2,3-dihydroxypropyl dodecylcarbamate | 133685-16-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: 2,3-dihydroxypropyl dodecylcarbamate
• 英文别名: 2,3-dihydroxypropyl N-dodecylcarbamate
• CAS: 133685-16-2
• 化学式: C₁₆H₃₃NO₄
• 分子量: 303.442
• InChiKey: XDVFJXAIGKOTQD-UHFFFAOYSA-N

物化性质

• 沸点：
  467.8±35.0 °C(Predicted)
• 密度：
  1.010±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  21
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  78.8
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  羟甲基二氧杂戊环酮 、 十二烷基伯胺 以 乙酸乙酯 为溶剂， 反应 3.0h， 生成 2,3-dihydroxypropyl dodecylcarbamate 、 1,3-dihydroxypropan-2-yl dodecylcarbamate
  参考文献：
  名称：

  [EN] ADJUVANTS BASED ON OPTIONALLY ALKOXYLATED REACTION PRODUCTS OF GLYCEROL CARBONATE AND ALKYLAMINES
  [FR] ADJUVANTS À BASE DE PRODUITS ÉVENTUELLEMENT ALCOXYLÉS DE LA RÉACTION ENTRE UN CARBONATE DE GLYCÉROL ET DES ALKYLAMINES

  摘要：

  本发明涉及一种组合物，包括一种杀虫剂和一种辅助剂，所述辅助剂选自下述化学式(I)的氨基甲酸酯、化学式(II)的氨基甲酸酯，或者一种聚合物，其可通过至少一种烷基氧化物和下述定义的化学式(I)和/或(II)的氨基甲酸酯的聚合获得。本发明还涉及通过将辅助剂和杀虫剂接触制备所述组合物的方法；一种聚合物，其可通过下述定义的聚合获得，其由下述定义的化学式(III)或(IV)的化合物组成；通过首先使甘油碳酸酯和下述化学式R-NH2的胺反应从而产生化学式(I)和/或(II)的氨基甲酸酯，然后聚合至少一种烷基氧化物和化学式(I)和/或(II)的氨基甲酸酯的方法制备所述聚合物；一种控制植物病原真菌和/或不受欢迎的植物生长和/或不受欢迎的昆虫或螨虫侵袭和/或调节植物生长的方法，其中允许所述组合物作用于各自的害虫、它们的环境或待保护免受各自害虫侵害的作物植物、土壤和/或不受欢迎的植物和/或作物植物和/或它们的环境；以及含有所述组合物的种子。

  公开号：

  WO2013127629A1

文献信息

• Carbamates from Glycerine Carbonate for Pearlization
  申请人：Evonik Industries AG

  公开号：US20150044264A1

  公开（公告）日：2015-02-12

  Alkyl and/or alkenyl glycerol carbamate prepared by reacting a carbonate selected from the group consisting of glycerol carbonate, diglycerol carbonate, polyglycerol carbonate and mixtures thereof, with an amine of the general formula (I): HNR 1 R 2 (I) wherein R 1 represents a hydrogen atom or a hydrocarbon group selected from the group consisting of alkyl groups and alkenyl groups having from 1 to 22 carbon atoms and R 2 represents a hydrocarbon group selected from the group consisting of alkyl groups and alkenyl groups having from 4 to 22 carbon atoms, and cyclic alkyl groups having 5 or 6 carbon atoms, are described along with methods for their use as pearlizing agents in surface-active preparations.

  通过将选自由甘油碳酸酯、二甘油碳酸酯、多甘油碳酸酯和其混合物的碳酸酯与通式（I）的胺反应制备烷基和/或烯基甘油氨基甲酸酯，其中R1表示氢原子或由1到22个碳原子的烷基和烯基基团组成的羟基碳基，R2表示由4到22个碳原子的烷基和烯基基团以及具有5或6个碳原子的环烷基组成的羟基碳基。同时还描述了它们作为表面活性制剂中珠光剂的使用方法。
• Alkyl and/or alkenyl glycerol carbamates
  申请人：——

  公开号：US20040110659A1

  公开（公告）日：2004-06-10

  Alkyl and/or alkenyl glycerol carbamate prepared by reacting a carbonate selected from the group consisting of glycerol carbonate, diglycerol carbonate, polyglycerol carbonate and mixtures thereof, with an amine of the general formula (I): HNR 1 R 2 (I) wherein R 1 represents a hydrogen atom or a hydrocarbon group selected from the group consisting of alkyl groups and alkenyl groups having from 1 to 22 carbon atoms and R 2 represents a hydrocarbon group selected from the group consisting of alkyl groups and alkenyl groups having from 4 to 22 carbon atoms, and cyclic alkyl groups having 5 or 6 carbon atoms, are described along with methods for their use as thickeners in surface-active preparations.

  烷基和/或烯基甘油氨基甲酸酯，其制备方法是将选自甘油碳酸酯、二甘油碳酸酯、聚甘油碳酸酯及其混合物的碳酸酯与通式 (I) 的胺反应： HNR 1 R 2 (I) 其中 R 1 代表氢原子或烃基，选自由碳原子数为 1-22 个的烷基和烯基组成的组，且 R 2 代表从具有 4 至 22 个碳原子的烷基和烯基以及具有 5 或 6 个碳原子的环状烷基组成的组中选出的烃基。
• Aminolysis Reaction of Glycerol Carbonate in Organic and Hydroorganic Medium
  作者：Bassam Nohra、Laure Candy、Jean-François Blanco、Yann Raoul、Zephirin Mouloungui

  DOI：10.1007/s11746-011-1995-5

  日期：2012.6

  AbstractAminolysis reaction of glycerol carbonate with primary amine in organic and hydroorganic media leads to the formation of two hydroxyurethane isomers and a partial decomposition of glycerol carbonate into glycerol. Aminolysis with a secondary amine promotes the condensation reaction and limits the formation of glycerol. The ratio of α versus β was determined by zgig 13C NMR. This technique permits computing the yield of α and β products in the medium. The quantity of glycerol was determined by GC analysis. The ratio of the isomers and the amount of glycerol depend on the amine and the solvent. Kinetic investigations reveal that, in hydroorganic medium, the more the alkyl chain of the amine increased, the less glycerol was formed. On the contrary, in organic medium, the alkyl chain of the amine does not play a major role in the formation of glycerol.
• Tosylated glycerol carbonate, a versatile bis-electrophile to access new functionalized glycidol derivatives
  作者：Jolanta Rousseau、Cyril Rousseau、Benita Lynikaite˙、Algirdas Šačkus、Claudia de Leon、Patrick Rollin、Arnaud Tatibouët

  DOI：10.1016/j.tet.2009.07.095

  日期：2009.10

  The reactivity of tosylated glycerol carbonate 2 toward nucleophiles has been exploited to generate glycidol analogues protected with carbonate or carbamate groups. The activated glycerol 2 is a reasonable linking agent with thiol and alcohol nucleophiles and an excellent and selective one with primary amines, allowing efficient bis-functionalizations of glycerol. (C) 2009 Elsevier Ltd. All rights reserved.
• ADJUVANTS BASED ON OPTIONALLY ALKOXYLATED REACTION PRODUCTS OF GLYCEROL CARBONATE AND ALKYLAMINES
  申请人：BASF SE

  公开号：US20150072856A1

  公开（公告）日：2015-03-12

  The present invention relates to a composition comprising a pesticide and an adjuvant selected from a carbamate of the formula (I), a carbamate of the formula (II), or a polymer, which is obtainable by polymerization of at least one alkylene oxide and a carbamate of the formula (I) and/or (II) as defined below. The invention further relates to a method of preparing said composition by bringing the adjuvant and the pesticide into contact; to a polymer, which is obtainable by the polymerization as defined below, and which consists of the compounds of the formula (III) or (IV) as defined below; to a method of preparing said polymer by first reacting a glycerol carbonate and an amine of the formula R—NH 2 yielding the carbamate of the formula (I) and/or (II); followed by polymerization of at least one alkylene oxide and the carbamate of the formula (I) and/or (II); to a method of controlling phytopathogenic fungi and/or undesired plant growth and/or undesired insect or mite attack and/or for regulating the growth of plants, wherein said composition is allowed to act on the respective pests, their environment or the crop plants to be protected from the respective pest, on the soil and/or on undesired plants and/or on the crop plants and/or on their environment; and to seed containing said composition.