n-5-hexenylsilane | 120287-17-4

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物
• 英文名称: n-5-hexenylsilane
• 英文别名: 5-hexenylsilane；(Hex-5-en-1-yl)silane；hex-5-enylsilane
• CAS: 120287-17-4
• 化学式: C₆H₁₄Si
• 分子量: 114.263
• InChiKey: IHUVWFSATFECBU-UHFFFAOYSA-N

物化性质

• 沸点：
  101-103 °C

计算性质

• 辛醇/水分配系数(LogP)：
  1.13
• 重原子数：
  7
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  6-溴-1-己烯 在 1,2-二溴乙烷 lithium aluminium tetrahydride 、 四氯化硅 、 magnesium 作用下， 以 乙醚 为溶剂， 反应 3.0h， 生成 n-5-hexenylsilane
  参考文献：
  名称：

  烯基硅烷结构对单核和双核有机钛介导的乙烯聚合的影响：同时聚烯烃支链和官能团的范围和机理介绍

  摘要：

  在有机钛介导的烯烃聚合过程中，研究了不同链长的烯基硅烷作为同时的链转移剂和共聚单体。乙烯聚合用活化的 CGCTiMe2 和 EBICGCTi2Me4 (CGC = Me2Si(Me4C5)(NtBu)；EBICGC = (mu-CH2CH2-3,3'){(eta5-茚基)[1-Me2Si(tBuN)]}2)在烯丙基硅烷、3-丁烯基硅烷、5-己烯基硅烷和7-辛烯基硅烷存在下的预催化剂。在这些烯基硅烷的存在下，观察到高聚合活性（高达 107 g 聚合物/（Ti.atm 乙烯.h 的摩尔数））、狭窄的产品共聚物多分散性和大量的长链支化。无论 Ti 核性如何，烯基硅烷掺入水平遵循 C8H15SiH3 < C6H11SiH3 大约 C4H7SiH3 < C3H5SiH3 的趋势。与 EBICGCTi2Me4 介导的共聚反应（高达 32%）相比，CGCTiMe2 介导的共聚反应（高达 54%）的烯基硅

  DOI：

  10.1021/ja0675292

文献信息

• Silylation reactions of olefins with monosilane and disilane in the presence of a transition metal complex, metal hydride, and radical initiator
  作者：Masayoshi Itoh、Kenji Iwata、Mineo Kobayashi

  DOI：10.1016/s0022-328x(98)00814-6

  日期：1999.2

  The catalytic reactions between monosilane or disilane and 1-hexene or 1,5-hexadiene were studied. The reactions with monosilane gave the silylated compounds in the presence of a platinum complex, LiAlH4 and a radical initiator. In the reactions with disilane, the same silylated compounds were produced in the presence of a platinum complex as in the reaction with monosilane, and disilanylated compounds

  研究了甲硅烷或乙硅烷与1-己烯或1,5-己二烯之间的催化反应。与甲硅烷的反应在铂络合物，LiAlH 4和自由基引发剂的存在下得到甲硅烷基化的化合物。在与乙硅烷的反应中，在铂络合物的存在下与在与甲硅烷的反应中产生相同的甲硅烷基化的化合物，并且使用LiAlH 4和自由基引发剂获得二甲硅烷基化的化合物。讨论了反应机理。
• Alkenylsilane Effects on Organotitanium-Catalyzed Ethylene Polymerization. Toward Simultaneous Polyolefin Branch and Functional Group Introduction
  作者：Smruti B. Amin、Tobin J. Marks

  DOI：10.1021/ja057947r

  日期：2006.4.1

  The comonomer 5-hexenylsilane is introduced into organotitanium-mediated ethylene polymerizations to produce silane-terminated ethylene/5-hexenylsilane copolymers. The resulting polymers were characterized by 1H and 13C NMR, GPC, and DSC. High activities (up to 107 g polymer/(mol Ti.atm ethylene.h)) and narrow polydispersities are observed in the polymerization/chain transfer process. Ethylene/5-hexenylsilane copolymer molecular weights are found to be inversely proportional to 5-hexenylsilane concentration, supporting a silanolytic chain transfer mechanism. Control experiments indicate that chain transfer mechanism by 5-hexenylsilane is significantly more efficient than that of n-hexylsilane for organotitanium-mediated ethylene polymerization. The present study represents the first case in which a functionalized comonomer is efficiently used to effect both propagation and chain transfer chemistry during olefin polymerization.