dibutylgermane | 29823-30-1

• 分子结构分类: 有机化合物 - 有机金属化合物
• 英文名称: dibutylgermane
• 英文别名: Dibutyl-german；Di-n-butylgerman
• CAS: 29823-30-1
• 化学式: C₈H₂₀Ge
• 分子量: 188.837
• InChiKey: LYDMUSGVFPJYPG-UHFFFAOYSA-N

物化性质

• 沸点：
  70-5°C 15mm
• 密度：
  0,978 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.59
• 重原子数：
  9
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• TSCA：
  No

反应信息

• 作为反应物：
  描述：

  dibutylgermane 以 正己烷 、 氘代甲苯 、 甲苯 为溶剂， 生成 [Pt(C(CO2Me)=C(CO2Me)GeBu2GeBu2GeBu2GeBu2)(1,2-bis(dimethylphosphino)ethane)]
  参考文献：
  名称：

  Chemical Properties of Tetragermaplatinacyclopentane. Insertion of an Alkyne into a Pt–Ge Bond and Silylation Caused by H₂SiPh₂

  摘要：

  A platinum complex having dibutylgermyl ligands, [Pt(GeHBu2)(2)(dmpe)] (dmpe = 1,2-bis(dimethylphosphino)ethane), reacted with excess H-2 GeBu2 at 90 degrees C to yield a five-membered tetragermaplatinacycle, [Pt(GeBu(2)GeBu(2)GeBu(2)G au(2))(dmpe)] (6). The direct reaction of H2GeBu2 with [Pt(dmpe)(2)] in 5:1 ratio also gave 6 in 67% yield. The reaction of dimethyl acetylenedicarboxylate with 6 caused insertion of a C C bond into a Pt-Ge bond to form a seven-membered germaplatinacycloheptene, which was characterized by X-ray crystallography. Complex 6 reacted with H2GePh2 and H2SiPh2 in 1:2 ratio to produce a mixture of tetragermane dihydride H(GeBu2)(4)H and bis(silyl)-or bis(germyl)platinum complexes [Pt(EHPh2)(2)(dmpe)] (E = Si, Ge).

  DOI：

  10.1021/om200275w
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 lithium aluminium tetrahydride 、 二丁醚 作用下， 生成 dibutylgermane
  参考文献：
  名称：

  Satge et al., Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1959, vol. 249, p. 131,132

  摘要：

  DOI：

文献信息

• Selective Chlorination of Germanium Hydrides
  作者：Thomas Hafner、Ana Torvisco、Michael Traxler、Melanie Wolf、Frank Uhlig

  DOI：10.1002/zaac.202000318

  日期：2020.12.31

  Methods for the selective chlorination of organogermylhydrides are given by the selective functionalization of organogermylhydrides of types R3GeH, R2GeH2 and RGeH3 (R = alkyl, aryl). The use of trichloroisocyanuric acid (TCCA) allows the direct conversion of Ge‐H functions into their monochlorinated derivatives R2Ge(Cl)H and RGe(Cl)H2.

  通过对R 3 GeH，R 2 GeH 2和RGeH 3类型（R =烷基，芳基）的有机锗氢化物进行选择性官能化，给出了对有机锗氢化物进行选择性氯化的方法。使用三氯异氰尿酸（TCCA）可以将Ge‐H功能直接转化为其单氯代衍生物R 2 Ge（Cl）H和RGe（Cl）H 2。
• The Thermal Reactions of Allyl-substituted Germyl Radicals
  作者：Kunio Mochida、Isoo Miyagawa

  DOI：10.1246/bcsj.56.1875

  日期：1983.6

  The allyldibutylgermyl and dibutyl(2-methylallyl)germyl radicals in benzene at 80 °C afforded diallyldibutylgermane and dibutylgermane, and dibutylbis(2-methylallyl)germane and dibutylgermane, respectively. The mechanism of these reactions is discussed.

  烯丙基二丁基甲锗基和二丁基(2-甲基烯丙基)甲锗基在80℃下在苯中分别生成二烯丙基二丁基锗烷和二丁基锗烷，以及二丁基双(2-甲基烯丙基)锗烷和二丁基锗烷。讨论了这些反应的机理。
• Homolytic hydrogermylation of alkenes with dibutylchlorogermane
  作者：Katsukiyo Miura、Kazunori Ootsuka、Akira Hosomi

  DOI：10.1016/j.jorganchem.2006.04.043

  日期：2007.1

  In the presence of Et3B-dry air, dibutylchlorogermane (Bu2GeClH) reacted smoothly with alkenes at room temperature to give hydrogermylation products in high yields. This homolytic hydrogermylation was applicable to various alkenes including electron-deficient, electron-rich, and internal alkenes. Under the same conditions, tributylgermane (Bu3GeH) showed much lower reactivity than Bu2GeClH. The Et3B-initiated reaction of 1,6-dienes with Bu2GeClH gave germylmethylated cyclopentanes. (c) 2006 Elsevier B.V. All rights reserved.
• Catalytic Synthesis of Cyclic and Linear Germoxanes Mediated by an Iron Complex
  作者：Masahiro Kamitani、Kozo Fukumoto、Ryosuke Tada、Masumi Itazaki、Hiroshi Nakazawa

  DOI：10.1021/om3001845

  日期：2012.4.23

  Six-membered cyclic germoxanes (R2GeO)(3) were selectively prepared via the thermal reaction of (alkyl)(2)-GeH2 in dimethylformamide (DMF). Linear metallagermoxanes with an E-O-Ge-O-E backbone (E = Si, Ge, Sn) were prepared by the reaction of Ph2GeH2 with R3EH in DMF. Their cyclic and linear germoxane formations were achieved using an iron catalyst, (eta(5)-C5H5)Fe(CO)(2)Me. An iron carbene complex was proposed to be an intermediate in the catalytic reaction.
• Cationic Hydridotriplatinum Complex with Bridging Germylene Ligands
  作者：Kimiya Tanaka、Makoto Tanabe、Tomohito Ide、Kohtaro Osakada

  DOI：10.1021/om500309k

  日期：2014.5.27

  Triplatinum complexes with bridging secondary germylene ligands, [(Pt(PMe3)}(3)(mu-GeR2)(3)] (R = Ph, Bu-n), were prepared from the reaction of H2GeR2 with [Pt(PMe3)4] in a 1:1 ratio. Protonation of the triplatinum complexes with HBF4 led to formation of the cationic hydride complexes [Pt(PMe3)}(3)(mu-GeR2)(3)(mu(3)-H)D3F4 (R = Ph, Bu-n). The results of multinuclear NMR spectra and DFT calculations of the cationic complexes revealed that the Pt3H core has a trigonal-pyramidal structure with rapid exchange of the mu(3)-hydride ligand position between the two possible positions on the opposite side of the Pt-3 plane.