N,N'-bis(2,6-diisopropylphenyl)-1,6,9,14-tetra(2,6-diisopropylphenoxy)-terrylene-3,4:11,12-tetracarboximide | 919488-80-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: N,N'-bis(2,6-diisopropylphenyl)-1,6,9,14-tetra(2,6-diisopropylphenoxy)-terrylene-3,4:11,12-tetracarboximide
• 英文别名: 11,26,34,36-Tetrakis[2,6-di(propan-2-yl)phenoxy]-7,22-bis[2,6-di(propan-2-yl)phenyl]-7,22-diazadecacyclo[14.14.2.22,5.217,20.03,12.04,9.013,31.018,27.019,24.028,32]hexatriaconta-1(31),2(36),3,5(35),9,11,13,15,17(34),18,20(33),24,26,28(32),29-pentadecaene-6,8,21,23-tetrone
• CAS: 919488-80-5
• 化学式: C₁₀₆H₁₁₀N₂O₈
• 分子量: 1540.05
• InChiKey: AXFMYJBQNFNZQR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  29
• 重原子数：
  116
• 可旋转键数：
  22
• 环数：
  16.0
• sp3杂化的碳原子比例：
  0.34
• 拓扑面积：
  112
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  丙泊酚 、 N,N'-bis(2,6-diisopropylophenyl)-1,6,9,13-tetrabromoterrylen-3,4:11,12-tetracarbooxdiimide 在 potassium carbonate 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 5.0h， 以92%的产率得到N,N'-bis(2,6-diisopropylphenyl)-1,6,9,14-tetra(2,6-diisopropylphenoxy)-terrylene-3,4:11,12-tetracarboximide
  参考文献：
  名称：

  Substituted Rylene Derivatives

  摘要：

  该公式的Rylene衍生物为I，其中变量的定义如下： Rylene是一个多环共轭环系统，包括至少一个苝并单元，可能包含杂原子作为环原子，可能被含有—CO—基团的基团所官能化，或者可能带有除A基团以外的其他取代基； A是公式的基团； X是氧或硫； R是相同或不同的基团：可选取代的烷基、环烷基、芳基、杂芳基、—U-芳基，其中U是—O—、—S—、—NR2—、—CO—、—SO—或—SO2—基团，或C1-C12-烷氧基、C1-C6-烷基硫基、—C≡CR2、—CR2═CR22、羟基、巯基、卤素、氰基、硝基、—NR3R4、—NR3COR4、—CONR3R4、—SO2NR3R4、—COOR3或—SO3R3； R′是相同或不同的基团：氢或R基团之一； R2是氢或烷基，当它们出现多次时，R2基团可以相同或不同； R3、R4各自独立地为氢；可选取代的烷基、芳基或杂芳基； n为1至8。

  公开号：

  US20080167467A1

文献信息

• [EN] TRANSMITTER FOR TRANSMITTING DATA AND FOR EMITTING ELECTROMAGNETIC RADIATION IN THE VISIBLE SPECTRAL RANGE AND DATA TRANSMISSION SYSTEM<br/>[FR] ÉMETTEUR DE TRANSMISSION DE DONNÉES ET D'ÉMISSION DE RAYONNEMENT ÉLECTROMAGNÉTIQUE DANS LA PLAGE SPECTRALE VISIBLE ET SYSTÈME DE TRANSMISSION DE DONNÉES
  申请人：BASF SE

  公开号：WO2019038354A1

  公开（公告）日：2019-02-28

  The present invention relates to a transmitter for transmitting data and for emitting electromagnetic radiation in the visible spectral range, wherein the transmitter comprises a) a radiation source for generating and emitting first electromagnetic radiation, b) a modulator being adapted to modulate the first electromagnetic radiation depending on the data to be transmitted generating modulated first electromagnetic radiation, and c) a frequency converter for converting at least a part of the modulated first electromagnetic radiation into modulated second electromagnetic radiation, said modulated second electromagnetic radiation being different from the modulated first electromagnetic radiation, wherein the frequency converter comprises a polymeric matrix material comprising at least one organic fluorescent colorant. Furthermore, the invention relates to an illumination device comprising such transmitter. Moreover, the invention relates to a data transmission system comprising such a transmitter as well as a receiver and a data analyzer.

  本发明涉及一种用于传输数据并在可见光谱范围内发射电磁辐射的发射机，其中该发射机包括a) 用于产生和发射第一电磁辐射的辐射源，b) 调制器，适用于根据要传输的数据调制第一电磁辐射，生成调制的第一电磁辐射，以及c) 频率转换器，用于将至少部分调制的第一电磁辐射转换为调制的第二电磁辐射，所述调制的第二电磁辐射与调制的第一电磁辐射不同，其中频率转换器包括至少一种有机荧光色料的聚合物基质材料。此外，该发明涉及一种包括该发射机的照明装置。此外，该发明涉及一种数据传输系统，包括该发射机、接收机和数据分析仪。
• Transmitter for transmitting data and for emitting electromagnetic radiation in the visible spectral range and data transmission system
  申请人：BASF SE

  公开号：US11496223B2

  公开（公告）日：2022-11-08

  The present invention relates to a transmitter for transmitting data and for emitting electromagnetic radiation in the visible spectral range, wherein the transmitter comprises a) a radiation source for generating and emitting first electromagnetic radiation, b) a modulator being adapted to modulate the first electromagnetic radiation depending on the data to be transmitted generating modulated first electromagnetic radiation, and c) a frequency converter for converting at least a part of the modulated first electromagnetic radiation into modulated second electromagnetic radiation, said modulated second electromagnetic radiation being different from the modulated first electromagnetic radiation, wherein the frequency converter comprises a polymeric matrix material comprising at least one organic fluorescent colorant. Furthermore, the invention relates to an illumination device comprising such transmitter. Moreover, the invention relates to a data transmission system comprising such a transmitter as well as a receiver and a data analyzer.

  本发明涉及一种用于传输数据和发射可见光谱范围内电磁辐射的发射机，其中发射机包括 a) 用于产生和发射第一电磁辐射的辐射源；b) 调制器，适于根据要传输的数据对第一电磁辐射进行调制，产生调制后的第一电磁辐射；以及 c) 频率转换器，用于将至少一部分调制后的第一电磁辐射转换为调制后的第二电磁辐射、c) 频率转换器，用于将至少一部分调制后的第一电磁辐射转换为调制后的第二电磁辐射，所述调制后的第二电磁辐射不同于调制后的第一电磁辐射，其中频率转换器包括聚合基体材料，该材料包含至少一种有机荧光着色剂。此外，本发明还涉及一种包含此类发射器的照明设备。此外，本发明还涉及一种数据传输系统，该系统包括这样一个发射器以及一个接收器和一个数据分析器。
• USE OF RYLENES AS MARKERS FOR LIQUIDS
  申请人：Gessner Thomas

  公开号：US20100011656A1

  公开（公告）日：2010-01-21

  The invention relates to the use of rylene derivatives of the general formula (I) as markers for liquids, where the symbols and indices have the meanings given in the specification.
• TRANSMITTER FOR TRANSMITTING DATA AND FOR EMITTING ELECTROMAGNETIC RADIATION IN THE VISIBLE SPECTRAL RANGE AND DATA TRANSMISSION SYSTEM
  申请人：BASF SE

  公开号：US20200259567A1

  公开（公告）日：2020-08-13

  The present invention relates to a transmitter for transmitting data and for emitting electromagnetic radiation in the visible spectral range, wherein the transmitter comprises a) a radiation source for generating and emitting first electromagnetic radiation, b) a modulator being adapted to modulate the first electromagnetic radiation depending on the data to be transmitted generating modulated first electromagnetic radiation, and c) a frequency converter for converting at least a part of the modulated first electromagnetic radiation into modulated second electromagnetic radiation, said modulated second electromagnetic radiation being different from the modulated first electromagnetic radiation, wherein the frequency converter comprises a polymeric matrix material comprising at least one organic fluorescent colorant. Furthermore, the invention relates to an illumination device comprising such transmitter. Moreover, the invention relates to a data transmission system comprising such a transmitter as well as a receiver and a data analyzer.
• RECEIVER COMPRISING A LUMINESCENT COLLECTOR FOR OPTICAL DATA COMMUNICATION
  申请人：BASF SE

  公开号：US20220049158A1

  公开（公告）日：2022-02-17

  A receiver comprising a luminescent collector (luminescent detector) comprising at least one organic fluorescent colorant B, an optical data communication system comprising said receiver, and to the use of the luminescent collector as fast photodetector in a receiver for an optical data communication system.