pentyl 4-methylbenzenesulfinate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: pentyl 4-methylbenzenesulfinate
• 化学式: C₁₂H₁₈O₂S
• 分子量: 226.34
• InChiKey: YKIRFBUAFQKGKQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  45.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  对甲苯亚磺酸 、 戊醇 在 异氰基乙酸乙酯 作用下， 以 二氯甲烷 为溶剂， 反应 6.0h， 以96%的产率得到pentyl 4-methylbenzenesulfinate
  参考文献：
  名称：

  异氰化物诱导的亚磺酸酯化以获得亚磺酸盐

  摘要：

  已经开发了异氰化物诱导的亚磺酸与醇或苯硫酚的酯化获得亚磺酸盐。各种伯醇、仲醇和叔醇可以与既定的协议兼容。值得注意的是，这种异氰化物诱导的合成策略具有操作简单、官能团耐受性好、40余例收率高达99%等优点。

  DOI：

  10.1002/adsc.202100915

文献信息

• Composition of cyclic olefin addition copolymer and cross-linked material
  申请人：JSR Corporation

  公开号：EP1195397A1

  公开（公告）日：2002-04-10

  A composition comprising a cyclic olefin addition copolymer containing recurring units of the following formulas (1) and (2), and at least one compound selected from (A) a compound acting as an acid when heated to 50°C or higher, (B) a metal compound of an alkoxy compound, aryloxy compound, carboxyl compound, β-diketone compound, halogen compound, or oxide, (C) an organic carboxylic acid, organic phosphoric acid, organic sulfonic acid, ammonia, primary to tertiary amine compound, or quaternary ammonium hydroxide compound. The composition exhibits excellent optical transparency, solvent resistance, dimensional stability, heat resistance, and adhesion to metals and inorganic materials, and suitable for use in optical transparent materials and electronic material parts, to a cross-linked product obtained by crosslinking the composition via siloxane bonds, and to a film, sheet, or coating made from the composition.

  一种包含环状烯烃加成共聚物的组合物，该共聚物含有以下式子(1)和(2)的重复单元、 和至少一种选自以下化合物的化合物：(A) 当加热到 50°C 或更高温度时起酸作用的化合物；(B) 烷氧基化合物、芳氧基化合物、羧基化合物、β-二酮化合物、卤素化合物或氧化物的金属化合物；(C) 有机羧酸、有机磷酸、有机磺酸、氨、伯胺至叔胺化合物或氢氧化季铵盐化合物。该组合物具有优异的光学透明性、耐溶剂性、尺寸稳定性、耐热性以及与金属和无机材料的粘附性，适用于光学透明材料和电子材料部件、通过硅氧烷键交联该组合物而获得的交联产品，以及由该组合物制成的薄膜、薄片或涂层。
• Resin film and applications thereof
  申请人：JSR CORPORATION

  公开号：US20040106740A1

  公开（公告）日：2004-06-03

  A film for a display device produced by using a transparent (crosslinked) resin film formed of a composition including a cyclic olefin addition copolymer of the present invention has optical transparency, heat resistance, liquid crystal resistance, dimensional stability, and adhesion and is suitably used as an alternative to a glass substrate of a liquid crystal display device and an EL display device. The transparent (crosslinked) resin film can be used as a polarizing film, surface protective film, retardation film, transparent conductive film, light diffusion film, film for an EL display device, transparent conductive composite material, antireflection film, and the like.

  使用由包括本发明环状烯烃加成共聚物在内的组合物形成的透明（交联）树脂薄膜生产的显示设备用薄膜具有光学透明性、耐热性、液晶耐受性、尺寸稳定性和附着力，可适当用作液晶显示设备和电致发光显示设备的玻璃基板的替代品。透明（交联）树脂薄膜可用作偏光膜、表面保护膜、延缓膜、透明导电膜、光扩散膜、EL 显示设备用膜、透明导电复合材料、抗反射膜等。
• US6790914B2
  申请人：——

  公开号：US6790914B2

  公开（公告）日：2004-09-14
• Isocyanide‐Induced Esterification of Sulfinic Acids to Access Sulfinates
  作者：Jianjing Yang、Haozhe Dong、Kelu Yan、Xiaodan Song、Jie Yu、Jiangwei Wen

  DOI：10.1002/adsc.202100915

  日期：2021.12.21

  The isocyanide-induced esterification of sulfinic acids with alcohols or thiophenols access to sulfinates has been developed. Various primary, secondary, and tertiary alcohols could be compatible with the established protocols. Notably, such an isocyanide-induced synthetic strategy presented the advantages of simple operation, good functional group tolerance, and more than 40 examples up to 99% yields

  已经开发了异氰化物诱导的亚磺酸与醇或苯硫酚的酯化获得亚磺酸盐。各种伯醇、仲醇和叔醇可以与既定的协议兼容。值得注意的是，这种异氰化物诱导的合成策略具有操作简单、官能团耐受性好、40余例收率高达99%等优点。