2,5-diphenyl-4,6-dimethyl-1,3,2,5-dioxaborataphosphorinane | 87579-69-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,5-diphenyl-4,6-dimethyl-1,3,2,5-dioxaborataphosphorinane
• 英文别名: 4,6-Dimethyl-2,5-diphenyl-1,3,2,5-dioxaboraphosphorinane；4,6-dimethyl-2,5-diphenyl-1,3,5,2-dioxaphosphaborinane
• CAS: 87579-69-9
• 化学式: C₁₆H₁₈BO₂P
• 分子量: 284.102
• InChiKey: LCRDDCQYRYVAIF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.93
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,5-diphenyl-4,6-dimethyl-1,3,2,5-dioxaborataphosphorinane 、 sulfur 以 苯 为溶剂， 以80%的产率得到4,6-dimethyl-2,5-diphenyl-5-sulfanylidene-1,3,5λ⁵,2-dioxaphosphaborinane
  参考文献：
  名称：

  Stereoisomer equilibrium of 4,6-disubstituted 2,5-diphenyl-2-bora-1,3,5-dioxaphosphorinanes

  摘要：

  DOI：

  10.1007/bf00954709
• 作为产物：
  描述：

  triethylammonium 2,2,5-triphenyl-4,6-dimethyl-1,3,2,5-dioxaborataphosphorinane 以 neat (no solvent) 为溶剂， 以48%的产率得到2,5-diphenyl-4,6-dimethyl-1,3,2,5-dioxaborataphosphorinane
  参考文献：
  名称：

  Reaction of ammonium 1,3,2,5-dioxaborataphosphorinanes with electrophilic reagents

  摘要：

  DOI：

  10.1007/bf00962675

文献信息

• Synthesis and spatial structure of 4,6-disubstituted 2-boro-1,3,5-dioxaphosphorinanes
  作者：B. A. Arbuzov、O. A. Erastov、G. N. Nikonov、I. P. Romanova、R. P. Arshinova、R. A. Kadyrov

  DOI：10.1007/bf00953166

  日期：1983.6
• Complexes of 1,3,2,5-dioxaboraphosphorinanes with borane
  作者：B. A. Arbuzov、G. N. Nikonov、A. A. Karasik、E. V. Malova

  DOI：10.1007/bf00961701

  日期：1990.5

  2,5-Diphenyl-4,6-di-R-1,3,2,5-dioxaboraphosphorinanes give borane complexes with a P --> B bond.
• Synthesis and structural features of 1,3,2,5-dioxaboraphosphorinane complexes with Pt(II) and Pd(II) salts
  作者：A. A. Karasik、G. N. Nikonov、B. A. Arbuzov、K. M. Enikeev、E. V. Malova

  DOI：10.1007/bf00963499

  日期：1991.10

  Complexes of composition L2MCl2 [M = Pt, R = H (I), Me (II), Ph (III)] and LMCl2 [M = Pd, R = H (IV)] are prepared by reaction of 4,6-R2-2,5-diphenyl-1,3,2,5-dioxaboraphosphorinanes (L) with MCl2. Far-IR and P-31 NMR spectroscopy are used to demonstrate that I is cis whereas II and III are trans complexes in the solid. The conformational behavior of I is studied by P-31 and H-1 NMR. The asymmetric form of I exhibits anomalous stability.
• O-Complexes of 1,3,2,5-dioxaboraphosphorinanes with copper(I) and silver(I) salts
  作者：B. A. Arbuzov、G. N. Nikonov、A. A. Karasik、K. M. Enikeev

  DOI：10.1007/bf00958578

  日期：1991.4

  1,3,2,5-Dioxaboraphosphorinanes interact stereospecifically with Cu(I) and Ag(I) salts to form the corresponding O-complexes. The three-dimensional structure of the ligands has been established from P-31 NMR and H-1 NMR data.
• Substitution of the chr-O fragment in 1,3,2,5-dioxaboraphosphorinanes
  作者：G. N. Nikonov、S. N. Ignat'eva、A. S. Balueva、O. A. Erastov、B. A. Arbuzov

  DOI：10.1007/bf00953433

  日期：1988.10