2,6-bis(bis(2-benzimidazolylmethyl)aminomethyl)-4-methylphenol | 89514-02-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 2,6-bis(bis(2-benzimidazolylmethyl)aminomethyl)-4-methylphenol
• 英文别名: 2,6-bis[bis(2-benzimidazolylmethyl)aminomethyl]-4-methylphenol；Hbbap；2,6-Bis[bis(2-benzimidazolyl-methyl)aminomethyl]-4-methylphenol；2,6-bis[[bis(1H-benzimidazol-2-ylmethyl)amino]methyl]-4-methylphenol
• CAS: 89514-02-3
• 化学式: C₄₁H₃₈N₁₀O
• 分子量: 686.819
• InChiKey: UHPOPCGQRZHLAI-UHFFFAOYSA-N

物化性质

• 密度：
  1.422±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  52
• 可旋转键数：
  12
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  141
• 氢给体数：
  5
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  2,6-bis(bis(2-benzimidazolylmethyl)aminomethyl)-4-methylphenol 、 copper perchlorate hexahydrate 在 NaN₃ 作用下， 以 甲醇 、 乙醇 为溶剂， 生成
  参考文献：
  名称：

  带有苯并咪唑或硫醚基团的双核配体的双核铜（I）和铜（II）配合物

  摘要：

  [Cu 2（HL）]（ClO 4）2的制备L ＝苯并咪唑或硫醚的配合物。在准备中egalement [Cu 2（L-Bzim）X]（ClO 4）2•xH 2 O avec X = N 3-，CH 3 COO-，[Cu 2（L-Bzim）L 2']（ClO 4） 3•xH 2 O L'= H 2 O，py。结构可能

  DOI：

  10.1016/s0020-1693(00)81819-8
• 作为产物：
  描述：

  2,6-双(氯甲基)-4-甲酚 、 bis(benzimidazol-2-ylmethyl)amine 在 三乙胺 作用下， 以 甲醇 为溶剂， 生成 2,6-bis(bis(2-benzimidazolylmethyl)aminomethyl)-4-methylphenol
  参考文献：
  名称：

  A new chemosensing ensemble for fluorescent recognition of pyrophosphate in water at physiological pH

  摘要：

  A novel chemosensing ensemble that exhibits sensitive and selective recognitions of pyrophosphate in 100% aqueous solution at physiological pH has been developed. The chemosensing ensemble was constructed by a dinuclear Zn(II) complex of 2,6-bis[(bis(2-benzimidazolylmethyl)amino)methyl]-p-cresol and sodium fluorescein, the receptor-indicator pair is able to highly selectively discriminate pyrophosphate from phosphate and other anions in water at physiological pH. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.09.133

文献信息

• Mono- and dinuclear cadmium(II) complexes based on polybenzimidazole-containing tetradentate and heptadentate ligands: Synthesis, structures and fluorescent properties
  作者：Feng-Mei Nie、Min Li、Guo-Xing Li

  DOI：10.1016/j.molstruc.2010.05.007

  日期：2010.8

  supramolecular network through hydrogen bonding and π–π stacking interactions. Both complexes present strong fluorescent emission in the solid state at room temperature. Experiment shows that there is a higher coordination ability of the carboxylate group of 4-chlorobenzoate as coligand with the dinuclear [Cd 2 (bbap)] 3+ core than with the mononuclear [Cd(ntb)] 2+ core.

  摘要 两种新型镉(II)配合物[Cd(ntb)(O 2 CC 6 H 4 - p -Cl)]ClO 4 ·3CH 3 OH ( 1 ) 和[Cd 2 (bbap)(O 2 CC 6 H 4 - p -Cl) 2 ]NO 3 ·3C 2 H 5 OH·H 2 O ( 2 ) 已被合成并通过元素分析、红外、 1 H NMR 和单晶 X 射线衍射进行了结构表征，其中 ntb 是 tris( 2-苯并咪唑基甲基)胺，bbap - 是2,6-双[双(2-苯并咪唑基甲基)氨基甲基]-4-甲基苯酚的阴离子。在配合物1中，镉离子与ntb的四个氮原子和4-氯苯甲酸阴离子的两个氧原子以双齿O,O'-螯合模式配位。在配合物 2 中，两个镉离子被 bbap 的 μ-苯氧基桥结合在一起，Cd1⋯Cd2 的间距为 3.934 A。两个镉离子中的每一个都进一步与二齿 O 中的 4-氯苯甲酸的羧酸根配位， O'-螯合模式
• ACTIVE INGREDIENTS WHICH IMPROVE PRIMARY DETERGENT POWER
  申请人：Henkel AG & Co. KGaA

  公开号：US20170145351A1

  公开（公告）日：2017-05-25

  The aim of the invention is to improve the primary detergent power of washing and cleaning agents, in particular with respect to bleach-sensitive or enzyme-sensitive soiling. This is substantially achieved by the incorporation of alkoxy group-carrying sulfocalixarenes or carboxycalixarenes.

  本发明的目的是提高洗涤和清洁剂的主要洗涤能力，特别是对于对漂白剂敏感或酶敏感的污垢。这主要通过引入携带烷氧基的磺酸卡立克烯或羧基卡立克烯来实现。
• Syntheses and Characterization of Dinuclear High-Spin Iron(II,III) and (III,III) Complexes with 2,6-Bis[bis(2-benzimidazolylmethyl)aminomethyl]-4-methylphenolate(1—)
  作者：Masatatsu Suzuki、Hiroki Oshio、Akira Uehara、Kazutoyo Endo、Makoto Yanaga、Sigeo Kida、Kazuo Saito

  DOI：10.1246/bcsj.61.3907

  日期：1988.11

  Two types of dinuclear high-spin mixed valence iron(II,III) complexes, [Fe2(L-Bzim)(RCOO)2](BF4)2·nH2O (RCOO=CH3COO (1) or C6H5COO (2)), and [Fe2(L-Bzim)(C6H5COO)2(OH)]BF4·H2O (3), and dinuclear high-spin iron(III,III) complexes, [Fe2(L-Bzim)(CH3COO)2](ClO4)3·3.5H2O (4) and [Fe2(L-py)(C6H5COO)2](ClO4)3·CH3CN·H2O (5) were prepared, where L-Bzim is 2,6-bis[bis(2-benzimidazolylmethyl)aminomethyl]-4-methylphenolate(1—)

  两种双核高自旋混合价铁(II,III)配合物，[Fe2(L-Bzim)(RCOO)2](BF4)2·n (RCOO=CH3COO (1) or C6H5COO (2))，和[Fe2(L-Bzim)(C6H5COO)2(OH)] ·H2O (3)，和双核高自旋铁(III,III)配合物，[Fe2(L-Bzim)(CH3COO)2](ClO4)制备了3·3.5 (4)和[Fe2(L-py)(C6H5COO)2]( )3·CH3CN· (5)，其中L-Bzim为2,6-双[双(2-苯并咪唑基甲基) )氨基甲基]-4-甲基苯酚酯(1-)和L-py是2,6-双[双(2-吡啶基甲基)氨基甲基]-4-甲基苯酚酯(1-)。混合价络合物的穆斯堡尔谱表明它们涉及等摩尔量的高自旋铁 (II) 和 (III) 离子。他们的 ESR 光谱在 gav=1.7 附近显示了一个信号，接近液氦温度特征的反铁磁自旋耦合高自旋铁
• Dinuclear Cobalt(II) Complexes with Various Dinucleating Ligands and Their Dioxygen Complexes
  作者：Masatatsu Suzuki、Hajime Kanatomi、Ichiro Murase

  DOI：10.1246/bcsj.57.36

  日期：1984.1

  moments of the complexes revealed that [Co2L(CH3COO)2]ClO4 (L=bpmp, bpmep, or bpep) are high-spin octahedral, whereas the other complexes have five-coordinate structure of high-spin configuration. Some of the bpmp and the bpmep complexes reacted reversibly with molecular oxygen more or less. The P1⁄2 of some complexes were determined spectrometrically. The oxygen affinities of the complexes are highly

  各种类型的双核钴(II)配合物，[Co2L(CH3COO)2] ，[Co2L(CH3COO)](ClO4)2，[CO2L(OH)]( )2，[Co2L(C3H3N2)] )2 ( −)=吡唑酸盐）和 [CO2LX2]( )n，其中 HL 代表 2,6-双[双（2-吡啶基甲基）氨基甲基]-4-甲基苯酚（Hbpmp），2,6-双[N-(2-吡啶基甲基)-2-(2-吡啶基)乙基氨基甲基]-4-甲基苯酚(Hbpmep), 2,6-双[双[2-(2-吡啶基)乙基]氨基甲基]-4-甲基苯酚( Hbpmep) 和 2,6-双[双(2-苯并咪唑基甲基)氨基甲基]-4-甲基苯酚(Hbbimp)，并且 X 是 N3-、NCS-、Cl-、Br-、H2O 或 py(吡啶)。配合物的电子光谱和磁矩表明[Co2L(CH3COO)2] (L=bpmp, bpmep, or bpep)
• Support-fixed bleaching catalyst complex compounds suitable as catalysts for peroxygen compounds
  申请人：——

  公开号：US20040266641A1

  公开（公告）日：2004-12-30

  The present invention relates to support-fixed bleaching catalyst(s)suitable or the catalysis of peroxide compounds, characterized in that the support-fixed bleaching catalyst(s) is/are covalently bonded to a support by means of at least one organic ligand of the bleaching catalyst. The bleaching catalyst(s) form(s) a complex with at least on transition metal. The invention further relates to support-fixed bleaching catalysts for the catalysis of peroxide compounds, where at least one ligand, covalently bonded to a support, is a transition-metal-free ligand, which chelates with transition metal, derived from another source, preferably from the bleaching composition and/or added water and thus forms the complex with a transition metal.

  本发明涉及适用于过氧化物催化的支撑固定漂白催化剂，其特征在于通过漂白催化剂的至少一个有机配体与支撑物共价键合而将支撑固定漂白催化剂共价键合到支撑物上。漂白催化剂与至少一种过渡金属形成复合物。本发明还涉及适用于过氧化物催化的支撑固定漂白催化剂，其中至少一个共价键合到支撑物上的配体是无过渡金属配体，它与来自另一来源的过渡金属螯合，优选地来自漂白组合物和/或加入的水，并因此形成与过渡金属的复合物。