Amidothiophosphorsaeurediphenylester | 19326-23-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Amidothiophosphorsaeurediphenylester
• 英文别名: Imino-diphenoxy-sulfanyl-lambda5-phosphane；imino-diphenoxy-sulfanyl-λ5-phosphane
• CAS: 19326-23-9
• 化学式: C₁₂H₁₂NO₂PS
• 分子量: 265.273
• InChiKey: CTIODMLSMUBNAR-UHFFFAOYSA-N

物化性质

• 熔点：
  112 °C
• 沸点：
  375.9±25.0 °C(Predicted)
• 密度：
  1.319±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  76.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Amidothiophosphorsaeurediphenylester 在 sodium hydroxide 作用下， 生成 amidothiophosphoric acid O-phenyl ester
  参考文献：
  名称：

  Ephraim, Chemische Berichte, 1911, vol. 44, p. 634

  摘要：

  DOI：
• 作为产物：
  描述：

  O,O-diphenyl phosphorochloridothioate 在 氨 作用下， 以 乙醚 为溶剂， 以100%的产率得到Amidothiophosphorsaeurediphenylester
  参考文献：
  名称：

  New mixed-donor unsymmetrical P–N–P ligands and their palladium(II) complexes

  摘要：

  不对称双齿配体 R2P(E)–N(H)–P(E′)R2′ [R, R′ = Ph, OPh, iPr; E, E′ = O, S, Se] 是通过氨化合物 R2P(E)NH2 [R = PhO, Ph; E = O, S, Se] 与磷电亲体 R2′P(E′)Cl [R′ = iPr, Ph, OPh; E′ = O, S, Se] 的缩合反应合成的。去质子化的配体（与 KOtBu 反应）可以与 Pd(OAc)2 反应，生成 [Ph2P(S)–N–P(O)(OPh)2]2Pd、[iPr2P(S)–N–P(O)(OPh)2]2Pd 和 [Ph2P(S)–N–P(S)(OPh)2]2Pd，这些化合物显示出四元或六元螯合环。新化合物通过光谱学（NMR、IR 和拉曼）和 X 射线晶体学进行了研究。

  DOI：

  10.1039/b103501k

文献信息

• A convenient and practical method for the synthesis ofN-thiophosphoryl aldimines and ketimines
  作者：Xinyuan Xu、Chungui Wang、Zhenghong Zhou、Zebing Zeng、Xinpeng Ma、Guofeng Zhao、Chuchi Tang

  DOI：10.1002/hc.20412

  日期：2008.4

  A convenient and practical method for the preparation of N-thiophosphoryl imines was developed through the thermal condensation of acetals with different thiophosphoramides at 120–160°C. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:238–244, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20412

  通过缩醛与不同硫代磷酰胺在 120-160°C 下的热缩合，开发了一种方便实用的制备 N-硫代磷酰亚胺的方法。© 2008 Wiley Periodicals, Inc. 杂原子化学 19:238–244, 2008; 在线发表于 Wiley InterScience (www.interscience.wiley.com)。DOI 10.1002/hc.20412
• Enamide von Phosphorsäure- und Thiophosphorsäureestern. 22. Mitt. über Untersuchungen an Acyl-enaminen
  作者：F. Eiden、E. Schönduve

  DOI：10.1002/ardp.19723050702

  日期：——

  Phosphorsäure‐ und Thiophosphorsäureester‐amide (1a–c, 5) reagieren mit substituierten Acetaldehyden (3a–d) zu den Enamiden 4a–h sowie 6a–d. Diese können durch katalytisches Hydrieren in N‐substituierte Phosphorsäureester‐amide (7a, b), durch Reaktion mit Aldehyden (3b, d) in 3‐Azapentadiene (12a, b) umgewandelt werden.

  磷酸酯和硫代磷酸酯酰胺 (1a – c, 5) 与取代的乙醛 (3a – d) 反应形成烯酰胺 4a – h 和 6a – d。它们可以通过催化氢化转化为 N-取代的磷酸酯酰胺 (7a, b)，并通过与醛 (3b, d) 反应转化为 3- 氮杂戊二烯 (12a, b)。
• The Synthesis and Evalution of Novel Aryl-Substituted Dithioimidophosphonates as an Extrantant for Metals
  作者：Ruiren Tang、Cancheng Gou

  DOI：10.1080/104265090968064

  日期：2005.12

  A novel series of O, O′, O″, O”′-tetraaryldithioimidophonates [(ArO) 2 PS] 2 NH 4 were synthesized by the reaction of O, O,-diaryl phosphorochlorothionates 2 and diarylphosphonothioic amide under a strong basic condition. The key intermediates 2a ∼ 2g were prepared from thiophosphyl chloride and substituted phenols under phase transfer catalysis conditions for the first time. These teteraaryl dithioimidophonates

  通过O,O,-二芳基氯硫代磷酸酯2和二芳基硫代膦酰胺在强碱性条件下反应合成了一系列新型O,O',O",O"'-四芳基二硫代亚氨基膦酸酯[(ArO)2PS]2NH4。以硫代磷酰氯和取代酚为原料，在相转移催化条件下首次制备了关键中间体2a~2g。这些四芳基二硫代亚氨基膦酸酯对来自硫酸盐溶液的 Zn 2 + 比 Fe 3 + 显示出高选择性。还讨论了取代基对标题化合物的 31 P NMR 的影响。
• Non-toxic corrosion-protection pigments based on manganese
  申请人：——

  公开号：US20040011252A1

  公开（公告）日：2004-01-22

  Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

  以锰为基础的缓蚀颜料含有三价或四价锰/价稳定剂复合物。一种无机或有机材料可用于稳定三价或四价锰离子，从而形成一种可少量溶解、溶解度低或不溶于水的化合物，具体取决于预期用途。选择特定的稳定剂是为了控制三价锰或四价锰在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。锰/价稳定剂组合的选择是基于锰配位化学的基本原理。文中介绍了许多锰价稳定剂组合，其性能与传统的六价铬或四价铅体系相当。需要强调的是，提供本摘要是为了符合要求提供摘要的规则，以便检索者或其他读者快速确定技术公开的主题。提交本摘要的前提是，本摘要不用于解释或限制权利要求的范围或含义。
• Non-toxic corrosion-protection pigments based on rare earth elements
  申请人：——

  公开号：US20040104377A1

  公开（公告）日：2004-06-03

  A corrosion-inhibiting pigment comprising a rare earth element and a valence stabilizer combinded to form a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, terbium, praseodymium, or a combination thereof, and at least one rare earth element is in the tetravalent oxidation state. An inorganic or organic material is used to stabilize the tetravalent rare earth ion to form a compound that is sparingly soluble in water. Specific stabilizers are chosen to control the release rate of tetravalent cerium, terbium, or praseodymium during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Many rare earth-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.

  一种缓蚀颜料，由稀土元素和价态稳定剂结合形成稀土/价态稳定剂复合物。稀土元素选自铈、铽、镨或它们的组合，至少有一种稀土元素处于四价氧化态。使用无机或有机材料来稳定四价稀土离子，以形成稀溶于水的化合物。选择特定的稳定剂是为了控制四价铈、铽或镨在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。本文介绍了许多稀土-价稳定剂组合，其性能可与传统的六价铬体系媲美。