diphenyltellurium di(acetate) | 39652-00-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diphenyltellurium di(acetate)
• 英文别名: diphenyl tellurium diacetate；diphenyltellurium diacetate；Diphenyltellur-diacetat；Diphenyltellurdiacetat；[Acetyloxy(diphenyl)-lambda4-tellanyl] acetate；[acetyloxy(diphenyl)-λ4-tellanyl] acetate
• CAS: 39652-00-1
• 化学式: C₁₆H₁₆O₄Te
• 分子量: 399.901
• InChiKey: RNMBRWKDTIKPHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.37
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  diphenyltellurium di(acetate) 以2%的产率得到
  参考文献：
  名称：

  UEMURA SAKAE; FUKUZAWA SHIN-ICHI; WAKASUGI MIKIO; OKANO MASAYA, J. ORGANOMETALL. CHEM., 1981, 214, NO 3, 319-324

  摘要：

  DOI：
• 作为产物：
  描述：

  dibromo-diphenyl-λ⁴-tellane 以 苯 为溶剂， 生成 diphenyltellurium di(acetate)
  参考文献：
  名称：

  Maksimenko, A. A.; Sadekov, I. D.; Minkin, V. I., Journal of general chemistry of the USSR, 1986, vol. 56, # 11, p. 2304 - 2306

  摘要：

  DOI：

文献信息

• One-pot synthesis, structural analysis, and oxidation applications of a series of diaryltellurium dicarboxylates
  作者：Yuga Shibuya、Anna Toyoda、Shiori Ohmura、Go Higashikawa、Shinichi Koguchi

  DOI：10.1039/d1ra06150j

  日期：——

  efficient one-pot synthesis of a variety of functionalized diaryltellurium dicarboxylates. The method is based on a mild photosensitized oxygenation of cheap and readily available carboxylic acids. The molecular structures of the diaryltellurium dicarboxylates were determined unambiguously using single-crystal X-ray diffraction analysis. The thus obtained diaryltellurium dicarboxylates were used to study

  本文介绍了一种简洁高效的一锅法合成多种官能化二芳基碲二羧酸盐的方法。该方法基于廉价且容易获得的羧酸的温和光敏氧化。使用单晶 X 射线衍射分析明确地确定了二芳基碲二羧酸盐的分子结构。如此获得的二芳基碲二羧酸盐用于研究安息香衍生物的氧化。
• Secondary bonding. Part 13. Aryl-tellurium(<scp>IV</scp>) and -iodine(<scp>III</scp>) acetates and trifluoroacetates. The crystal and molecular structures of bis-(p-methoxyphenyl)tellurium diacetate, µ-oxo-bis[diphenyltrifluoroacetoxytellurium] hydrate, and [bis(trifluoroacetoxy)iodo]benzene
  作者：Nathaniel W. Alcock、W. David Harrison、Colin Howes

  DOI：10.1039/dt9840001709

  日期：——

  The crystal and molecular structures of the title compounds have been determined from diffractometer data by the heavy-atom method, and their preparations are described. Crystals of (p-MeOC6H4)2Te(O2CMe)2(1) are monoclinic, space group P21/c, with unit-cell dimensions a= 9.529(2), b= 11.984(2), c= 17.035(2)Å, β= 101.70(2)°, Z = 4, and for 3 033 observed reflections [I/σ(I) > 3.0], R= 0.022. Crystals

  通过重原子法由衍射仪数据确定了标题化合物的晶体和分子结构，并描述了它们的制备。（p -MeOC 6 H 4）2 Te（O 2 CMe）2（1）的晶体为单斜晶，空间群P 2 1 / c，晶胞尺寸a = 9.529（2），b = 11.984（2） ，c＝ 17.035（2）Å，β＝ 101.70（2）°，Z ＝ 4，并且对于3,033个观察到的反射[ I /σ（I）＞ 3.0]，R＝ 0.022。[Ph 2 Te（O 2CCF 3）] 2 O} 2 ·H 2 O（2）是三斜晶系，空间群P，其像元尺寸为a = 13.988（3），b = 14.287（3），c = 15.689（3）Å，α ＝ 80.40（2），β＝ 81.89（2），γ＝ 86.65（2）°，Z＝ 2，并且对于5290次观察到的反射，R＝ 0.042。PhI（O 2 CCF 3）2（3）晶体是三斜晶系，空间群P，其晶胞尺寸a
• Organotellurium chemistry
  作者：Bhuvan C. Pant

  DOI：10.1016/s0022-328x(00)83885-1

  日期：1974.1

  Diaryltellurium diacetates have been prepared in excellent yields by the oxidation of diaryltellurides with lead tetraacetate and also by the reaction of diaryltellurium dichlorides with silver acetate. Hydrolysis, reduction and exchange reactions of these derivatives and their spectral data are described.

  通过用四乙酸铅氧化二芳基碲化物和通过二氯化二芳基碲与乙酸银的反应，已经以优异的产率制备了二乙酸二芳基碲。描述了这些衍生物的水解，还原和交换反应及其光谱数据。
• A Convenient and General Preparation of Diphenyl Tellurium Dicarboxylates
  作者：Seizo Tamagaki、Isao Hatanaka、Seizi Kozuka

  DOI：10.1246/bcsj.50.2501

  日期：1977.9

  A number of diphenyl tellurium dicarboxylates were readily prepared from diphenyl telluroxide and carboxylic acids or anhydrides. Some of them were also derived through the carboxylate exchange from readily available tellurium carboxylates.

  许多二苯基碲二羧酸盐很容易由二苯基碲氧化物和羧酸或酸酐制备。其中一些还通过羧酸盐交换从容易获得的碲羧酸盐中衍生而来。
• Electrolytic partial fluorination of organic compounds. X. Selective anodic fluorination of organic tellurium compounds
  作者：Toshio Fuchigami、Toshiyasu Fujita、Akinori Konno

  DOI：10.1016/s0040-4039(00)73137-6

  日期：1994.6

  organic tellurium compounds was carried out in the presence of fluoride ions and difluorination occurred at the tellurium atom selectively in excellent yields and with high current efficiencies regardless of their structures. This is the first example of anodic fluorination of tellurides and also that of electrosynthesis of hypervalent tellurides.

  各种类型的有机碲化合物的阳极氧化都是在氟离子的存在下进行的，无论其结构如何，碲原子选择性地以优异的收率和高电流效率在碲原子上发生二氟化。这是碲化物阳极氟化的第一个例子，也是高价碲化物电合成的第一个例子。