1-nonyl thiocyanate | 25681-48-5

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: 1-nonyl thiocyanate
• 英文别名: nonylsulfanyl cyanate；Thiocyansaeure-nonylester；Nonylthiocyanat；nonyl thiocyanate
• CAS: 25681-48-5
• 化学式: C₁₀H₁₉NS
• 分子量: 185.334
• InChiKey: OLKYACJKIWRGPG-UHFFFAOYSA-N

物化性质

• 沸点：
  156-157 °C(Press: 19 Torr)
• 密度：
  0.9091 g/cm3(Temp: 25 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  49.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-nonyl thiocyanate 在 硫酸 作用下， 生成 thiocarbamic acid S-nonyl ester
  参考文献：
  名称：

  Thiocarbamate. Mitt. VII: Einwirkung von konz. Schwefels�ure auf aliphatische und hydroaromatische Rhodanide

  摘要：

  DOI：

  10.1007/bf00899195
• 作为产物：
  描述：

  1-溴壬烷 、 potassium thioacyanate 在 乙醇 作用下， 生成 1-nonyl thiocyanate
  参考文献：
  名称：

  The Preparation of Some Normal Aliphatic Thiocyanates

  摘要：

  DOI：

  10.1021/ja01304a053

文献信息

• FLUOROALKYLATING AGENT
  申请人：IHARA CHEMICAL INDUSTRY CO., LTD.

  公开号：US20170197920A1

  公开（公告）日：2017-07-13

  Problem to be Solved It is intended to provide an industrially preferable fluoroalkylating agent and use thereof. Solution The present invention provides a fluoroalkylating agent represented by the general formula (1) wherein R 1 is a C1 to C8 fluoroalkyl group; R 2 and R 3 are each independently a C1 to C12 alkyl group or the like; Y 1 to Y 4 are each independently a hydrogen atom, a halogen atom, or the like; and X − is a monovalent anion. A compound of the general formula (3): R 4 —S—R 1 having an introduced C1 to C8 fluoroalkyl group is easily obtained by reacting a compound of the general formula (2): R 4 —S—Z wherein R 4 is a hydrocarbon group or the like; and Z is a leaving group, with the compound of the general formula (1).

  要解决的问题 旨在提供一种工业上可取的氟烷基化剂及其使用方法。 解决方案 本发明提供了一种由通式（1）表示的氟烷基化剂，其中R 1 是C1到C8的氟烷基团；R 2 和R 3 分别独立地是C1到C12的烷基团或类似物；Y 1 到Y 4 分别独立地是氢原子、卤素原子或类似物；X − 是一价阴离子。 通式（3）的化合物：R 4 —S—R 1 ，其中引入了C1到C8的氟烷基团，可通过将通式（2）的化合物：R 4 —S—Z（其中R 4 是烃基团或类似物；Z是离去基团）与通式（1）的化合物反应而轻松获得。
• Preparation of Alkyl Nitrates, Nitrites, and Thiocyanates from Alcohols Utilizing Trichloroisocyanuric Acid with Triphenylphosphine
  作者：Gene A. Hiegel、Jeremiah Nguyen、Yan Zhou

  DOI：10.1081/scc-200025580

  日期：2004.1.1

  Abstract Alcohols in acetonitrile are converted into alkyl nitrates, nitrites, or thiocyanates by the action of triphenylphosphine and trichloroisocyanuric acid along with silver nitrate, silver nitrite, or sodium thiocyanate, respectively.

  摘要 乙腈中的醇在三苯基膦和三氯异氰尿酸与硝酸银、亚硝酸银或硫氰酸钠的作用下分别转化为硝酸烷基酯、亚硝酸盐或硫氰酸盐。
• Residual control of parasites by long-acting shampoo formulations
  申请人：LABORATOIRES VIRBAC

  公开号：EP0714601A1

  公开（公告）日：1996-06-05

  The invention relates to shampoo compositions comprising a detergent and at least one active compound selected from juvenile hormone-like nitrogen containing heterocyclic compounds, other insect growth regulators such as methoprene or fenoxycarb, synthetic pyrethroids and mixtures thereof, wherein the dose of the active compound is sufficient for leaving on the haircoat of a warm-blooded animal after rinse out the shampoo an ovicidally and/or insecticidally and/or acaricidally residual effective amount against ectoparasites of said compound. Such shampoo compositions are useful for a residual control of ectoparasites on warm-blooded animals.

  本发明涉及由洗涤剂和至少一种活性化合物组成的洗发水组合物，这些活性化合物选自含杂环化合物的稚虫激素样氮、其他昆虫生长调节剂如甲氧苄啶或唑螨酯、合成除虫菊酯及其混合物，其中活性化合物的剂量足以在洗发水冲洗后在温血动物的毛发上残留有效量的卵杀螨剂和/或杀虫剂和/或杀螨剂。这种洗发水组合物可用于温血动物体外寄生虫的残留控制。
• Fluoroalkylating agent
  申请人：KUMIAI CHEMICAL INDUSTRY CO., LTD.

  公开号：US10308613B2

  公开（公告）日：2019-06-04

  Problem to be Solved It is intended to provide an industrially preferable fluoroalkylating agent and use thereof. Solution The present invention provides a fluoroalkylating agent represented by the general formula (1) wherein R1 is a C1 to C8 fluoroalkyl group; R2 and R3 are each independently a C1 to C12 alkyl group or the like; Y1 to Y4 are each independently a hydrogen atom, a halogen atom, or the like; and X− is a monovalent anion. A compound of the general formula (3): R4—S—R1 having an introduced C1 to C8 fluoroalkyl group is easily obtained by reacting a compound of the general formula (2): R4—S—Z wherein R4 is a hydrocarbon group or the like; and Z is a leaving group, with the compound of the general formula (1).

  有待解决的问题 旨在提供一种工业上更理想的氟烷基化剂及其用途。 解决方案 本发明提供了一种由通式（1）表示的氟烷基化剂，其中 R1 是 C1 至 C8 氟烷基；R2 和 R3 各自独立地是 C1 至 C12 烷基或类似基团；Y1 至 Y4 各自独立地是氢原子、卤素原子或类似基团；X- 是单价阴离子。 通式（3）的化合物：将通式（2）的化合物与通式（1）的化合物反应，很容易得到具有引入的 C1 至 C8 氟烷基的 R4-S-R1 化合物：其中 R4 是烃基或类似物；Z 是离去基团。
• Procatalysts, catalyst systems, and use in olefin polymerization
  申请人：——

  公开号：US20010025005A1

  公开（公告）日：2001-09-27

  There are described solid procatalysts, catalyst systems incorporating the solid procatalysts, and the use of the catalyst systems in olefin polymerization and interpolymerization.

  本文介绍了固体原催化剂、含有固体原催化剂的催化剂体系以及催化剂体系在烯烃聚合和互聚中的应用。