳负离子中心，并且可以得出以下近似的p K a值：Ph 2 CH 2，33.4； n 2 ＝1。pH值（2-噻吩基）CH 2，30.0; pH值（2-呋喃基）CH 2，29.6; （2-噻吩基）2 CH 2，27.1。噻吩环中2-Cl取代基的作用与苯环中p -Cl取代基的作用接近，苯环中p -Me取代基的作用与2-Me取代物的作用非常接近噻吩或呋喃环上的取代基。产物和速率同位素效应（通过使用MeOD确定）与速率确定步骤中碳负离子的分离是一致的。

表征谱图